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公开(公告)号：KR1020040016564A
公开(公告)日：2004-02-25
申请号：KR1020020048795
申请日：2002-08-19
Applicant: 제일모직주식회사
CPC classification number: C08L25/12 , C08J2300/22 , C08L33/06 , C08L51/04 , C08L2205/22
Abstract: PURPOSE: A thermoplastic resin composition using microparticle is provided, to lower the gloss with suppressing the deterioration of the mechanical properties. CONSTITUTION: The thermoplastic resin composition comprises 10-50 parts by weight of the graft copolymer resin prepared by copolymerizing 10-30 parts by weight of a cyano vinyl compound and 70-90 parts by weight of an aromatic vinyl compound to 30-60 parts by weight of a rubbery polymer; 40-80 parts by weight of the copolymer consisting of 20-40 wt% of a cyano vinyl compound and 60-80 wt% of an aromatic vinyl compound; and 1-50 parts by weight of a crosslinkable organic microparticle. Preferably the crosslinkable organic microparticle is prepared by dispersing a polymer organic dispersant aqueous solution and a solution containing a crosslinkable monomer, an initiator and a polymerizable monomer to a drop of 0.1-3.0 micrometers and polymerizing it at a temperature of 50-80 deg.C, and has a particle size of 1-20 micrometers.
Abstract translation: 目的：提供使用微粒的热塑性树脂组合物，以降低光泽度，抑制机械性能的劣化。 构成：热塑性树脂组合物包含10-50重量份的接枝共聚物树脂，其通过将10-30重量份的氰基乙烯基化合物和70-90重量份的芳族乙烯基化合物共聚合至30-60重量份 橡胶状聚合物的重量; 由20-40重量％的氰基乙烯基化合物和60-80重量％的芳族乙烯基化合物组成的共聚物40-80重量份; 和1-50重量份的可交联有机微粒。 优选地，可交联有机微粒通过将聚合物有机分散剂水溶液和含有可交联单体，引发剂和可聚合单体的溶液分散在0.1-3.0微米的滴下并在50-80℃的温度下聚合来制备 ，并且具有1-20微米的粒度。
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公开(公告)号：KR100394059B1
公开(公告)日：2003-09-19
申请号：KR1019980053799
申请日：1998-12-08
Applicant: 제일모직주식회사
Abstract: PURPOSE: Provided is styrene thermoplastic resin composition that is excellent in antistatics and can be used for a tray of semiconductor parts. CONSTITUTION: Styrene thermoplastic resin composition comprises 100 pts.wt. of a rubber-modified styrene resin having an average molecular weight of 19-22, 1.0-3.0 pts.wt. of a mixture of anionic surfactant, 0.05-1.0 pts.wt of a glyceryl monostearate, 0.3-0.7 pts.wt. of titanium dioxide and 0.01-0.1 pts.wt. of zinc-stearate. The rubber-modified styrene resin comprises 90-92 pts.wt. of a monovinyl aromatic compound, 8-10 pts.wt. of a polybutadiene rubber, 1.0-2.5 pts.wt. of a liquid paraffin-mineral oil, 0.05-0.1 pts.wt. of triethyleneglycol-bis-3-(3-t-butyl-4-hydroxy-5-methylphenyl)propionate. The mixture of anionic surfactant comprises a chlorosulfonated and saponificated paraffin oil and magnesium stearate.
Abstract translation: 用途：提供抗静电性能优异的苯乙烯热塑性树脂组合物，可用于半导体部件的托盘。 构成：苯乙烯热塑性树脂组合物含有100重量份。 的平均分子量为19-22的橡胶改性苯乙烯树脂，1.0-3.0重量份。 阴离子表面活性剂，0.05-1.0重量份甘油单硬脂酸酯，0.3-0.7重量份 的二氧化钛和0.01-0.1重量份。 的硬脂酸锌。 橡胶改性苯乙烯树脂包含90-92重量份。 的单乙烯基芳族化合物，8-10重量份。 的聚丁二烯橡胶，1.0-2.5重量份。 的液体石蜡 - 矿物油，0.05-0.1重量份。 的三甘醇 - 双-3-（3-叔丁基-4-羟基-5-甲基苯基）丙酸酯。 阴离子表面活性剂的混合物包含氯磺化和皂化石蜡油和硬脂酸镁。
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公开(公告)号：KR1020000009056A
公开(公告)日：2000-02-15
申请号：KR1019980029225
申请日：1998-07-21
Applicant: 제일모직주식회사
CPC classification number: C08L25/04 , C08J2300/22 , C08K5/01 , C08K5/098 , C08L51/04 , C08L83/04 , C08L2201/04
Abstract: PURPOSE: A styrene thermoplastic resin composition is provided which is excellent in electrostatic discharge resistance and surface glossiness by adding glyceryl monostearate, a higher fatty acid and a surfactant to a rubber-denatured styrene resin. CONSTITUTION: The composition comprises: 100 pts.wt. of a rubber-denatured styrene resin having a weight average molecular weight of 200,000-250,000; 1.0-3.0 pts.wt of an anionic surfactant mixture, 0.05-1.0 pts.wt. of glyceryl monostearate and 0.01-0.1 pts.wt. of zinc stearate. The rubber-denatured styrene resin is produced by adding a mono vinyl aromatic compound, a polybutadiene rubber, a liquid paraffin-mineral oil, polydimethylsiloxane or polydiphenylsiloxane, and an antioxidant, followed by mass polymerization.
Abstract translation: 目的：提供一种苯乙烯热塑性树脂组合物，其通过将丙烯酸单硬脂酸酯，高级脂肪酸和表面活性剂加入到橡胶变性苯乙烯树脂中而具有优异的耐静电电导性和表面光泽度。 构成：组合物包括：100重量份 的重均分子量为200,000〜25万的橡胶变性苯乙烯树脂; 1.0-3.0重量份阴离子表面活性剂混合物，0.05-1.0重量份 的单硬脂酸甘油酯和0.01-0.1重量份 的硬脂酸锌。 橡胶变性苯乙烯树脂通过加入单乙烯基芳族化合物，聚丁二烯橡胶，液体石蜡 - 矿物油，聚二甲基硅氧烷或聚二苯基硅氧烷和抗氧化剂，然后进行大规聚合而制备。
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公开(公告)号：KR100833928B1
公开(公告)日：2008-05-30
申请号：KR1020060136720
申请日：2006-12-28
Applicant: 제일모직주식회사
Inventor： 김준수
Abstract: A polycarbonate resin composition, a pellet prepared by extruding the composition, and a housing for electric or electronic parts molded by using the composition are provided to improve heat resistance and abrasion resistance. A polycarbonate resin composition comprises 50-95 parts by weight of a polycarbonate resin; and 5-50 parts by weight of the carbon black having a particle size of 1-30 nm. Preferably the carbon black is selected from the group consisting of furnace black, thermal black, channel black, acetylene black, lamp black and their mixture.
Abstract translation: 提供聚碳酸酯树脂组合物，通过挤出组合物制备的颗粒，以及通过使用该组合物模制的电气或电子部件的壳体，以改善耐热性和耐磨性。 聚碳酸酯树脂组合物包含50-95重量份的聚碳酸酯树脂; 和5-50重量份的粒径为1-30nm的炭黑。 优选地，炭黑选自炉黑，热黑，通道黑，乙炔黑，灯黑及其混合物。
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公开(公告)号：KR100540910B1
公开(公告)日：2006-01-12
申请号：KR1019990057933
申请日：1999-12-15
Applicant: 제일모직주식회사
IPC: C08L55/02
Abstract: 본 발명은 평균입자직경이 0.20-0.30㎛인 그라프트 공중합체수지와 평균입자직경이 0.10-0.20㎛인 그라프트 공중합체수지의 합 15-25중량%와 매트릭스 SAN수지 75-85중량%로 구성되는 내구성/내충격성이 우수한 ABS수지 조성물이 제공되는 것이며 전기전자 부품, 자동차 부품 등에 광범위하게 이용될 수 있다.
ABS수지, SAN수지, 내구성, 내충격성-
Patent Agency Ranking
公开(公告)号：KR100424639B1
公开(公告)日：2005-02-23
申请号：KR1019980029224
申请日：1998-07-21
Applicant: 제일모직주식회사
Abstract: 본 발명은 알케닐 방향족 화합물 100중량부에 부타디엔고무 5 내지 15중량부, 비닐시아나이드 성분이 20 내지 40중량%함유되어 있고, 중량평균분자량이 5만 내지 30만인 스티렌계 공중합체 5 내지 20중량부를 1차 반응기에서 벌크중합시켜 고형분함량이 15 내지 45%가 되도록한 후 2차 반응기로 이송시켜 현탁중합하여 반응을 완료하는 것을 특징으로 하는 내화학성이 우수한 스티렌계 열가소성 수지의 제조방법에 관한 것으로, 비닐시아나이드를 모노머 형태가 아닌 폴리머 형태로 투입하여 중합함으로써 내충격성의 향상과 더불어 내화학성의 향상을 도모할 수 있게 된다.
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公开(公告)号：KR1020020044387A
公开(公告)日：2002-06-15
申请号：KR1020000073763
申请日：2000-12-06
Applicant: 제일모직주식회사
Inventor： 김준수
IPC: C08L25/12
CPC classification number: C08L51/06 , C08J2300/22 , C08K5/05 , C08K5/098 , C08K5/524 , C08L25/12 , C08L2201/08 , C08L2205/025 , C08L2205/03
Abstract: PURPOSE: Provided is a thermoplastic resin composition excellent in thermal stability and light stability, comprising hindered phenolic antioxidant, phosphite based antioxidant, hals based UV stabilizer, and stearate based metal salt, in addition to base resin. CONSTITUTION: The composition comprises a base resin consisting of (a) 10-60 parts by weight of styrene-based graft copolymer resin having average particle diameter of 0.10-0.40 micrometer, (b) 20-80 parts by weight of styrene-acrylonitrile(SAN) resin containing 20-40 wt% of acrylonitrile and having a weight average molecular weight of 100,000-140,000, and (c) 20-80 parts by weight of SAN resin containing 25-35 wt% of acrylonitrile and having a weight average molecular weight of 80,000-110,000(wherein, (a)+(b)+(c) = 100 parts by weight); (d) 0.05-2 parts by weight of hindered phenolic compound; (e) 0.05-4 parts by weight of phosphite based compound; (f) hals compound; and (g) 0.1-3.0 parts by weight of barium stearate.
Abstract translation: 目的：提供热稳定性和光稳定性优异的热固性树脂组合物，除了基础树脂之外，还包含受阻酚抗氧化剂，亚磷酸酯类抗氧化剂，基于紫外线稳定剂和硬脂酸盐的金属盐。 组成：该组合物包括由（a）10-60重量份平均粒径为0.10-0.40微米的苯乙烯基接枝共聚物树脂组成的基础树脂，（b）20-80重量份苯乙烯 - 丙烯腈（ SAN）树脂，其含有20-40重量％的丙烯腈，重均分子量为100,000-140,000，和（c）20-80重量份含25-35重量％丙烯腈的SAN树脂，其重均分子量 重量80,000-110,000（其中（a）+（b）+（c）= 100重量份）; （d）0.05-2重量份的受阻酚类化合物; （e）0.05-4重量份的亚磷酸酯基化合物; （f）复仇; 和（g）0.1-3.0重量份硬脂酸钡。
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公开(公告)号：KR1020020003458A
公开(公告)日：2002-01-12
申请号：KR1020000037910
申请日：2000-07-04
Applicant: 제일모직주식회사
CPC classification number: C08L55/02 , C08J2300/22 , C08K5/20 , C08L25/12 , C08L2205/025 , C08L2205/03
Abstract: PURPOSE: Provided is a thermoplastic resin composition with improved impact-resistance, rigidity, and fluidity, which includes a rubber-reinforced styrene-based graft copolymer resin and acrylonitrile-styrene copolymers(SAN resin). CONSTITUTION: The thermoplastic resin composition comprises: (A) 15-40pts.wt. of the rubber-reinforced styrene-based graft copolymer resin containing a rubber having an average particle size of 0.1-0.4 micrometer, which is produced by grafting a graft monomer mixture comprising acrylonitrile and styrene monomers on a rubber latex; (B) 25-45pts.wt. of a SAN resin(b1) having the acrylonitrile content of 25-35wt% and a weight average molecular weight of 100,000-130,000, and 35-65pts.wt. of a SAN resin(b2) having the acrylonitrile content of 30-40wt% and a weight average molecular weight of 80,000-120,000, wherein the amount of the component (B) is 20-80pts.wt.; and (C) 3-10pts.wt. (based on the total base resin (A)+(B) of 100pts.wt.) of ethylene bis fatty acid amide.
Abstract translation: 目的：提供具有改善的抗冲击性，刚性和流动性的热塑性树脂组合物，其包括橡胶增强的苯乙烯基接枝共聚物树脂和丙烯腈 - 苯乙烯共聚物（SAN树脂）。 构成：热塑性树脂组合物包含：（A）15-40pts.wt。 通过将包含丙烯腈和苯乙烯单体的接枝单体混合物接枝在橡胶胶乳上而制备的含有平均粒度为0.1-0.4微米的橡胶的橡胶增强苯乙烯接枝共聚物树脂; （B）25-45pts.wt。 的丙烯腈含量为25-35重量％，重均分子量为100,000-130,000的SAN树脂（b1）和35-65pts.wt。 的丙烯腈含量为30-40重量％，重均分子量为80,000-120,000的SAN树脂（b2），其中组分（B）的量为20-80pts.wt。 和（C）3-10pts.wt。 （基于100重量份的总基础树脂（A）+（B））的乙烯双脂肪酸酰胺。
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公开(公告)号：KR100639043B1
公开(公告)日：2006-10-31
申请号：KR1020050105852
申请日：2005-11-07
Applicant: 제일모직주식회사
IPC: C08L69/00
Abstract: Provided is a polycarbonate-based alloy thermoplastic resin composition which is low in gloss and is excellent in scratch resistance without the deterioration of impact strength by using crosslinking organic microparticles. The composition comprises 40-95 parts by weight of a thermoplastic polycarbonate resin; 1-50 parts by weight of a graft copolymer obtained by graft polymerizing 5-95 parts by weight of a monomer mixture comprising 50-95 parts by weight of styrene, alpha -methylstyrene, halogen or alkyl-substituted styrene, C1-C8 alkyl methacrylate, C1-C8 alkyl acrylate or their mixture and 5-50 parts by weight of acrylonitrile, methacrylonitrile, C1-C8 alkyl methacrylate, C1-C8 alkyl acrylate, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixture, to 5-95 parts by weight of a polymer selected from butadiene rubber, acrylic rubber, ethylene-propylene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber, isoprene rubber, ethylene-propylene-diene terpolymer, polyorganosiloxane-poly(alkyl (meth)acrylate) rubber composite and their mixture; 1-50 parts by weight of a vinyl-based copolymer or its mixture obtained by copolymerizing 50-95 parts by weight of styrene, alpha-methylstyrene, ring-substituted styrene, C1-C8 alkyl methacrylate, C1-C8 alkyl acrylate or their mixture and 5-50 parts by weight of acrylonitrile, methacrylonitrile, C1-C8 alkyl methacrylate, C1-C8 alkyl acrylate, maleic anhydride, C1-C4 alkyl or phenyl-substituted maleimide or their mixture; and 1-50 parts by weight of a crosslinking organic microparticle. Preferably the crosslinking organic microparticle has a particle size of 1-20 micrometers.
Abstract translation: 本发明提供一种聚碳酸酯系合金的热塑性树脂组合物，其光泽低，且耐划伤性优异，且不会因使用交联有机微粒而使冲击强度降低。 该组合物包含40-95重量份的热塑性聚碳酸酯树脂; 1-50重量份接枝共聚物，其通过将5-95重量份包含50-95重量份苯乙烯，α-甲基苯乙烯，卤素或烷基取代的苯乙烯，甲基丙烯酸C1-C8烷基酯 ，丙烯酸C 1 -C 8烷基酯或它们的混合物和5-50重量份的丙烯腈，甲基丙烯腈，甲基丙烯酸C 1 -C 8烷基酯，丙烯酸C 1 -C 8烷基酯，马来酸酐，C 1 -C 4烷基或苯基N-取代的马来酰亚胺或它们的混合物， （丁二烯橡胶，丙烯酸橡胶，乙烯 - 丙烯橡胶，苯乙烯 - 丁二烯橡胶，丙烯腈 - 丁二烯橡胶，异戊二烯橡胶，乙烯 - 丙烯 - 二烯三元共聚物，聚有机硅氧烷 - 聚 ）丙烯酸酯）橡胶复合物及其混合物; 1-50重量份的通过共聚合50-95重量份的苯乙烯，α-甲基苯乙烯，环取代的苯乙烯，甲基丙烯酸C1-C8烷基酯，丙烯酸C1-C8烷基酯或它们的混合物获得的乙烯基共聚物或其混合物 和5-50重量份的丙烯腈，甲基丙烯腈，甲基丙烯酸C1-C8烷基酯，丙烯酸C1-C8烷基酯，马来酸酐，C1-C4烷基或苯基取代的马来酰亚胺或它们的混合物; 和1-50重量份的交联有机微粒。 交联有机微粒优选具有1-20微米的粒度。
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公开(公告)号：KR100617340B1
公开(公告)日：2006-08-28
申请号：KR1020050066718
申请日：2005-07-22
Applicant: 제일모직주식회사
Abstract: 본 발명의 저광택 난연성 폴리카보네이트 수지조성물은 (A) 열가소성 폴리카보네이트 수지 45∼95 중량부, (B) 스티렌과 아크릴로니트릴과의 혼합물인 단량체 혼합물을 고무성분에 그라프트 중합하여 얻은 고무변성 스티렌계 그라프트 공중합체 1∼50 중량부, (C) 스티렌과 아크릴로니트릴을 공중합하여 얻은 비닐계 공중합체 1∼50 중량부, (D) 인계 난연제 1∼30 중량부 및 (E) 상기 구성성분 (A)+(B)+(C)+(D)의 100 중량부에 대하여 입자크기가 다른 2종 이상의 불소화 폴리올레핀계 수지 0.1∼10 중량부로 구성된다.
폴리카보네이트, 인계 난연제, 불소화 폴리올레핀계 수지, 폴리테트라플로오로에틸렌, 저광택성Abstract translation: 本发明（A）一种苯乙烯热塑性聚碳酸酯树脂，45-95重量份，（B）的低光泽的阻燃聚碳酸酯树脂组合物的橡胶改性的接枝单体的混合物和苯乙烯和丙烯腈在橡胶成分的混合物聚合而得到的基于 为1〜50重量份接枝共聚物，（C）1〜50重量份的通过共聚合苯乙烯和丙烯腈而得到的乙烯基类共聚物的，（d）1至30重量份基于磷的阻燃剂，以及（E）组分（ 它是：a）+（B）+（C）+（d）100重量份的2种不同的配置部分的粒径的重量基于氟化聚烯烃的树脂0.1至10或更多个相对于所述。
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