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公开(公告)号：KR100373898B1
公开(公告)日：2003-02-26
申请号：KR1020000072514
申请日：2000-12-01
Applicant: 신디알 에스.피.에이. , 에니테크놀로지 에스.피.에이.
CPC classification number: C01B37/00 , B01J29/40 , B01J29/89 , B01J35/08 , B01J37/0045 , B01J37/0072 , B01J37/0219 , C01B39/026 , C07C231/10
Abstract: The present invention relates to a process for the preparation of zeolitic catalysts comprising zeolite and oligomeric silica, which can be used in industrial reactors. The process consists in directly mixing the suspension, resulting from the synthesis of the zeolite, with an oligomeric silica sol, obtained from the hydrolysis of a tetra-alkyl ortho silicate in the presence of tetraalkylammonium hydroxide, and in subjecting the mixture to rapid drying, by feeding to a spray-dry.
Abstract translation: 本发明涉及一种制备包含沸石和低聚二氧化硅的沸石催化剂的方法，其可用于工业反应器中。 该方法包括将由沸石合成得到的悬浮液直接与在四烷基氢氧化铵存在下由原硅酸四烷基酯水解得到的低聚硅溶胶混合并使混合物快速干燥， 通过喂食喷雾干燥。 ＆lt;图像＆GT;
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Patent Agency Ranking
公开(公告)号：KR1020010070223A
公开(公告)日：2001-07-25
申请号：KR1020000068585
申请日：2000-11-17
Applicant: 신디알 에스.피.에이.
IPC: B01J29/89
CPC classification number: B01J29/035 , B01J29/06 , B01J29/40 , B01J29/7007 , B01J29/7034 , B01J29/89 , B01J2229/40 , C01B37/00 , C01B37/02 , C01B39/026 , C07C249/04 , C07D201/04 , C07C251/44
Abstract: PURPOSE: A method of removing a casting agent from synthetic zeolite is provided. CONSTITUTION: In the method in which a casting agent is removed from synthetic zeolite, especially from silicalite, titanium silicalite, and a composite material containing zeolite, the zeolite is activated as a catalyst, and the above materials are treated by a solvent comprising 20-100mol.% of methanol, ethyl ester or methyl halides at a temperature range of 250 to 280deg.C for 0.25-72 hours in a gas phase.
Abstract translation: 目的：提供从合成沸石中除去流延剂的方法。 构成：在从合成沸石，特别是硅沸石，钛硅沸石，含有沸石的复合材料中除去铸造剂的方法中，沸石作为催化剂活化，上述物质用20- 100mol％的甲醇，乙酯或甲基卤，在250〜280℃的温度范围内，在气相中为0.25-72小时。
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公开(公告)号：KR100350255B1
公开(公告)日：2002-08-24
申请号：KR1019990048161
申请日：1999-11-02
Applicant: 신디알 에스.피.에이.
Inventor： 발두찌루이기 , 부쪼니로베르또 , 달로로레오나르도 , 데알베르티지오르다노
IPC: B01J21/12
CPC classification number: B01J35/08 , B01J29/035 , B01J29/40 , B01J29/89 , B01J37/033 , B01J2229/26 , B01J2229/32 , B01J2229/42 , C07C231/10
Abstract: 본발명은옥심의아미드로의전위반응에적합한촉매의제조방법에관한것이다. 본방법은상기반응에서실질적으로불활성인규산질리간드내에 MFI 형제올라이트의서브미크론입자를구형화(englobing)하는것으로이루어진다.
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公开(公告)号：KR1020010062071A
公开(公告)日：2001-07-07
申请号：KR1020000072514
申请日：2000-12-01
Applicant: 신디알 에스.피.에이. , 에니테크놀로지 에스.피.에이.
CPC classification number: C01B37/00 , B01J29/40 , B01J29/89 , B01J35/08 , B01J37/0045 , B01J37/0072 , B01J37/0219 , C01B39/026 , C07C231/10
Abstract: PURPOSE: A process for producing a zeolite catalyst containing zeolite and oligomeric silica which can be used in industrial reactors is provided. CONSTITUTION: The process for the preparation of zeolitic catalysts based on the rapid drying of an aqueous dispersion comprising crystalline zeolite, oligomeric silica and tetra-alkylammonium hydroxide, is characterized in that the aqueous dispersion is prepared by directly mixing the suspension resulting from the synthesis of the zeolite with an oligomeric silica sol obtained from the hydrolysis of a tetra-alkyl ortho silicate in the presence of tetra-alkylammonium hydroxide.
Abstract translation: 目的：提供可用于工业反应器中的含有沸石和低聚二氧化硅的沸石催化剂的制备方法。 构成：基于快速干燥包含结晶沸石，低聚二氧化硅和四烷基氢氧化铵的水性分散体制备沸石催化剂的方法的特征在于，水分散体通过直接混合由合成 在四烷基氢氧化铵存在下，由四烷基原硅酸盐水解获得的具有低聚二氧化硅溶胶的沸石。
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公开(公告)号：KR100393438B1
公开(公告)日：2003-08-02
申请号：KR1020000068585
申请日：2000-11-17
Applicant: 신디알 에스.피.에이.
IPC: B01J29/89
CPC classification number: B01J29/035 , B01J29/06 , B01J29/40 , B01J29/7007 , B01J29/7034 , B01J29/89 , B01J2229/40 , C01B37/00 , C01B37/02 , C01B39/026 , C07C249/04 , C07D201/04 , C07C251/44
Abstract: The present invention relates to a method for the removal of the templating agent from synthetic zeolites in general and in particular from silicalite, titanium silicalite and from composite materials containing zeolites and for their activation as catalysts. The method consists in treating the above materials with solvents in vapor phase and at a low temperature.
Abstract translation: 本发明涉及从合成沸石中，特别是从硅沸石，钛硅沸石和含沸石的复合材料中除去模板剂并将其作为催化剂活化的方法。 该方法包括用气相和低温溶剂处理上述材料。
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公开(公告)号：KR1020000035163A
公开(公告)日：2000-06-26
申请号：KR1019990048161
申请日：1999-11-02
Applicant: 신디알 에스.피.에이.
Inventor： 발두찌루이기 , 부쪼니로베르또 , 달로로레오나르도 , 데알베르티지오르다노
IPC: B01J21/12
CPC classification number: B01J35/08 , B01J29/035 , B01J29/40 , B01J29/89 , B01J37/033 , B01J2229/26 , B01J2229/32 , B01J2229/42 , C07C231/10
Abstract: PURPOSE: An MFI-type zeolite based catalyst and its preparation method are provided, which catalyst is useful for the transformation of oximes into amides. CONSTITUTION: The MFI-type zeolite based catalyst is prepared by: preparing silicate oligomer by hydrolyzing silicon alkoxide; mixing the oligomer with an aqueous or aqueous alcoholic dispersion solution of sub micro particles of MFI-type zeolite which is acidified to pH below 5; emulsifying the aqueous or aqueous alcoholic ligand/zeolite mixture in an organic solvent; contacting the emulsion with a basic solution to bind the dispersed micro drops; and washing calcining the obtained micro sphere. Preferably the MFI-type zeolite is selected from the zeolite whose mole ratio of Si/Al (or Si/B, Si/Ga, Si/In, or Si/Ti) is more than 1,000, and silicalite-1. The MFI-type zeolite based catalyst is such that the silicate ligand represented by SiO2 is more than 30 wt%, the outer surface area is 60-80 square meter per gram, the specific volumes of micro pore and mesopore are 0.2-0.3 ml/g and 0.1-0.4 ml/g, respectively, the bulk density is 0.7-0.85 g/ml, and the Davison index is less than 6.
Abstract translation: 目的：提供一种MFI型沸石基催化剂及其制备方法，该催化剂可用于将肟转化为酰胺。 构成：MFI型沸石基催化剂通过以下步骤制备：通过水解硅醇盐制备硅酸盐低聚物; 将低聚物与酸化至pH低于5的MFI型沸石的亚微米颗粒的水性或水性醇分散液混合; 在有机溶剂中乳化水性或水性醇配体/沸石混合物; 使所述乳液与碱性溶液接触以结合分散的微滴; 并洗涤煅烧所获得的微球。 优选地，MFI型沸石选自Si / Al（或Si / B，Si / Ga，Si / In或Si / Ti）的摩尔比大于1000且硅沸石-1的沸石。 MFI型沸石基催化剂使得由SiO 2表示的硅酸盐配体大于30重量％，外表面积为60-80平方米/克，微孔和中孔的比体积为0.2-0.3毫升/ g和0.1-0.4ml / g，堆积密度为0.7-0.85g / ml，Davison指数小于6。
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