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Patent Agency Ranking
公开(公告)号：KR1020140019637A
公开(公告)日：2014-02-17
申请号：KR1020120086013
申请日：2012-08-06
Applicant: 제일모직주식회사
CPC classification number: C08G64/083 , C08G64/14
Abstract: A polycarbonate resin in the present invention is polymerized by a branching agent repregented by chemical formula 2, Mark-Houwink constant thereof is 0.4-0.60, and the concentration of a terminal hydroxyl group is 22% of total terminal groups. The branched polycarbonate resin remarkably decreases the concentration of hydroxyl groups so yellowness is improved and highly branched structure can be obtained. In the chemical formula 1, each of R1, R2, R3, and R4 is independently a substituted or non-substituted C1-10 alkyl group, a substituted or non-substituted C6-C18 aryl group, a C1-C10 alkyl group with halogen or a C1-C10 alkoxy group, or a C6-C18 aryl group with halogen or a C1-C10 alkoxy group substituent; W is a linear, branched, or cyclic saturated or unsaturated hydrocarbon group, saturated or unsaturated cyclic hydrocarbon substituent-containing hydro carbon group, an O or S-containing hydro carbon group, or S.
Abstract translation: 本发明的聚碳酸酯树脂通过化学式2表示的支化剂聚合，Mark-Houwink常数为0.4〜0.60，末端羟基的浓度为总末端的22％。 支链聚碳酸酯树脂显着降低羟基的浓度，因此改善了黄色度并且可以获得高度支化的结构。 在化学式1中，R 1，R 2，R 3和R 4各自独立地为取代或未取代的C 1-10烷基，取代或未取代的C 6 -C 18芳基，具有卤素的C 1 -C 10烷基 或C 1 -C 10烷氧基，或具有卤素或C 1 -C 10烷氧基取代基的C 6 -C 18芳基; W是直链，支链或环状饱和或不饱和烃基，含饱和或不饱和环烃基取代基的烃基，含O或S的氢碳基团或S.
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公开(公告)号：KR1020140097919A
公开(公告)日：2014-08-07
申请号：KR1020130010679
申请日：2013-01-30
Applicant: 제일모직주식회사
CPC classification number: C08G64/307 , C08J9/122 , C08J2203/06 , C08J2369/00
Abstract: A method for preparing a polycarbonate resin of the present invention comprises a step of: polymerizing aromatic dihidroxy compounds and diaryl carbonate and preparing a polycarbonate prepolymer; injecting and mixing an inert gas into the produced polycarbonate prepolymer; and foaming and polymerizing the polycarbonate prepolymer in which the inert gas is mixed. The method for preparing the polycarbonate resin can prevent or reduce the yellowing phenomenon during melt polymerization of the polycarbonate resin.
Abstract translation: 制备本发明的聚碳酸酯树脂的方法包括以下步骤：使芳族二羟基化合物和碳酸二芳酯聚合并制备聚碳酸酯预聚物; 将惰性气体注入并混合到所生产的聚碳酸酯预聚物中; 并使其中混合惰性气体的聚碳酸酯预聚物发泡和聚合。 聚碳酸酯树脂的制备方法可以防止或降低聚碳酸酯树脂熔融聚合过程中的泛黄现象。
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公开(公告)号：KR1020140086774A
公开(公告)日：2014-07-08
申请号：KR1020120157678
申请日：2012-12-28
Applicant: 제일모직주식회사
CPC classification number: C08G64/083 , C08G64/14 , C08G64/307
Abstract: A manufacturing method for branched polycarbonate of the present invention comprises: a step of manufacturing a first raw material by mixing an aromatic dihydroxy compound, diarylcarbonate and 60-140 ppb (weight) of a catalyst with respect to the aromatic dihydroxy compound and reacting the same; a step of manufacturing a second raw material by mixing an aromatic dihydroxy compound, diarylcarbonate, a phosphorus based branching agent and 350-450 ppb (weight) of a catalyst with respect to the aromatic dihydroxy compound and reacting the same; and a step of performing melt polymerization on 100 parts by weight of the first raw material and 1-20 parts by weight of the second raw material. The branched polycarbonate manufactured by the manufacturing method has excellent thermal stability since catalyst content is low and exhibits excellent color stability and mobility.
Abstract translation: 本发明的支链聚碳酸酯的制造方法包括：通过将芳族二羟基化合物，二芳基碳酸酯和60-140ppb（重量）的催化剂相对于芳族二羟基化合物混合并使其反应来制造第一原料的步骤 ; 通过将芳族二羟基化合物，碳酸二芳基酯，磷基支化剂和相对于芳族二羟基化合物的350-450ppb（重量）的催化剂混合并使其反应来制造第二原料的步骤; 以及对第一原料100重量份和第二原料1-20重量份进行熔融聚合的工序。 通过制造方法制造的支化聚碳酸酯由于催化剂含量低而具有优异的热稳定性，并表现出优异的颜色稳定性和迁移率。
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公开(公告)号：KR101499246B1
公开(公告)日：2015-03-05
申请号：KR1020120086013
申请日：2012-08-06
Applicant: 제일모직주식회사
CPC classification number: C08G64/083 , C08G64/14
Abstract: 본 발명의 분지형 폴리카보네이트 수지는 하기 화학식 2로 표시되는 분지제를 사용하여 중합되고, 마크-휴잉크 상수가 0.4 내지 0.60이며, 말단 하이드록시기의 농도가 전체 말단기의 22 몰% 이하인 것을 특징으로 한다. 본 발명의 분지형 폴리카보네이트 수지는 특정 분지제를 도입하여 말단 히드록시기의 농도를 대폭 감소시켜 황색도가 개선되고 우수한 초고분지 구조를 얻을 수 있다.
[화학식 2]
상기 화학식 2에서, R1, R2, R3 및 R4는 각기 독립적으로 치환 혹은 비치환된 C1-C10 알킬기, 치환 혹은 비치환된 C6-C18 아릴기, 할로젠 또는 C1-C10 알콕시 그룹 치환기를 가지는 C1-C10 알킬기 또는 할로젠 또는 C1-C10 알콕시 그룹 치환기를 가지는 C6-C18 아릴기이고, W는 직쇄상, 분지쇄상 또는 고리형의 포화 또는 불포화 탄화수소기, 포화 또는 불포화 환상 탄화수소 치환기를 갖는 탄화수소기, O 또는 S 함유 탄화수소기, O 또는 S임.-
公开(公告)号：KR1020140097918A
公开(公告)日：2014-08-07
申请号：KR1020130010678
申请日：2013-01-30
Applicant: 제일모직주식회사
Abstract: A method for manufacturing recyclable polycarbonate of the present invention comprises the steps of forming molten material by heating phenols D., aromatic carbonate, and waste poly carbonate; pressing the molten materials; and polymerizing poly carbonate by reducing the pressure to the molten materials. The manufacturing method of recyclable poly carbonate uses waste poly carbonate products as reacting materials for a poly carbonate melting polymerization process.
Abstract translation: 制造本发明的可回收聚碳酸酯的方法包括以下步骤：通过加热酚D.，芳族碳酸酯和废聚碳酸酯形成熔融材料; 挤压熔融材料; 并通过降低熔融材料的压力来聚合碳酸酯。 可回收聚碳酸酯的制造方法使用废聚碳酸酯制品作为聚碳酸酯熔融聚合方法的反应材料。
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