公开(公告)号：KR100875371B1

公开(公告)日：2008-12-22

申请号：KR1020070050842

申请日：2007-05-25

Applicant: 재단법인서울대학교산학협력재단

Inventor： 김현중 ,  김희수 ,  이병호

IPC: C08L101/16 ,  C08L1/00 ,  C08L69/00

Abstract: A bio-composites with improved mechanical properties is provided to suppress hydrolysis progressing due to high temperature and/or the moisture in the manufacture of the bio composites containing a biodegradable polymer and to maintain the property in high temperature and high humidity environment. A bio-composites with improved mechanical properties comprises a main material consisting of a biodegradable polymer and a cellulose based-natural matter; and 0.1-50 weight% of an antihydrotic agent. The biodegradable polymer is a polybutylene succinate(PBS), polybutylene succinate adipate(PBSA) or polylactic acid(PLA).

Abstract translation: 提供具有改进的机械性能的生物复合材料，以抑制由于制造含有生物可降解聚合物的生物复合材料时的高温和/或水分而导致的水解进展，并保持高温高湿环境下的性能。 具有改进的机械性能的生物复合材料包含由可生物降解的聚合物和基于纤维素的天然物质组成的主要材料; 和0.1-50重量％的抗水剂。 生物可降解聚合物是聚琥珀酸丁二醇酯（PBS），聚丁二酸丁二醇酯己二酸酯（PBSA）或聚乳酸（PLA）。

公开(公告)号：KR100870597B1

公开(公告)日：2008-11-25

申请号：KR1020070078305

申请日：2007-08-03

Applicant: 재단법인서울대학교산학협력재단

Inventor： 김현중 ,  이병호 ,  김희수

IPC: B29C70/12 ,  B29C70/10 ,  B29C43/02

CPC classification number: B29C70/10 ,  B29C70/465 ,  B29K2995/006

Abstract: A method for manufacturing polylactic acid bio composite material is provided to produce a polylactic acid bio composite material by adopting a compression molding using a carding process. A method for manufacturing polylactic acid bio composite material comprises a step for preparing the web by blending fabric through a carding process by selecting substrate polymer the polylactic acid(PLA) fiber and natural fiber as reinforcing material; a step for making the mat by pre-loading the web; and a step for manufacturing by compressing and molding the bio composite plate mat. In a step for preparing web, the web is prepared by replacing some of polylactic acid fiber with the polypropylene fiber. The replaced polypropylene fiber forms 15~35 weight% among the web total weight.

Abstract translation: 提供聚乳酸生物复合材料的制造方法，通过采用使用梳理法的压缩成型制造聚乳酸生物复合材料。 制造聚乳酸生物复合材料的方法包括通过梳理方法通过将聚乳酸（PLA）纤维和天然纤维作为增强材料选择基质聚合物来混合织物来制备网的步骤; 通过预加载网来制作垫子的步骤; 以及通过压缩和模制生物复合板垫来制造的步骤。 在制备网的步骤中，通过用聚丙烯纤维代替一些聚乳酸纤维来制备网。 取代的聚丙烯纤维在纤维网总重量中形成15〜35重量％。

公开(公告)号：KR100801443B1

公开(公告)日：2008-02-11

申请号：KR1020060123473

申请日：2006-12-07

Applicant: 재단법인서울대학교산학협력재단

Inventor： 송인규 ,  김희수 ,  정지철

IPC: B01J31/18 ,  B01J27/24 ,  B01J21/18 ,  B82Y30/00

CPC classification number: B01J27/24 ,  B01J21/18 ,  B01J31/18 ,  B01J35/04 ,  B01J37/00

Abstract: A heteropoly acid catalyst immobilized onto nitrogen-containing mesoporous carbon is provided to form a cationic functional group in mesoporous carbon simply and efficiently as compared with a conventional method, a preparation method the catalyst is provided, and a preparation method of methacrylic acid using the catalyst is provided to maximize production of methacrylic acid by maximizing a surface type oxidation reaction of the heteropoly acid catalyst in the conversion reaction of methacrolein using the heteropoly acid catalyst. A heteropoly acid catalyst immobilized onto nitrogen-containing mesoporous carbon is characterized in that: the heteropoly acid catalyst is used in an acid catalytic reaction or an oxidation reduction catalytic reaction; and the heteropoly acid catalyst is immobilized onto the nitrogen-containing mesoporous carbon through chemical bonding by hydrogenating nitrogen-containing mesoporous carbon having an average pore size ranging from 2 to 1000 nm to convert the nitrogen into an amine group(-NR1R2R3^+) and by reacting the amine group with a heteropoly acid catalyst, wherein R1, R2 and R3, each independently is hydrogen or an alkyl group having 1 to 20 carbon atoms. The nitrogen-containing mesoporous carbon is prepared by using carbon molecular sieve as a porous carbonaceous material and using spherical or nano-structured silica or nano-structured inorganic compound as a template.

Abstract translation: 提供固定在含氮介孔碳上的杂多酸催化剂，与常规方法相比，简单有效地形成阳离子官能团，提供催化剂的制备方法和使用催化剂的甲基丙烯酸的制备方法 被提供以通过使用杂多酸催化剂在异丁烯醛的转化反应中使杂多酸催化剂的表面型氧化反应最大化来最大化甲基丙烯酸的产生。 固定在含氮介孔碳上的杂多酸催化剂的特征在于：所述杂多酸催化剂用于酸催化反应或氧化还原催化反应; 并通过化学键合将杂多酸催化剂固定在含氮介孔碳上，氢化含有平均孔径为2〜1000nm的含氮介孔碳，将氮转化成胺基（-NR1R2R3 +）和 通过使胺基与杂多酸催化剂反应，其中R 1，R 2和R 3各自独立地是氢或具有1至20个碳原子的烷基。 通过使用碳分子筛作为多孔碳质材料并使用球形或纳米结构的二氧化硅或纳米结构的无机化合物作为模板来制备含氮介孔碳。

公开(公告)号：KR1020090104170A

公开(公告)日：2009-10-06

申请号：KR1020080029463

申请日：2008-03-31

Applicant: 재단법인서울대학교산학협력재단

Inventor： 송인규 ,  윤민혜 ,  서정길 ,  김희수 ,  정지철 ,  박동률

IPC: B01J23/755 ,  B01J21/06 ,  C01B3/38 ,  C01B3/26

CPC classification number: Y02P20/52 ,  B01J23/755 ,  B01J21/066 ,  B01J37/0009 ,  B01J37/036 ,  C01B3/38

Abstract: PURPOSE: A nickel catalyst and a manufacturing method thereof are provided to offer very stable catalytic activity for a long time, and to manufacture hydrogen gas of high concentration by ethanol autothermal reforming reaction. CONSTITUTION: A nickel catalyst supported on mesoporous zirconia is used for manufacturing hydrogen by autothermal reforming reaction of ethanol. The catalyst uses a block copolymer or a cationic surfactant as a mold. In the catalyst, the nickel of 1 ~ 50 weight parts is supported on a zirconia carrier of 100 weight parts. The zirconia carrier having a mesopore is manufactured by a thermo-polymerization method.

Abstract translation: 目的：提供镍催化剂及其制造方法，能够长时间提供非常稳定的催化活性，并通过乙醇自热重整反应制备高浓度的氢气。 构成：通过乙醇的自热重整反应，使用负载在介孔氧化锆上的镍催化剂来制造氢。 催化剂使用嵌段共聚物或阳离子表面活性剂作为模具。 在催化剂中，1〜50重量份的镍负载在100重量份的氧化锆载体上。 具有中孔的氧化锆载体通过热聚合法制造。

公开(公告)号：KR1020080103734A

公开(公告)日：2008-11-28

申请号：KR1020070050842

申请日：2007-05-25

Applicant: 재단법인서울대학교산학협력재단

Inventor： 김현중 ,  김희수 ,  이병호

IPC: C08L101/16 ,  C08L1/00 ,  C08L69/00

Abstract: A bio-composites with improved mechanical properties is provided to suppress hydrolysis progressing due to high temperature and/or the moisture in the manufacture of the bio composites containing a biodegradable polymer and to maintain the property in high temperature and high humidity environment. A bio-composites with improved mechanical properties comprises a main material consisting of a biodegradable polymer and a cellulose based-natural matter; and 0.1-50 weight% of an antihydrotic agent. The biodegradable polymer is a polybutylene succinate(PBS), polybutylene succinate adipate(PBSA) or polylactic acid(PLA).

Abstract translation: 提供了具有改善的机械性质的生物复合材料，以抑制由于在含有可生物降解的聚合物的生物复合材料的制造中的高温和/或水分导致的水解进程并且保持在高温和高湿度环境中的性质。 具有改善的机械性能的生物复合材料包括由可生物降解的聚合物和基于纤维素的天然物质组成的主要材料; 和0.1-50重量％的抗水解剂。 生物可降解聚合物是聚丁二酸丁二醇酯（PBS），聚丁二酸丁二醇酯己二酸酯（PBSA）或聚乳酸（PLA）。

公开(公告)号：KR100869445B1

公开(公告)日：2008-11-18

申请号：KR1020070104824

申请日：2007-10-18

Applicant: 재단법인서울대학교산학협력재단

Inventor： 송인규 ,  김희수 ,  정지철 ,  박동률 ,  라경원 ,  이주형 ,  이상희

IPC: C07C31/20 ,  C07C31/18

Abstract: A method for manufacturing dimethoxymethane is provided to increase the production of dimethoxymethane due to the property of acid existing within a catalyst and to improve the oxidation reaction property in the methanol transformation reaction, compared with a unsupported catalyst by introducing a cation functional group to the mesopore carbon containing nitrogen and using a heteropolyacid catalyst. A method for manufacturing dimethoxymethane comprises a step for passing through the intermediate of dimethoxymethane by an acid-catalyzed reaction and a consecutive oxidation reaction of methanol or producing formaldehyde by the direct oxidation reaction of methanol; a step for preparing methoxymethanol by the acid catalytic reaction between the formaldehyde and methanol; a step for preparing dimethoxymethane by the acid catalytic reaction between methoxymethanol and methanol. In the chemical reaction, the heteropolyacid catalyst which can perform a Bi-functional catalyst of the acid catalytic reaction and oxidation reaction at the same time is used. The heteropolyacid catalyst is fixed to a mesopore carbon containing nitrogen having the average pore size of 2-50nm.

Abstract translation: 提供了制造二甲氧基甲烷的方法，由于通过在阳离子官能团中引入阳离子官能团，与催化剂相比，由于存在于催化剂内的酸的性质，提高了甲醇转化反应中的氧化反应性，从而提高了二甲氧基甲烷的生成 含氮的氮和使用杂多酸催化剂。 制备二甲氧基甲烷的方法包括通过酸催化反应和甲醇的连续氧化反应或通过甲醇的直接氧化反应产生甲醛来通过二甲氧基甲烷的中间体的步骤; 通过甲醛和甲醇之间的酸催化反应制备甲氧基甲醇的步骤; 通过甲氧基甲醇和甲醇之间的酸催化反应制备二甲氧基甲烷的步骤。 在化学反应中，使用能够同时进行酸催化反应和氧化反应的双功能催化剂的杂多酸催化剂。 将杂多酸催化剂固定在平均孔径为2-50nm的含有氮的中孔碳上。

公开(公告)号：KR100943832B1

公开(公告)日：2010-02-25

申请号：KR1020080029463

申请日：2008-03-31

Applicant: 재단법인서울대학교산학협력재단

Inventor： 송인규 ,  윤민혜 ,  서정길 ,  김희수 ,  정지철 ,  박동률

IPC: B01J23/755 ,  B01J21/06 ,  C01B3/38 ,  C01B3/26

CPC classification number: Y02P20/52

Abstract: 본 발명은 중형기공 지르코니아에 담지된 니켈 촉매, 그 제조방법 및 상기 촉매를 이용한 에탄올의 자열개질반응에 의한 수소 제조방법에 관한 것으로서, 보다 상세하게는 에탄올의 자열개질반응에 의한 수소제조에 사용되는 촉매에 있어서, 상기 촉매는 블록 공중합체 또는 양이온성 계면활성제를 주형으로 하고 지르코늄 전구체를 졸-겔법에 의해 수화 및 축합한 후 수열중합법에 의해 제조된 중형기공을 갖는 지르코니아 담체 100중량부에 대해 1 내지 50중량부 범위의 니켈이 담지된 것을 특징으로 하는 중형기공을 갖는 지르코니아 담체에 담지된 니켈촉매, 그 제조방법 및 상기 촉매를 이용한 에탄올의 자열개질반응(Autothermal Reforming)에 의한 수소 제조방법에 관한 것이다. 본 발명은 양이온성 계면활성제 또는 블록공중합체를 주형으로 하여 수열합성에 의해 중형 기공을 갖는 지르코니아를 담체를 제조하고 상기 담체에 니켈 촉매를 담지한 형태의 촉매를 제공하여, 이를 에탄올 자열 개질반응을 통한 수소제조 공정에 이용할 경우 활성금속 성분인 니켈을 고분산시켜 탄소침적과 소결현상이 완화되어 장시간 높은 활성을 유지하고, 수소 생산량을 증가시킬 수 있다.
중형 기공 지르코니아, 니켈촉매, 에탄올, 자열개질반응, 수소

公开(公告)号：KR100770158B1

公开(公告)日：2007-10-25

申请号：KR1020060060416

申请日：2006-06-30

Applicant: 재단법인서울대학교산학협력재단

Inventor： 송인규 ,  김희수 ,  정지철

IPC: C08F4/02 ,  C08F4/00 ,  C08F20/06 ,  B82B3/00

CPC classification number: C07C49/08 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01J37/0201 ,  B01J37/0236 ,  C07C57/04 ,  C07F9/005 ,  C07F11/005

Abstract: A supported heteropolyacid catalyst immobilized on mesoporous carbon is provided to allow firm chemical bonding between a heteropolyacid catalyst and mesoporous carbon, to activate properties as an oxidation catalyst, and to increase the selectivity during a catalytic reaction, particularly for preparing a methacrylic acid. A supported heteropolyacid catalyst immobilized on mesoporous carbon is obtained by immobilizing at least one anionic heteropolyacid selected from the group consisting of (a) Keggin type heteropolyacids including 12-molybdophosphoric acid(H3PMo12O40), 12-tungstophosphoric acid(H3PW12O40), 12-tungstosilicic acid(H4SiW12O40), 12-molybdotungstophosphoric acid(H3PMo12-xWxO40, x=0-12), 12-molybdovanadophosphoric acid(H3+xPMo12-xVxO40, x=0-12) and 12-tungstovanadophosphoric acid(H3+xPW12-xVxO40, x=0-12), and (b) Wells-Dawsons type heteropolyacids including 18-molybdophosphoric acid(H6P2Mo18O62), 18-tungstophosphoric acid(H6P2W18O62), 18-molybdotungstophosphoric acid(H6P2Mo18-xWxO62, x=0-18), 18-molybdovanadophosphoric acid(H6+xP2Mo18-xVxO62, x=0-18), 18-tungstovanadophosphoric acid(H6+xP2W18-xVxO62, x=0-18) and 18-tungstoneobiumphosphoric acid(H6+xP2W18-xNbxO62, x=0-18) to mesoporous carbon having cationic functional groups attached to the surface thereof through a chemical bonding.

Abstract translation: 提供了固定在中孔碳上的负载型杂多酸催化剂，以使杂多酸催化剂和介孔碳之间的牢固化学键合活化作为氧化催化剂的性能，并提高催化反应中的选择性，特别是用于制备甲基丙烯酸。 固定在介孔碳上的负载型杂多酸催化剂是通过将至少一种选自（a）包括12-钼磷酸（H3PMo12O40），12-钨磷酸（H3PW12O40），12-钨磷酸（H3PW12O40）），12-钨硅酸的Keggin型杂多酸 （H 4 SiW 12 O 40），12-钼钨磷酸（H3PMo12-xWxO40，x = 0-12），12-钼钒酸（H3 + xPMo12-xVxO40，x = 0-12）和12-钨钨磷酸（H3 + xPW12-xVxO40，x = 0-12），（b）包含18-钼磷酸（H6P2Mo18O62），18-钨磷酸（H6P2W18O62），18-钼钨磷酸（H6P2Mo18-xWxO62，x = 0-18），18-钼磷酸 钼钨钒酸（H6 + xP2Mo18-xVxO62，x = 0-18），18-钨钒酸（H6 + xP2W18-xVxO62，x = 0-18）和18-钨磷钨酸（H6 + xP2W18-xNbxO62，x = 0-18 ）与具有通过化学键合附着于其表面的阳离子官能团的介孔碳。