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公开(公告)号：WO2012053693A1
公开(公告)日：2012-04-26
申请号：PCT/KR2010/008312
申请日：2010-11-24
CPC classification number: C08L33/12 , C08G77/04 , C08L33/08 , C08L33/10 , C08L51/06 , C08L53/00 , C08L83/00 , C08L83/04 , C08L2205/02 , C08L2205/025 , C08L2205/035 , C08L33/18
Abstract: 본 발명은 투명 열가소성 수지 조성물에 관한 것으로, (A) 부타디엔의 입자크기가 700∼1800 Å인 코어-쉘 구조의 그라프트 수지인 메틸메타크릴레이트-스티렌-아크릴로니트릴-부타디엔 공중합체(g-MABS); (B) 부타디엔의 입자크기가 2000∼4000 Å인 코어-쉘 구조의 그라프트 수지인 메틸메타크릴레이트-스티렌-아크릴로니트릴-부타디엔 공중합체(g-MABS); (C) 디메틸 폴리실록산; 및 (D) (메타)아크릴산 알킬 에스테르 성분이 40∼100 % 포함된 기초수지로 구성된다.
Abstract translation: 本发明涉及一种透明热塑性树脂组合物，其包含含有40-100％的（A）甲基丙烯酸甲酯 - 苯乙烯 - 丙烯腈 - 丁二烯共聚物（g-MABS）的基础树脂，其为具有核 - 壳的接枝树脂 结构，丁二烯的粒度为700-1800; （B）具有核 - 壳结构的接枝树脂的甲基丙烯酸甲酯 - 苯乙烯 - 丙烯腈 - 丁二烯共聚物（g-MABS），丁二烯的粒径为2000-4000埃; （C）二甲基聚硅氧烷; 和（D）（甲基）丙烯酸烷基酯。
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公开(公告)号：KR101288562B1
公开(公告)日：2013-07-22
申请号：KR1020117003324
申请日：2010-12-09
Applicant: 제일모직주식회사
Abstract: (A)(A-1) 폴리알킬(메타)아크릴레이트 수지 및 (A-2) 비닐계 공중합체를 포함하는 기초 수지; 및 (B) 고무질 중합체에, 방향족 비닐 화합물, 시안화 비닐 화합물 및 아크릴계 화합물 중 적어도 두 화합물의 공중합체가 그라프트된 코어-쉘 구조의 공중합체를 포함하는 열가소성 수지 조성물 및 이를 이용한 성형품이 제공된다.
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公开(公告)号：KR1020090072651A
公开(公告)日：2009-07-02
申请号：KR1020070140822
申请日：2007-12-28
Applicant: 제일모직주식회사
Abstract: A thermoplastic resin composition is provided to ensure excellent weatherability while maintaining heat resistance and impact strength of intrinsic resin. A thermoplastic resin composition with excellent weatherability comprises an acrylic graft-copolymer 20~60 parts by weight, diene graft-copolymer 0~20 parts by weight, and a copolymer 40~80 parts by weight of vinyl cyanide compound with average molecular weight of 80,000~400,000 and aromatic vinyl compound. The acrylic graft-copolymer is obtained by emulsion graft-polymerizing a monomer mixture 40~80 parts by weight consisting of a vinyl cyanide compound 30~35 weight% and an aromatic vinyl compound 70~65 weight% to an acrylic synthetic rubber 20~60 parts by weight.
Abstract translation: 提供热塑性树脂组合物以确保优异的耐候性，同时保持本征树脂的耐热性和冲击强度。 具有优异耐候性的热塑性树脂组合物包括20〜60重量份的丙烯酸接枝共聚物，0〜20重量份的二烯接枝共聚物和平均分子量为80,000的共聚物40〜80重量份的乙烯基氰化合物 〜40万和芳香族乙烯基化合物。 丙烯酸接枝共聚物通过乳液接枝聚合40〜80重量份的单体混合物而得到，所述单体混合物由30〜35重量％的乙烯基氰化合物和70〜65重量％的芳香族乙烯基化合物组成的丙烯酸合成橡胶20〜60 重量份。
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公开(公告)号：KR101277720B1
公开(公告)日：2013-06-24
申请号：KR1020117003323
申请日：2010-12-09
Applicant: 제일모직주식회사
CPC classification number: C08L33/06 , C08F279/02 , C08K5/20 , C08L51/04 , C08L2207/53 , C08F212/08 , C08F220/18 , C08F220/44
Abstract: (A) 쉘에 아크릴계 화합물을 포함하는 코어-쉘 구조의 공중합체, (B) 아크릴계 단량체를 포함하는 아크릴계 중합체 및 (C) 표면 조정제를 포함하는 열가소성 수지 조성물 및 이를 이용한 성형품이 제공된다.
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公开(公告)号：KR1020120037817A
公开(公告)日：2012-04-20
申请号：KR1020100099504
申请日：2010-10-12
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition is provided to have excellent scratch resistance, impact resistance, transparence, and productivity, and to embody various colors of high quality. CONSTITUTION: A thermoplastic resin composition comprises: 10-40 weight% of a core-shell structured copolymer containing an acryl-based compound; 60-90 weight% of an acrylic polymer containing acrylic compound; and 0.01-0.5 parts by weight of sparkle agent containing glass flake on the basis of 100.0 parts by weight of the total weight of core-shell structure copolymer and the acrylic copolymer. The core-shell structured copolymer comprises a copolymer in which an acrylic compound, an aromatic compound, and a cyanide vinyl compound are grafted to polybutadiene rubber.
Abstract translation: 目的：提供热塑性树脂组合物以具有优异的耐刮擦性，抗冲击性，透明性和生产率，并且具有高品质的各种颜色。 构成：热塑性树脂组合物包括：10-40重量％的含有丙烯酸类化合物的核 - 壳结构共聚物; 60-90重量％的含丙烯酸类化合物的丙烯酸类聚合物; 和0.01-0.5重量份的基于100.0重量份核 - 壳结构共聚物和丙烯酸共聚物总重量的闪光剂的玻璃薄片。 核 - 壳结构共聚物包括其中丙烯酸化合物，芳族化合物和氰化乙烯基化合物接枝到聚丁二烯橡胶上的共聚物。
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Patent Agency Ranking
公开(公告)号：KR1020110082121A
公开(公告)日：2011-07-18
申请号：KR1020117003323
申请日：2010-12-09
Applicant: 제일모직주식회사
CPC classification number: C08L33/06 , C08F279/02 , C08K5/20 , C08L51/04 , C08L2207/53 , C08F212/08 , C08F220/18 , C08F220/44
Abstract: PURPOSE: A thermoplastic resin composition is provided to ensure excellent scratch resistance, surface slip property, abrasion resistance, high glossiness, impact resistance, heat resistance, processability, and colorability. CONSTITUTION: A thermoplastic resin composition comprises (A) 10-40 weight% of a copolymer having a core-shell structure including an acrylic compound on a shell; (B) 60-90 weight% of an acrylic polymer including an acrylic monomer; and (C) 0.1-5 parts by weight of a surface modifier based on 100 parts by weight of (A) and (B) components.
Abstract translation: 目的：提供热塑性树脂组合物以确保优异的耐刮擦性，表面滑动性，耐磨性，高光泽度，耐冲击性，耐热性，加工性和着色性。 构成：热塑性树脂组合物包含（A）10-40重量％的在壳上具有包含丙烯酸化合物的核 - 壳结构的共聚物; （B）60-90重量％的包含丙烯酸类单体的丙烯酸类聚合物; 和（C）基于100重量份的（A）和（B）组分的0.1-5重量份的表面改性剂。
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公开(公告)号：KR101399390B1
公开(公告)日：2014-05-27
申请号：KR1020100102171
申请日：2010-10-20
Applicant: 제일모직주식회사
CPC classification number: C08L33/12 , C08G77/04 , C08L33/08 , C08L33/10 , C08L51/06 , C08L53/00 , C08L83/00 , C08L83/04 , C08L2205/02 , C08L2205/025 , C08L2205/035 , C08L33/18
Abstract: 본 발명은 투명 열가소성 수지 조성물에 관한 것으로, (A) 부타디엔의 입자크기가 700~1800 Å인 코어-쉘 구조의 그라프트 수지인 메틸메타크릴레이트-스티렌-아크릴로니트릴-부타디엔 공중합체(g-MABS);(B) 부타디엔의 입자크기가 2000~4000 Å인 코어-쉘 구조의 그라프트 수지인 메틸메타크릴레이트-스티렌-아크릴로니트릴-부타디엔 공중합체(g-MABS);(C) 디메틸 폴리실록산; 및 (D) (메타)아크릴산 알킬 에스테르 성분이 40~100% 포함된 기초수지로 구성된다.
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公开(公告)号：KR101323142B1
公开(公告)日：2013-10-30
申请号：KR1020100111405
申请日：2010-11-10
Applicant: 제일모직주식회사
Abstract: 본 발명은 (A) 고무변성 스티렌계 그라프트 공중합체 수지 10 내지 20 중량%; (B) 폴리메틸메타크릴레이트(PMMA) 수지 30 내지 50 중량%; 및 (C) (메타)아크릴산 알킬 에스테르 성분이 5∼50 중량% 포함된 스티렌계 공중합체 수지 40 내지 60 중량%;를 포함하는 내스크래치성이 우수한 열가소성 수지 조성물을 제공한다. 본 발명에 따른 내스크래치성이 우수한 열가소성 수지 조성물은 내스크래치성, 충격 강도, 착색성, 광택도 등과 같은 물성 발란스가 우수하며, 사출성형성이 우수하다.
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公开(公告)号：KR1020110082122A
公开(公告)日：2011-07-18
申请号：KR1020117003324
申请日：2010-12-09
Applicant: 제일모직주식회사
Abstract: PURPOSE: A thermoplastic resin composition is provided to ensure excellent scratch resistance, colorability, high temperature thermal stability, impact resistance, glossiness, transparency, weather resistance, and processability, thereby enabling use for various electric and electronic part, automobile parts and general general merchandises. CONSTITUTION: A thermoplastic resin composition comprises: (A) 60-95 wt% of a base resin including (A-1) a poly(alkyl methacrylate) resin and (A-2) a vinyl-based copolymer; and (B) 5-40 wt% of a copolymer having a core-shell structure, in which a copolymer of at least two compounds selected from an aromatic vinyl compound, cyanic vinyl compound, and acrylic compound is grafted onto a gum polymer.
Abstract translation: 目的：提供热塑性树脂组合物以确保优异的耐刮擦性，着色性，高温热稳定性，耐冲击性，光泽度，透明性，耐候性和加工性，从而可用于各种电气和电子部件，汽车部件和一般通用商品 。 构成：热塑性树脂组合物包含：（A）60-95重量％的包含（A-1）聚（甲基丙烯酸烷基酯）树脂和（A-2）乙烯基类共聚物的基础树脂; 和（B）5-40重量％的具有核 - 壳结构的共聚物，其中至少两种选自芳族乙烯基化合物，氰乙烯基化合物和丙烯酸化合物的化合物的共聚物接枝到胶聚合物上。
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公开(公告)号：KR100887316B1
公开(公告)日：2009-03-06
申请号：KR1020070130674
申请日：2007-12-14
Applicant: 제일모직주식회사
Abstract: A high weather resistant and heat-resistant thermoplastic resin composition is provide to improve injection stability and colorability, and to maintain the properties like weather resistance and impact strength by adding a maleimide heat-resistant resin to a blend consisting of an acryl graft-copolymer, a diene graft-copolymer, and vinyl cyanide-aromatic vinyl-heat resistant alpha-methylstyrene ter-polymer. A high weather resistant and heat-resistant thermoplastic resin composition comprises (A) an acrylic graft copolymer 20-50 weight% which is grafted with a monomer mixture consisting of an aromatic vinyl compound and a vinyl cyanide compound to the acrylic rubber; (B) a diene-based graft copolymer 5-10 weight% which is grafted with a monomer mixture consisting of an aromatic vinyl compound and a vinyl cyanide compound to the diene-based rubber; (C) vinyl cyanide-aromatic vinyl copolymer 20-50 weight%; (D) an alpha-methyl styrene-based compound 10-20 weight% which is a terpolymer copolymerized with an aromatic vinyl compound, a vinyl cyanide compound and an alpha-methyl styrene compound; and (E) a copolymer 5-10 weight% of an N-substituted maleimide compound and an aromatic vinyl compound.
Abstract translation: 提供高耐候性和耐热性的热塑性树脂组合物以提高注射稳定性和着色性，并且通过向由丙烯酸接枝共聚物组成的共混物中加入马来酰亚胺耐热树脂来保持耐候性和冲击强度的性能， 二烯接枝共聚物和乙烯基氰 - 芳族乙烯基耐热α-甲基苯乙烯三元共聚物。 高耐候性和耐热性热塑性树脂组合物包含（A）20-50重量％的丙烯酸接枝共聚物，其与由芳族乙烯基化合物和乙烯基氰化合物组成的单体混合物接枝到丙烯酸橡胶上; （B）5-10重量％的二烯基接枝共聚物，其与由芳族乙烯基化合物和乙烯基氰化合物组成的单体混合物接枝到二烯基橡胶上; （C）乙烯基氰 - 芳族乙烯基共聚物20-50重量％; （D）与芳族乙烯基化合物，乙烯基氰化合物和α-甲基苯乙烯化合物共聚的三元共聚物的α-甲基苯乙烯基化合物10-20重量％ 和（E）5-10重量％的N-取代马来酰亚胺化合物和芳族乙烯基化合物的共聚物。
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