公开(公告)号：KR1020000035163A

公开(公告)日：2000-06-26

申请号：KR1019990048161

申请日：1999-11-02

Applicant: 신디알 에스.피.에이.

Inventor： 발두찌루이기 ,  부쪼니로베르또 ,  달로로레오나르도 ,  데알베르티지오르다노

IPC: B01J21/12

CPC classification number: B01J35/08 ,  B01J29/035 ,  B01J29/40 ,  B01J29/89 ,  B01J37/033 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/42 ,  C07C231/10

Abstract: PURPOSE: An MFI-type zeolite based catalyst and its preparation method are provided, which catalyst is useful for the transformation of oximes into amides. CONSTITUTION: The MFI-type zeolite based catalyst is prepared by: preparing silicate oligomer by hydrolyzing silicon alkoxide; mixing the oligomer with an aqueous or aqueous alcoholic dispersion solution of sub micro particles of MFI-type zeolite which is acidified to pH below 5; emulsifying the aqueous or aqueous alcoholic ligand/zeolite mixture in an organic solvent; contacting the emulsion with a basic solution to bind the dispersed micro drops; and washing calcining the obtained micro sphere. Preferably the MFI-type zeolite is selected from the zeolite whose mole ratio of Si/Al (or Si/B, Si/Ga, Si/In, or Si/Ti) is more than 1,000, and silicalite-1. The MFI-type zeolite based catalyst is such that the silicate ligand represented by SiO2 is more than 30 wt%, the outer surface area is 60-80 square meter per gram, the specific volumes of micro pore and mesopore are 0.2-0.3 ml/g and 0.1-0.4 ml/g, respectively, the bulk density is 0.7-0.85 g/ml, and the Davison index is less than 6.

Abstract translation: 目的：提供一种MFI型沸石基催化剂及其制备方法，该催化剂可用于将肟转化为酰胺。 构成：MFI型沸石基催化剂通过以下步骤制备：通过水解硅醇盐制备硅酸盐低聚物; 将低聚物与酸化至pH低于5的MFI型沸石的亚微米颗粒的水性或水性醇分散液混合; 在有机溶剂中乳化水性或水性醇配体/沸石混合物; 使所述乳液与碱性溶液接触以结合分散的微滴; 并洗涤煅烧所获得的微球。 优选地，MFI型沸石选自Si / Al（或Si / B，Si / Ga，Si / In或Si / Ti）的摩尔比大于1000且硅沸石-1的沸石。 MFI型沸石基催化剂使得由SiO 2表示的硅酸盐配体大于30重量％，外表面积为60-80平方米/克，微孔和中孔的比体积为0.2-0.3毫升/ g和0.1-0.4ml / g，堆积密度为0.7-0.85g / ml，Davison指数小于6。

公开(公告)号：KR100370994B1

公开(公告)日：2003-02-06

申请号：KR1020000061212

申请日：2000-10-18

Applicant: 신디알 에스.피.에이.

Inventor： 만떼가짜마리아안젤라 ,  발두찌루이기 ,  리베티프란꼬

IPC: B01J29/90

CPC classification number: B01J29/90 ,  B01J29/89

Abstract: A process is described for regenerating exhausted zeolitic catalysts containing titanium and deriving from oxidation processes of organic substrates with hydrogen peroxide. Said process consists in carrying out a treatment in an aqueous medium with hydrogen peroxide in the presence of inorganic fluorinated compounds, subsequent to thermal treatment of the exhausted catalyst.

Abstract translation: 描述了用于再生含钛的耗竭沸石催化剂并衍生自用过氧化氢氧化有机底物的方法。 所述方法包括在热处理耗尽的催化剂之后，在无机氟化合物存在下，在含水介质中用过氧化氢进行处理。

公开(公告)号：KR100350255B1

公开(公告)日：2002-08-24

申请号：KR1019990048161

申请日：1999-11-02

Applicant: 신디알 에스.피.에이.

Inventor： 발두찌루이기 ,  부쪼니로베르또 ,  달로로레오나르도 ,  데알베르티지오르다노

IPC: B01J21/12

CPC classification number: B01J35/08 ,  B01J29/035 ,  B01J29/40 ,  B01J29/89 ,  B01J37/033 ,  B01J2229/26 ,  B01J2229/32 ,  B01J2229/42 ,  C07C231/10

Abstract: 본발명은옥심의아미드로의전위반응에적합한촉매의제조방법에관한것이다. 본방법은상기반응에서실질적으로불활성인규산질리간드내에 MFI 형제올라이트의서브미크론입자를구형화(englobing)하는것으로이루어진다.

公开(公告)号：KR1020010060158A

公开(公告)日：2001-07-06

申请号：KR1020000061212

申请日：2000-10-18

Applicant: 신디알 에스.피.에이.

Inventor： 만떼가짜마리아안젤라 ,  발두찌루이기 ,  리베티프란꼬

IPC: B01J29/90

CPC classification number: B01J29/90 ,  B01J29/89

Abstract: PURPOSE: To regenerate an exhausted zeolitic catalyst resulting from the oxidation process of an organic substrate using hydrogen peroxide and containing titanium. CONSTITUTION: The process for the regeneration of exhausted catalysts consisting of microporous crystalline materials with an MFI-type structure containing titanium and originally having a composition corresponding to the following chemical formula: xTiO 2·(1-x)SiO2, wherein x ranges from 0.0001 to 0.04 and preferably from 0.01 to 0.03, which consists in subjecting the catalyst, previously calcined, to a treatment in an aqueous medium with hydrogen peroxide, in the presence of fluorinated inorganic compounds.

Abstract translation: 目的：使用过氧化氢并含有钛使有机底物的氧化过程产生的耗尽的沸石催化剂再生。 构成：由具有包含钛的MFI型结构的微孔结晶材料组成的排气催化剂的再生方法，其原始具有对应于以下化学式的组成：xTiO 2·（1-x）SiO 2，其中x为0.0001 至0.04，优选为0.01至0.03，其特征在于，在氟化无机化合物的存在下，将预先煅烧的催化剂在含水介质中用过氧化氢进行处理。