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公开(公告)号：KR100944039B1
公开(公告)日：2010-02-24
申请号：KR1020080015534
申请日：2008-02-20
Applicant: 전남대학교산학협력단 , 주식회사 세아엠앤에스
CPC classification number: Y02P10/234
Abstract: 본 발명은 몰리브덴 제조 공정에서 발생하는 폐수로부터 유기용매를 이용하여 폐수에 잔류하는 몰리브덴 및 구리 등 유가금속을 회수함을 목적으로 한다.
본 발명에 의한 몰리브덴 제조 공정에서 발생된 폐수에 잔류하는 몰리브덴과 구리의 회수 방법은, 몰리브덴이 함유된 폐수에 유기용매를 첨가하여 상기 유기용매에 몰리브덴 이온을 포집하는 단계와; 상기 단계에 의해 몰리브덴 이온이 포집된 유기용매에 암모니아수를 첨가하여 상기 몰리브덴 이온을 상기 유기용매로부터 역추출하는 단계와; 상기 단계에 의해 몰리브덴 이온이 역추출된 암모니아수에 산을 첨가하여 pH 2 이하로 조절함으로써 몰리브덴을 회수하는 단계를 포함하여 이루어진다.
폐수, 몰리브덴, 용매추출, 구리-
公开(公告)号：KR101048293B1
公开(公告)日：2011-07-13
申请号：KR1020100018443
申请日：2010-03-02
Applicant: 전남대학교산학협력단
CPC classification number: C02F1/26 , C02F1/5272 , C02F1/54
Abstract: PURPOSE: A method for manufacturing molybdenum is provided to obtain highly purified molybdenum by collecting molybdenum and eliminating arsenic from the molybdenum through a solvent extraction process. CONSTITUTION: An amine-based organic solvent is added in wastewater containing molybdenum and arsenic. Molybdenum ions are collected by the amine-based organic solvent. Ammonia water is added to back-extract the molybdenum ions(S20). Magnesium salt is added to precipitate an arsenic compound. A solid-liquid separating process is implemented. Acid is added to the liquid obtained through the solid-liquid separating process, and highly purified molybdenum is collected(S50).
Abstract translation: 目的：提供钼的制造方法，通过收集钼并通过溶剂萃取方法从钼中除去砷来获得高纯度的钼。 构成：在含有钼和砷的废水中加入胺类有机溶剂。 钼离子由胺类有机溶剂收集。 加入氨水以提取钼离子（S20）。 加入镁盐以沉淀砷化合物。 实行固液分离处理。 将酸加入到通过固液分离过程获得的液体中，并收集高纯度的钼（S50）。
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公开(公告)号：KR1020090090215A
公开(公告)日：2009-08-25
申请号：KR1020080015534
申请日：2008-02-20
Applicant: 전남대학교산학협력단 , 주식회사 세아엠앤에스
CPC classification number: Y02P10/234 , C22B7/00 , C22B3/00 , C22B15/00 , C22B34/34
Abstract: A method for collecting copper and molybdenum remaining in effluent generated in a manufacturing process is provided to reduce mineral import by recycling the copper and the molybdenum with a counter-current extraction mode. A method for collecting copper and molybdenum remaining in effluent generated in a manufacturing process includes the following steps of: collecting a molybdenum ion in an organic solvent by adding an Amine series organic solvent(S10); separating the collected organic solvent from the effluent(S20); performing a counter-current extraction process of the molybdenum ion by adding an ammonia solution(S30); and collecting molybdenum by adding acid on the ammonia solution(S40).
Abstract translation: 提供一种用于收集在制造过程中产生的流出物中剩余的铜和钼的方法，以通过以逆流提取模式回收铜和钼来减少矿物进口。 在制造过程中产生的废水中残留的铜和钼的收集方法包括以下步骤：通过加入胺系列有机溶剂在有机溶剂中收集钼离子（S10）; 从流出物中分离收集的有机溶剂（S20）; 通过加入氨溶液进行钼离子的逆流提取处理（S30）; 并通过在氨溶液中加酸收集钼（S40）。
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