公开(公告)号：KR1020120060980A

公开(公告)日：2012-06-12

申请号：KR1020100095759

申请日：2010-10-01

Applicant: 유한회사 피피지코리아

Inventor： 남준현 ,  김동간 ,  박찬남 ,  한종희 ,  정호철 ,  박경민

IPC: C08L83/04 ,  C08L33/04 ,  C08F20/20 ,  C09D5/18

Abstract: PURPOSE: A manufacturing method of organic silane and phosphate ester copolymer resin is provided to manufacture a thermosetting flame retardant pigment with high clearness and effectively improved toxicity of combustion gas in halogen based flame retardant paint. CONSTITUTION: A solution-polymerizable acrylic polyol resin composition comprises 40-70 weight% of copolymer of phosphor-silane monomers, and 30-60 weight% of organic solvent. The copolymer of the acrylic monomer is 30.0-60.0 weight% of an organosilane monomer, and 40.0-70.0 weight% of a phosphate ester monomer. The phosphate-silane acrylic resin composition has non-volatile fraction of 40-70%, a Gardner bubble viscosity of U - Z6, the acid value of 0-20 mg/KOH, and the color value of 3 or less. The phosphate ester is 1 phosphate (meth)acrylate compound comprising ethylenically unsaturated double bond in chemical formula 1.

Abstract translation: 目的：提供有机硅烷和磷酸酯共聚物树脂的制造方法，以制造具有高清晰度并有效提高燃烧气体在卤素阻燃涂料中的毒性的热固性阻燃颜料。 构成：可溶液聚合的丙烯酸多元醇树脂组合物包含40-70重量％的荧光体 - 硅烷单体和30-60重量％的有机溶剂的共聚物。 丙烯酸类单体的共聚物为有机硅烷单体的30.0〜60.0重量％，磷酸酯单体为40.0〜70.0重量％。 磷酸酯 - 硅烷丙烯酸树脂组合物的非挥发分为40-70％，加德纳气泡粘度为U-Z6，酸值为0-20mg / KOH，颜色值为3以下。 磷酸酯是化学式1中含有烯键式不饱和双键的磷酸酯（甲基）丙烯酸酯化合物。