公开(公告)号：KR1020000053293A

公开(公告)日：2000-08-25

申请号：KR1019997004276

申请日：1997-10-30

Applicant: 신젠타 리미티드

Inventor： 비숍나이젤더글라스 ,  어치크리스토퍼존 ,  썬리레이몬드레오 ,  샐먼로저 ,  갓프리크리스토퍼리차드에일즈 ,  루이스테렌스

IPC: C07D451/02

CPC classification number: C07D519/00 ,  A01N43/90 ,  A01N47/38

Abstract: PURPOSE: Novel bicyclic amine derivatives, processes for preparing them, insecticidal compositions comprising them and methods of using them, are provided to combat and control insect pests. CONSTITUTION: A compound of formula (I): P-R2-Q or an acid addition salt, quaternary ammonium salt or N-oxide derived therefrom, are provided. In formula (I), each of P and Q is, independently, a group of formula (B): wherein J is CH2-CH2 or CH=CH; R1 is a substituted or unsubstituted 6-membered heterocyclic ring containing only one nitrogen as the heteroatom, and at least one unsaturation (double bond) between adjacent atoms in the ring, said heterocyclic ring being optionally fused to a benzene ring, wherein the substituents, if present, are selected from halogen atoms, cyano, alkyl, alkenyl, alkynyl, alkoxy, haloalkyl, haloalkenyl, alkylthio and alkyl amino groups, any of which groups contain up to six carbon atoms; R2 is a bidentate linking group and is a substituted or unsubstituted alkylene, alkylenearyl, alkyleneheteroaryl, (wherein the heteroaryl is pyridinyl, pyrimidynyl, pyridaznyl, pyrazinyl, triazinyl (1,2,3- or 1,2,4- or 1,3,5-), furyl, thienyl, pyrrolyl, pyrazoyl, imidazolyl, triazolyl, (1,2,3- or 1,2,4-), tetrazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiadiazolyl, quinolinyl, isoquinolinyl, cinnolinyl, quinazolinyl, quinoxalinyl, indolinyl, isoindolinyl, benzofuranyl, benzothienyl or benzimidazolinyl), alkenylene, alkylenylarylalkylenyl, carbonyl or diacyl group, provided that when R2 is alkenylene or alkylenylarylalkylenyl said group does not have an unsaturated carbon atom bonding directly to the ring nitrogen of formula (B); R3 is cyano.

Abstract translation: 目的：提供新型双环胺衍生物，其制备方法，包含它们的杀虫组合物及其使用方法，以对抗和控制虫害。 构成：提供式（I）化合物：P-R2-Q或酸加成盐，季铵盐或由其衍生的N-氧化物。 在式（I）中，P和Q各自独立地是式（B）的基团：其中J是CH 2 -CH 2或CH = CH; R 1是仅含有一个氮作为杂原子的取代或未取代的6元杂环，并且环中相邻原子之间的至少一个不饱和键（双键），所述杂环任选地与苯环稠合，其中取代基， 选自卤素原子，氰基，烷基，烯基，炔基，烷氧基，卤代烷基，卤代烯基，烷硫基和烷基氨基，其中任何一个基团含有最多六个碳原子; R2是双齿连接基团，是取代或未取代的亚烷基，亚烷基硬脂基，亚烷基杂芳基（其中杂芳基是吡啶基，嘧啶基，哒嗪基，吡嗪基，三嗪基（1,2,3-或1,2,4-或1,3 ，5-），呋喃基，噻吩基，吡咯基，吡唑基，咪唑基，三唑基，（1,2,3-或1,2,4-），四唑基，恶唑基，异恶唑基，噻唑基，异噻唑基，恶二唑基，噻二唑基，喹啉基，异喹啉基 ，噌啉基，喹唑啉基，喹喔啉基，二氢吲哚基，异吲哚啉基，苯并呋喃基，苯并噻吩基或苯并咪唑啉基），亚烯基，亚烷基芳基亚烷基，羰基或二酰基，条件是当R 2是亚烯基或亚烷基芳基亚烷基时，所述基团不具有直接键合到环氮上的不饱和碳原子 的式（B）; R3是氰基。