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    농약 중간물로서 2-(피리드-2-일옥시메틸)페닐아세테이트의 제조방법
    1.
    发明授权
    농약 중간물로서 2-(피리드-2-일옥시메틸)페닐아세테이트의 제조방법 失效
    농약중물물로서2-（-2-리드-2-일옥시메틸）페닐아세테이트의제조방농

    公开(公告)号：KR100406474B1

    公开(公告)日：2004-03-24

    申请号：KR1019980702497

    申请日：1996-09-24

    Applicant: 신젠타 리미티드

    Inventor： 윌리엄스알프레드글린 ,  문스고든리차드 ,  워딩튼폴앤서니

    IPC: C07D213/64

    CPC classification number: C07D213/64 ,  C07C59/48

    Abstract: PCT No. PCT/GB96/02337 Sec. 371 Date Feb. 19, 1998 Sec. 102(e) Date Feb. 19, 1998 PCT Filed Sep. 24, 1996 PCT Pub. No. WO97/12864 PCT Pub. Date Apr. 10, 1997The invention relates to a process for the preparation of 2-(pyrid-2-yloxymethyl)phenylacetates of formula (I) useful as intermediates for agricultural pesticides, which comprises reacting a 2-pyridine of formula (II), wherein L is a leaving group and A, D and m are as defined in the description with a compound MO-CH2R where M is a metal atom and R is the residue of a metal salt of phenylacetic acid. It also includes the compounds MO-CH2R, a process for their preparation and a "one-pot" process for the preparation of 2-(pyrid-2-yloxymethyl) phenylacetates from 3-isochromanone.

    Abstract translation: PCT No.PCT / GB96 / 02337 Sec。 371日期1998年2月19日 102（e）日期1998年2月19日PCT归档1996年9月24日PCT Pub。 WO97 / 12864 PCT Pub。 日期1997年4月10日本发明涉及制备可用作农业农药中间体的式（I）2-（吡啶-2-基氧基甲基）苯基乙酸酯的方法，该方法包括使式（II）的2-吡啶， 其中L是离去基团，A，D和m如说明书中对化合物MO-CH2R所定义，其中M是金属原子，R是苯乙酸金属盐的残基。 它还包括化合物MO-CH 2 R，它们的制备方法和“一锅法” 由3-异苯并二氢吡喃酮制备2-（吡啶-2-基氧基甲基）苯基乙酸酯的方法。

    농약 중간물로서 2-(피리드-2-일옥시메틸)페닐아세테이트의 제조방법
    2.
    发明公开
    농약 중간물로서 2-(피리드-2-일옥시메틸)페닐아세테이트의 제조방법 失效
    生产2-（吡啶-2-基氧基甲基）苯乙酸酯作为农药中间体的方法

    公开(公告)号：KR1019990064020A

    公开(公告)日：1999-07-26

    申请号：KR1019980702497

    申请日：1996-09-24

    Applicant: 신젠타 리미티드

    Inventor： 윌리엄스알프레드글린 ,  문스고든리차드 ,  워딩튼폴앤서니

    IPC: C07D213/64

    Abstract: 본 발명은 화학식(2)(식중, L은 이탈그룹이고 A, D 및 m은 명세서에서 정의한 바와 같음)의 2-피리딘을 화합물 MO-CH
    2 R(M은 금속 원자이고 R은 2-페닐아세트산의 금속염 잔기임)와 반응시키는 것을 포함하는, 농약 중간물로 유용한 화학식(1)의 2-(피리드-2-일옥시메틸)페닐 아세테이트의 제조방법에 관한다. 또한 본 발명은 화합물 MO-CH
    2 R, 이의 제조방법 및 3-이소크로마논으로부터2-(피리드-2-일옥시메틸)페닐 아세테이트를 제조하는 "원-포트" 방법을 포함한다.
    [화학식 1]

    [화학식 2]

    플루오르화 방법
    4.
    发明公开
    플루오르화 방법 无效
    荧光法

    公开(公告)号：KR1020000076122A

    公开(公告)日：2000-12-26

    申请号：KR1019997008211

    申请日：1997-03-11

    Applicant: 신젠타 리미티드

    Inventor： 윌리엄스알프레드글린

    IPC: C07C17/20

    Abstract: 본발명은 1,1,1,4-테트라클로로부탄또는 1,1,4-트리클로로부트-1-엔과증기상플루오르화수소를반응시키는것을포함하는 1,1-디플루오로-1,4-디클로로부탄을제조하는방법에관한다. 이생성물은유용한용매특성을가지며또한플루오로카본관능의도입을위한합성화학에서유용하다.

    3-이소크로마논을제조하는방법
    6.
    发明公开
    3-이소크로마논을제조하는방법 失效
    制备3-异丙基酮的方法

    公开(公告)号：KR1020000016708A

    公开(公告)日：2000-03-25

    申请号：KR1019980710315

    申请日：1997-05-21

    Applicant: 신젠타 리미티드

    Inventor： 존스,레이몬드,빈센트히본 ,  스탠든마이클찰스헨리 ,  윌리엄스알프레드글린 ,  포스터니콜라스러셀

    IPC: C07D311/20

    CPC classification number: C07D311/76

    Abstract: PURPOSE: A preparation method of 3-isochromanone by reacting o-tolyacetic acid with sulfuryl chloride and treating obtained 2-chloromethylphenylacetic acid with a base is provided which is useful as an intermediate for manufacturing a germicide. CONSTITUTION: 3-Isochromanone is prepared by reacting o-tolyacetic acid with sulfuryl chloride in the presence of a free radical initiator, e.g. AIBN, followed by ring closure of the 2-chlorometylphenylacetic acid so formed with a base, e.g. potassium bicarbonate. For an example, 750g o-tolyacetic acid and 1323ml fluorobenzene are reacted and mixed under an atmosphere of nitrogen and reacted with 11.3g AIBN and 680.3g sulfuryl chloride at 80°C for 1 hr. The reactant is added with 908g saturated potassium bicarbonate and 3.3g potassium iodide to give 453.7g 3-isochromanone(yield:60.4%).

    Abstract translation: 目的：提供3-邻异色酮的制备方法，通过邻甲苯乙酸与磺酰氯反应，并用碱处理得到的2-氯甲基苯基乙酸，可用作制造杀菌剂的中间体。 构成：3-异色满酮是通过在自由基引发剂存在下，使邻苯二甲酸与磺酰氯反应来制备的。 AIBN，然后用碱形成的2-氯甲基苯基乙酸闭环， 碳酸氢钾 例如，将750g邻苯二甲酸和1323ml氟苯在氮气氛下反应并混合，并与11.3g AIBN和680.3g磺酰氯在80℃反应1小时。 向反应物中加入908g饱和碳酸氢钾和3.3g碘化钾，得到453.7g 3-异色满酮（产率：60.4％）。

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