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    불투명한 미세기공 축방향 연신 필름, 이의 제조방법 및 이에 투명한 패턴을 얻기위한 방법
    3.
    发明公开
    불투명한 미세기공 축방향 연신 필름, 이의 제조방법 및 이에 투명한 패턴을 얻기위한 방법 有权
    非透明微晶轴向拉伸薄膜，其生产工艺及其获取透明图案的方法

    公开(公告)号：KR1020090093945A

    公开(公告)日：2009-09-02

    申请号：KR1020097009170

    申请日：2007-09-26

    Applicant: 아그파-게바에르트 엔.브이.

    Inventor： 꾸앵땅디르크 ,  린데루끄

    IPC: C08J5/18

    CPC classification number: G03C1/7954 ,  B29C55/06 ,  B29C55/143 ,  B29K2033/18 ,  B29K2067/00 ,  B29K2105/0032 ,  B29K2105/0088 ,  B29K2105/04 ,  B29K2711/12 ,  B29K2995/0025 ,  B41M5/36 ,  B41M5/41 ,  B41M5/508 ,  B41M2205/02 ,  B41M2205/12 ,  C08J5/18 ,  C08J2367/02 ,  C08K3/013 ,  C08L25/12 ,  C08L67/02 ,  Y10S430/165 ,  Y10T156/10 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/249953 ,  Y10T428/249978 ,  Y10T428/249992 ,  Y10T428/254 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L2666/06 ,  C08L35/00 ,  C08L25/00

    Abstract: A film consisting essentially of a continuous phase linear polyester matrix having dispersed therein a non-crosslinked random SAN-polymer and dispersed or dissolved therein at least one ingredient from the group of ingredients consisting of inorganic opacifying pigments, whitening agents, colorants, UV-absorbers, light stabilizers, antioxidants and flame retardants, wherein the film is white, microvoided, non-transparent and axially stretched; the linear polyester matrix has monomer units consisting essentially of at least one aromatic dicarboxylic acid, at least one aliphatic diol and optionally at least one aliphatic dicarboxylic acid; the weight ratio of the linear polyester to the non-crosslinked SAN-polymer is in the range of 2.0:1 to 19.0:1; and one of said at least one aromatic dicarboxyate monomer units is isophthalate and said isophthalate is present in said polyester matrix in a concentration of 15 mole % or less of all the dicarboxylate monomer units in said linear polyester matrix; the use of the non-transparent microvoided axially stretched film as a synthetic paper; an image recording element comprising the non-transparent microvoided axially stretched film; a process for the preparing of the non-transparent microvoided axially stretched film; and a process for obtaining a transparent pattern therewith.

    Abstract translation: 基本上由连续相线性聚酯基质组成的薄膜，其中分散有非交联的随机SAN聚合物，并且分散或溶解于由无机遮光颜料，增白剂，着色剂，UV吸收剂组成的组中的至少一种成分 光稳定剂，抗氧化剂和阻燃剂，其中该膜是白色，微孔，不透明和轴向拉伸; 线性聚酯基质具有基本上由至少一种芳族二羧酸，至少一种脂族二醇和任选的至少一种脂族二羧酸组成的单体单元; 线性聚酯与非交联SAN聚合物的重量比在2.0:1至19.0:1的范围内; 所述至少一种芳族二羧酸酯单体单元之一为间苯二甲酸酯，所述间苯二甲酸酯以所述线性聚酯基质中所有二羧酸单体单元的15摩尔％以下的浓度存在于所述聚酯基质中; 使用非透明微孔轴向拉伸膜作为合成纸; 图像记录元件，包括所述非透明微孔轴向拉伸膜; 用于制备不透明微孔轴向拉伸膜的方法; 以及用于获得透明图案的处理。

    불투명 미세기공 자가-지지성 필름의 제조 방법
    5.
    发明公开
    불투명 미세기공 자가-지지성 필름의 제조 방법 有权
    生产非透明微胶囊自支撑膜的方法

    公开(公告)号：KR1020090077941A

    公开(公告)日：2009-07-16

    申请号：KR1020097009169

    申请日：2007-10-01

    Applicant: 아그파-게바에르트 엔.브이.

    Inventor： 꾸앵땅디르크

    IPC: C08J5/18 ,  C08L67/03 ,  G03C1/795 ,  B41M5/41

    CPC classification number: G03C1/7954 ,  B29C55/06 ,  B29C55/143 ,  B29K2033/18 ,  B29K2067/00 ,  B29K2105/0032 ,  B29K2105/0088 ,  B29K2105/04 ,  B29K2711/12 ,  B29K2995/0025 ,  B41M5/36 ,  B41M5/41 ,  B41M5/508 ,  B41M2205/02 ,  B41M2205/12 ,  C08J5/18 ,  C08J2367/02 ,  C08K3/013 ,  C08L25/12 ,  C08L67/02 ,  Y10S430/165 ,  Y10T156/10 ,  Y10T428/24802 ,  Y10T428/24893 ,  Y10T428/249953 ,  Y10T428/249978 ,  Y10T428/249992 ,  Y10T428/254 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L2666/06 ,  C08L35/00 ,  C08L25/00

    Abstract: A process for producing a non-transparent microvoided self-supporting film comprising the steps of: i) mixing at least one linear polyester having together monomer units consisting essentially of terephthalate, isophthalate and aliphatic dimethylene with the molar ratio of isophthalate monomer units to terephthalate monomer units being at least 0.02 to provide a linear polyester matrix; at least one amorphous high polymer with a higher glass transition temperature than the glass transition temperature of said linear polyester matrix and/or at least one crystalline high polymer having a higher melting point than the glass transition temperature of said linear polyester matrix; and optionally at least one ingredient from the group of ingredients consisting of inorganic opacifying pigments, whitening agents, UV-absorbers, light stabilizers, antioxidants, flame retardants and colorants in a kneader or an extruder; ii) forming the mixture produced in step i) in a thick film followed by quenching; iii) longitudinally stretching the thick film at a stretching force of >4 N/mm2 to at least twice the initial length; and iv) transversly stretching the longitudinally stretched film from step (iii) to at least twice the initial width; the use of the non-transparent microvoided axially stretched film produced according to the above-described process as a synthetic paper; and the use of the non-transparent microvoided axially stretched film produced according to the above-described process image recording elements.

    Abstract translation: 一种制造不透明的微孔自支撑膜的方法，包括以下步骤：i）将至少一种线性聚酯与单体单元的单体单元与对苯二甲酸酯单体的摩尔比混合在一起的基本上由对苯二甲酸酯，间苯二甲酸酯和脂肪族二亚甲基组成的单体单元 单元为至少0.02以提供线性聚酯基质; 至少一种具有比所述线性聚酯基质的玻璃化转变温度高的玻璃化转变温度和/或具有比所述线性聚酯基体的玻璃化转变温度更高的熔点的至少一种结晶高分子的至少一种无定形高分子; 和任选的至少一种成分，由捏合机或挤出机中的无机遮光颜料，增白剂，紫外线吸收剂，光稳定剂，抗氧化剂，阻燃剂和着色剂组成的成分组成; ii）在厚膜中形成步骤i）中制备的混合物，随后淬火; iii）以> 4N / mm 2的拉伸力纵向拉伸厚膜至初始长度的至少两倍; 和iv）将从步骤（iii）的纵向拉伸膜横向拉伸至初始宽度的至少两倍; 使用根据上述方法制造的非透明微孔轴向拉伸膜作为合成纸; 以及使用根据上述处理图像记录元件制造的非透明微孔轴向拉伸膜。

    불투명한 미세기공 2축 연신 필름, 합성지에서의 이의 용도 및 이를 포함하는 화상 기록 소자
    7.
    发明公开
    불투명한 미세기공 2축 연신 필름, 합성지에서의 이의 용도 및 이를 포함하는 화상 기록 소자 有权
    非透明微型双向拉伸膜，其在合成纸中的使用和包含其的图像记录元件

    公开(公告)号：KR1020100015931A

    公开(公告)日：2010-02-12

    申请号：KR1020097022381

    申请日：2008-03-18

    Applicant: 아그파-게바에르트 엔.브이.

    Inventor： 꾸앵땅디르크 ,  브리피터

    IPC: C08J9/22 ,  C08J5/18 ,  C08L23/20 ,  G03G7/00

    CPC classification number: G03C1/7954 ,  B29C55/005 ,  B29K2067/00 ,  B29K2105/04 ,  B29K2105/16 ,  B41M3/14 ,  B42D25/29 ,  C08L67/02 ,  Y10T428/24992 ,  Y10T428/249953 ,  Y10T428/249978 ,  Y10T428/254 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L25/00 ,  C08L35/00

    Abstract: A non-transparent microvoided biaxially stretched self-supporting non-laminated polymeric film, the film comprising linear polyester as a continuous phase and dispersed uniformly therein an amorphous high polymer comprising at least one chain-polymerized block with a higher glass transition temperature than the glass transition temperature of the continuous phase and isotactic poly (4-methyl-1-pentene), wherein the linear polyester consists essentially of aromatic dicarboxylate and aliphatic dimethylene monomer units, wherein the combined concentration of the uniformly dispersed amorphous high polymer and isotactic poly (4-methyl-1-pentene) in the film is 5 to 35% by weight; the use of the above-described non-transparent microvoided biaxially stretched film in synthetic paper; an image recording element comprising the above-described non-transparent microvoided biaxially stretched film; and a process for producing a transparent pattern comprising the step of : image-wise application of heat optionally supplemented by the application of pressure to the above-described non-transparent microvoided biaxially stretched film.

    Abstract translation: 不透明微孔双轴拉伸自支撑非层压聚合物膜，该膜包含线性聚酯作为连续相并均匀分散在其中，包含至少一个玻璃化转变温度高于玻璃的链聚合嵌段的无定形高聚物 连续相和全同立构聚（4-甲基-1-戊烯）的转变温度，其中线性聚酯基本上由芳族二羧酸酯和脂族二亚甲基单体单元组成，其中均匀分散的无定形高分子和全同立构聚（4 - 甲基-1-戊烯）为5〜35重量％ 在合成纸中使用上述非透明微孔双轴拉伸膜; 包括上述非透明微孔双轴拉伸膜的图像记录元件; 以及用于制造透明图案的方法，包括以下步骤：将任选地通过施加压力的热量的图像方式施加到上述非透明微孔双轴拉伸膜。

    불투명한 미세기공 축방향 연신 필름, 이의 제조방법 및 이로 투명한 패턴을 수득하는 방법
    8.
    发明公开
    불투명한 미세기공 축방향 연신 필름, 이의 제조방법 및 이로 투명한 패턴을 수득하는 방법 无效
    非透明微晶轴向拉伸薄膜，其生产工艺及其获取透明图案的方法

    公开(公告)号：KR1020090125844A

    公开(公告)日：2009-12-07

    申请号：KR1020097022389

    申请日：2008-03-26

    Applicant: 아그파-게바에르트 엔.브이.

    Inventor： 꾸앵땅디르크 ,  브리피터

    IPC: C08J5/18 ,  C08L67/02 ,  G03C1/795 ,  B41M5/41

    CPC classification number: G03C1/7954 ,  B29C55/005 ,  B29K2067/00 ,  B29K2105/04 ,  B29K2105/16 ,  B41M3/14 ,  B42D25/29 ,  C08L67/02 ,  Y10T428/24992 ,  Y10T428/249953 ,  Y10T428/249978 ,  Y10T428/254 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L25/00 ,  C08L35/00

    Abstract: A film consisting essentially of a continuous phase linear polyester matrix having dispersed therein a non-crosslinked random SAN-polymer and dispersed or dissolved therein at least one ingredient from the group of ingredients consisting of inorganic opacifying pigments, whitening agents, colorants, UV-absorbers, light stabilizers, antioxidants and flame retardants, wherein the film is white, microvoided, non-transparent and axially stretched; the linear polyester matrix has monomer units consisting essentially of at least one aromatic dicarboxylic acid, at least one aliphatic diol and optionally at least one aliphatic dicarboxylic acid; and the weight ratio of the linear polyester to the non-crosslinked SAN-polymer is in the range of 2.0:1 to 19.0:1, wherein one of the said at least one aliphatic dimethylene monomer units is selected from the group consisting of neopentylene and 1, 4-cyclohexanedimethylene in a concentration of 30 mole % or less of all aliphatic dimethylene monomer units; the use of the film as or in synthetic paper; an image recording element comprising the film; a process for the preparing of the non-transparent microvoided axially stretched film; and a process for obtaining a transparent pattern therewith.

    Abstract translation: 基本上由连续相线性聚酯基质组成的薄膜，其中分散有非交联的随机SAN聚合物，并且分散或溶解于由无机遮光颜料，增白剂，着色剂，UV吸收剂组成的组中的至少一种成分 光稳定剂，抗氧化剂和阻燃剂，其中该膜是白色，微孔，不透明和轴向拉伸; 线性聚酯基质具有基本上由至少一种芳族二羧酸，至少一种脂族二醇和任选的至少一种脂族二羧酸组成的单体单元; 并且线性聚酯与非交联SAN聚合物的重量比在2.0:1至19.0:1的范围内，其中所述至少一种脂族二亚甲基单体单元之一选自新戊烯和 所有脂族二亚甲基单体单元的浓度为30摩尔％以下的1,4-环己烷二亚甲基; 使用胶片或合成纸; 包括该膜的图像记录元件; 用于制备不透明微孔轴向拉伸膜的方法; 以及用于获得透明图案的处理。

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