Abstract:
Nickel catalyst dipped on zirconia-titania complex metal oxides, a manufacturing method thereof, and a production method of hydrogen with autothermal reforming of ethanol using the catalyst are provided to offer excellent durability for a long time with high activation of the zirconia-titania complex metal oxides. Nickel catalyst dipped on zirconia-titania complex metal oxides is used for manufacturing hydrogen by autothermal reforming reaction of ethanol. The zirconia-titania complex metal oxides are manufactured by condensing and hydration of titanium or zirconium. The catalyst is represented by a chemical formula, Ni/ZraTibO2(0=0.2). This chemical formula is made by dipping the nickel metal with a ratio of 1 ~ 50 parts by weight based on the zirconia-titania complex metal oxides precursor 100 parts by weight.