Abstract:
PURPOSE: A hyperbranched polymer, a fuel cell electrode including thereof, and a fuel cell including the electrode are provided to simply mass produce the polymer with an easy synthesizing process, and to improve the oxygen permeability, the durability, and the heat resistance of the electrode. CONSTITUTION: A hyperbranched polymer with the degree of branching of 0.05~1, contains a dendritic unit marked with chemical formula 1, a linear unit marked with chemical formula 2, a terminal unit marked with chemical formula 3. In the chemical formulas, R is selected from the group consisting of fluorine, a fluorinated alkyl group with C1~C20, a fluorinated aryl group with C6~C20, a fluorinated heteroaryl group with C2~C20, a fluorinated cycloalkyl group with C6~C20, and a fluorinated heterocyclic group with C2~C20.
Abstract:
PURPOSE: A porous membrane is provided to have excellent chemical and mechanical stability, thereby being useful as a support material. CONSTITUTION: A porous membrane comprises a polyazole-based polymerization reaction product and one or more compounds selected from the compounds indicated in chemical formula 1-6. The porous film is a total pore area of 100-200 m^2/g and the porosity is 40-80%. A manufacturing method of an electrolyte film comprises: a step of obtaining hydrogen ion-conductive polymer solution by mixing hydrogen ion-conductive polymer and organic solvent; and a step of supporting hydrogen ion-conductive polymer into the pores of the porous membrane by using the hydrogen ion-conductive polymer solution.
Abstract:
PURPOSE: A compound is provided to ensure excellent heat resistance and phosphoric acid resistance and to obtain a fuel cell with an improved lifetime property and cell performance when applied to the electrode and the electrolyte film for the fuel cell. CONSTITUTION: A compound is a polymerization product of a composition that contains a diisocyanate-based compound represented by chemical formula 1 below and an aromatic polyol represented by chemical formula 2, wherein A1 and A2 are each independently a substituted or unsubstituted C1-C30 alkylene group, a substituted or unsubstituted C2-C30 alkenylene group, a substituted or unsubstituted C2-C30 alkynylene group, a substituted or unsubstituted C6-C30 arylene group, a substituted or unsubstituted C2-C30 heteroarylene group, a substituted or unsubstituted C4-C30 carbon cyclic group, or a substituted or unsubstituted C6-C30 condensed polycyclic group; m is 0 or 1; R1 is a hydrogen atom or -P(-O)RR'; R and R' are each independently a hydrogen atom, a C1-C30 alkyl group, or a C6-C30 aryl group; and L is represented by chemical formula 1A.
Abstract:
PURPOSE: A polymer composition is provided to obtain a cross-linked polymer composition with enhanced capability of retaining phosphoric acid at a wide range of temperature and to secure long-term durability and enhanced proton conductivity. CONSTITUTION: A polymer composition comprises: a polymer having a first repeating unit represented by chemical formula 1 and a second repeating unit represented by chemical formula 2, and an oxazine-based monomer. In chemical formula 1, Ar is a substituted or unsubstituted C6-C20 arylene group or a substituted or unsubstituted C3-C20 heteroarylene group and m is a number from 0.01 from 1. In chemical formula 2, R1 is a hydrogen atom, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C1-C20 alkoxy group, a substituted or unsubstituted C6-C20 aryl group, a substituted or unsubstituted C6-C20 aryloxy group, a substituted or unsubstituted C3-C20 heteroaryl group, or a substituted or unsubstituted C3-C20 heteroaryloxy group; R2 and R3 are each independently a hydrogen atom, an unsubstituted or substituted C1-C20 alkyl group, an unsubstituted or substituted C1-C20 alkoxy group, an unsubstituted or substituted C6-C20 aryl group, an unsubstituted or substituted C6-C20 aryloxy group, an unsubstituted or substituted C3-C20 heteroaryl group, or an unsubstituted or substituted C3-C20 heteroaryloxy group, or R2 and R3 may be linked to form a C4-C20 carbocyclic group or a C3-C20 heterocyclic group; and n is a number from 0 to 0.99.