公开(公告)号：KR100464698B1

公开(公告)日：2005-01-05

申请号：KR1020010081703

申请日：2001-12-20

Applicant: 제일모직주식회사

Inventor： 이병도 ,  장기보 ,  임광열 ,  박상규 ,  전동원 ,  이철호

IPC: C08J3/16

Abstract: PURPOSE: Provided is a method for producing condensed particles using rubber latex having a middle particle size by adding unsaturated acid monomer containing copolymer latex to a synthetic rubber latex having a middle particle size. CONSTITUTION: The method includes the steps of mixing a synthetic rubber latex with a particle size of 1,500 to 2,500 angstrom, an anionic emulsifying agent, non-ionic emulsifying agent and a defoaming agent, while stirring to pretreat the synthetic rubber latex; mixing ion exchanging water and pH controller to a unsaturated acid containing copolymer latex having a solid content of 10 to 50 wt% to adjust the solid content of the copolymer latex to 1 to 10 wt% and the pH of 5 to 11; and adding the unsaturated acid containing copolymer latex treated as above into the pretreated synthetic rubber latex.

Abstract translation: 目的：提供一种通过向具有中等粒度的合成橡胶胶乳中加入含有不饱和酸单体的共聚物胶乳而使用具有中等粒度的橡胶胶乳生产冷凝颗粒的方法。 该方法包括将粒径为1,500至2,500埃的合成橡胶胶乳，阴离子乳化剂，非离子乳化剂和消泡剂混合，同时搅拌预处理合成胶乳; 将离子交换水和pH调节剂混合到含有10〜50重量％固体成分的不饱和酸共聚物胶乳中，使共聚物胶乳的固体成分浓度为1〜10重量％，pH值为5〜11。 并将如上处理的含不饱和酸的共聚物胶乳加入预处理的合成橡胶胶乳中。

公开(公告)号：KR100348425B1

公开(公告)日：2002-08-10

申请号：KR1020000032874

申请日：2000-06-15

Applicant: 제일모직주식회사

Inventor： 박준식 ,  전동원

IPC: C08F2/02

Abstract: 본 발명의 내화학성이 우수한 열가소성 수지의 제조방법은 고무성분 5 내지 15중량부, 알케닐 방향족 화합물 85 내지 95중량부 및 산화방지제 0.1 내지 3.0중량부를 혼합용해시켜 제1 반응기에서 벌크중합을 행하고, 모노머입자 전환율이 15 내지 45중량%에 이르렀을때 이를 제2 반응기로 옮겨 중합개시제, 분산제, 윤활제 및 분산매를 첨가하고 현탁중합하는 단계로 이루어지는 것을 특징으로 한다.

公开(公告)号：KR100443659B1

公开(公告)日：2004-08-09

申请号：KR1020010065317

申请日：2001-10-23

Applicant: 제일모직주식회사

Inventor： 장기보 ,  이병도 ,  임광열 ,  박상규 ,  전동원 ,  이철호

IPC: C08C1/16

Abstract: PURPOSE: Provided is a method for producing coagulated particles of rubber latex excellent in stability, which shows small changes of particle diameter with the lapse of time. CONSTITUTION: The method comprises the steps of (i) forming a seed synthetic rubber latex by typical emulsion polymerization, (ii) mixing an ion-exchanged water, pH adjusting agent, and emulsifier into a unsaturated acid-containing copolymer latex having solid content of 10-50 wt%, to pre-treat the latex so as to have solid content of 1-10 wt% and pH of 3-11, (iii) introducing the pre-treated latex into the seed synthetic rubber latex formed from the step(i), and (iv) adding an ion-exchanged water, anionic emulsifier, nonionic emulsifier, antifoaming agent, and water-soluble polymer to the seed synthetic rubber latex. The method is characterized in that the water-soluble polymer is selected from the group consisting of polyethylene glycol having number average molecular weight of 200-20,000, copolymer of ethylene glycol and ethylene oxide, and a copolymer of polypropylene glycol and propylene glycol and ethylene oxide.

Abstract translation: 目的：提供一种稳定性优异的橡胶胶乳凝聚粒子的制造方法，粒径随时间变化小。 构成：该方法包括以下步骤：（i）通过典型的乳液聚合形成种子合成橡胶胶乳，（ii）将离子交换水，pH调节剂和乳化剂混合到含不饱和酸的共聚物胶乳中， （iii）将预处理的胶乳引入由步骤（a）形成的种子合成橡胶胶乳中，以预处理胶乳以具有1-10重量％的固含量和3-11的pH， （i），和（iv）向种子合成橡胶胶乳中加入离子交换水，阴离子乳化剂，非离子乳化剂，消泡剂和水溶性聚合物。 该方法的特征在于水溶性聚合物选自数均分子量为200-20,000的聚乙二醇，乙二醇和环氧乙烷的共聚物以及聚丙二醇和丙二醇和环氧乙烷的共聚物 。

公开(公告)号：KR1020030051980A

公开(公告)日：2003-06-26

申请号：KR1020010081703

申请日：2001-12-20

Applicant: 제일모직주식회사

Inventor： 이병도 ,  장기보 ,  임광열 ,  박상규 ,  전동원 ,  이철호

IPC: C08J3/16

Abstract: PURPOSE: Provided is a method for producing condensed particles using rubber latex having a middle particle size by adding unsaturated acid monomer containing copolymer latex to a synthetic rubber latex having a middle particle size. CONSTITUTION: The method includes the steps of mixing a synthetic rubber latex with a particle size of 1,500 to 2,500 angstrom, an anionic emulsifying agent, non-ionic emulsifying agent and a defoaming agent, while stirring to pretreat the synthetic rubber latex; mixing ion exchanging water and pH controller to a unsaturated acid containing copolymer latex having a solid content of 10 to 50 wt% to adjust the solid content of the copolymer latex to 1 to 10 wt% and the pH of 5 to 11; and adding the unsaturated acid containing copolymer latex treated as above into the pretreated synthetic rubber latex.

Abstract translation: 目的：提供使用具有中等粒径的橡胶胶乳的缩合粒子的制造方法，该方法是在具有中等粒径的合成橡胶胶乳中添加含有不饱和单体的共聚物胶乳。 方法：该方法包括以下步骤：在搅拌下将合成橡胶胶乳混合至1500-2,500埃的粒度的合成橡胶胶乳，阴离子乳化剂，非离子乳化剂和消泡剂; 将离子交换水和pH调节剂与固含量为10〜50重量％的不饱和酸共聚物胶乳混合，将共聚物胶乳的固体成分调整为1〜10重量％，pH为5〜11， 并将上述处理的不饱和酸共聚物胶乳加入预处理的合成橡胶胶乳中。

公开(公告)号：KR1020010112872A

公开(公告)日：2001-12-22

申请号：KR1020000032874

申请日：2000-06-15

Applicant: 제일모직주식회사

Inventor： 박준식 ,  전동원

IPC: C08F2/02

CPC classification number: H01L2924/14

Abstract: A bump forming method comprising a first step of forming a ball (5) at a distal end of a wire (4) which protrudes from a lower end of a capillary (12); a second step of opening a clamper (11) which securely holds the wire (4) above the capillary (12) and bringing down the capillary (12) as well as the clamper (11), in which an amount of movement of the clamper (11) is smaller than that of the capillary (12) by such an amount as to be equivalent to a length of the wire (4) being protruded from the lower end of the capillary (12) in the first step; a third step of forming a bump (21) from the ball (5) by bonding; and a fourth step of separating the wire (4) from the bump (21) by closing the clamper (11) and lifting up the clamper (11) and the capillary (21) to an initial position of the first step as well as causing a distal end of the wire (4) to protrude from the lower end of the capillary (12) by a predetermined length, whereby a step of drawing out a leading end of the wire (4) from the capillary (12) is eliminated.

Abstract translation: 一种凸块形成方法，包括在从毛细管（12）的下端突出的线（4）的远端处形成球（5）的第一步骤; 打开夹持器（11）的第二步骤，其将毛细管（12）上方的丝线（4）牢固地保持在其上并使毛细管（12）以及夹持器（11）下降，其中钳位器 （11）的长度小于毛细管（12）的等于在第一步骤中从毛细管（12）的下端突出的线材（4）的长度的量; 通过接合从球（5）形成凸块（21）的第三步骤; 以及通过闭合所述夹持器（11）并将所述夹持器（11）和所述毛细管（21）提升到所述第一步骤的初始位置并且引起所述第一步骤的初始位置而将所述线（4）与所述凸块（21）分离的第四步骤 电线（4）的远端从毛细管（12）的下端突出预定的长度，从而从毛细管（12）抽出导线（4）的前端的步骤被消除。

公开(公告)号：KR100463482B1

公开(公告)日：2004-12-29

申请号：KR1020010068870

申请日：2001-11-06

Applicant: 제일모직주식회사

Inventor： 이병도 ,  장기보 ,  임광열 ,  전동원

IPC: C08J3/16

CPC classification number: C08J3/03

Abstract: A method of preparing a synthetic rubber latex which comprises: (a) pretreating a seed synthetic rubber latex with deionised water, an anionic emulsifier, a non-ionic emulsifier and an anti-foaming agent; (b) mixing an unsaturated acid-containing copolymer latex, having 10 to 50% by weight solids content, with deionized water and a pH controlling agent to produce an unsaturated acid-containing latex with 1 to 10% by weight solids content and a pH of 5 to 11; and (c) adding the latex of (a) to the latex of (b). The seed synthetic rubber latex preferably has particle sizes from 700-1500 Ñ and a solids content of from 30 to 50% by weight. The synthetic rubber latex may comprise polybutadiene, butadiene-styrene copolymer, butadiene- a -methyl styrene copolymer, butadiene-(meth)acrylate copolymer or mixtures thereof. The unsaturated acid monomer may comprise (meth)acrylic acid, methyl acrylic acid, itaconic acid, crotonic acid, fumaric acid or maleic acid.

Abstract translation: 一种制备合成橡胶胶乳的方法，该方法包括：＆lt; SL＆gt; （a）用去离子水，阴离子乳化剂，非离子乳化剂和消泡剂预处理种子合成橡胶胶乳; （b）将含有10至50重量％固体含量的不饱和含酸共聚物胶乳与去离子水和pH控制剂混合以产生含有1至10重量％固体的不饱和含酸胶乳 含量和5至11的pH; 和（c）将（a）的胶乳加入（b）的胶乳中。 ＆LT; / SL＆GT; 种子合成橡胶胶乳优选具有700-1500和Ntilde的粒度; 和30-50重量％的固体含量。 合成橡胶胶乳可以包含聚丁二烯，丁二烯 - 苯乙烯共聚物，丁二烯-α-甲基苯乙烯共聚物，丁二烯 - （甲基）丙烯酸酯共聚物或其混合物。 不饱和酸单体可以包含（甲基）丙烯酸，甲基丙烯酸，衣康酸，巴豆酸，富马酸或马来酸。

公开(公告)号：KR1020030034395A

公开(公告)日：2003-05-09

申请号：KR1020010065317

申请日：2001-10-23

Applicant: 제일모직주식회사

Inventor： 장기보 ,  이병도 ,  임광열 ,  박상규 ,  전동원 ,  이철호

IPC: C08C1/16

Abstract: PURPOSE: Provided is a method for producing coagulated particles of rubber latex excellent in stability, which shows small changes of particle diameter with the lapse of time. CONSTITUTION: The method comprises the steps of (i) forming a seed synthetic rubber latex by typical emulsion polymerization, (ii) mixing an ion-exchanged water, pH adjusting agent, and emulsifier into a unsaturated acid-containing copolymer latex having solid content of 10-50 wt%, to pre-treat the latex so as to have solid content of 1-10 wt% and pH of 3-11, (iii) introducing the pre-treated latex into the seed synthetic rubber latex formed from the step(i), and (iv) adding an ion-exchanged water, anionic emulsifier, nonionic emulsifier, antifoaming agent, and water-soluble polymer to the seed synthetic rubber latex. The method is characterized in that the water-soluble polymer is selected from the group consisting of polyethylene glycol having number average molecular weight of 200-20,000, copolymer of ethylene glycol and ethylene oxide, and a copolymer of polypropylene glycol and propylene glycol and ethylene oxide.

Abstract translation: 目的：提供稳定性优异的胶乳凝固粒子的方法，随着时间的推移，粒径的变化小。 构成：该方法包括以下步骤：（i）通过典型的乳液聚合形成种子合成橡胶胶乳，（ii）将离子交换水，pH调节剂和乳化剂混合到具有固体含量的不饱和酸的共聚物胶乳中 10-50重量％，以预处理胶乳以使固体含量为1-10重量％，pH为3-11，（iii）将预处理的胶乳引入由步骤 （i）中，和（iv）向种子合成橡胶胶乳中加入离子交换水，阴离子乳化剂，非离子乳化剂，消泡剂和水溶性聚合物。 该方法的特征在于，水溶性聚合物选自数均分子量为200-20,000的聚乙二醇，乙二醇和环氧乙烷的共聚物，以及聚丙二醇和丙二醇与环氧乙烷的共聚物 。

公开(公告)号：KR1020030013229A

公开(公告)日：2003-02-14

申请号：KR1020010068870

申请日：2001-11-06

Applicant: 제일모직주식회사

Inventor： 이병도 ,  장기보 ,  임광열 ,  전동원

IPC: C08J3/16

CPC classification number: C08J3/03

Abstract: PURPOSE: Provided is a process for producing a large particle-sized synthetic rubber latex having excellent stability and little time-change of particle size by adding a seed synthetic rubber latex to an unsaturated acid-contained copolymer latex. CONSTITUTION: The process contains the steps of: pre-treating the seed synthetic rubber latex by mixing and stirring the seed synthetic rubber latex with an anionic emulsifier, a non-ionic emulsifier, and a defoaming agent; mixing the unsaturated acid-contained copolymer latex having the solid content of 10-50wt% with ion exchange water and a pH controller to adjust the solid content of the copolymer latex to be 1-10wt% and pH to be 5-11; adding the pre-treated seed synthetic rubber latex to the adjusted unsaturated acid-contained copolymer latex for 30 minutes to 3 hours. The anionic emulsifier is selected from rosin acid soap, sodium lauryl sulfate, sodium oleate, and etc., the non-ionic emulsifier is selected from ethylene oxide-propylene oxide copolymers, polyoxyethylene octylphenyl ethers, polyoxyethylene nonylphenyl ethers, and the defoaming agent is selected from fatty alcohols, fatty acid esters, phosphate esters, and silicone oil emulsion.

Abstract translation: 目的：提供一种通过向含不饱和酸的共聚物胶乳中加入种子合成橡胶胶乳来制备具有优异的稳定性和较小的粒度时间变化的大粒径合成橡胶胶乳的方法。 方案：该方法包括以下步骤：通过用阴离子乳化剂，非离子乳化剂和消泡剂混合和搅拌种子合成橡胶胶乳预处理种子合成橡胶胶乳; 将具有10-50重量％固体含量的不饱和酸的共聚物胶乳与离子交换水和pH值调节剂混合，将共聚物胶乳的固体含量调节至1-10重量％，pH值为5-11; 将预处理的种子合成橡胶胶乳添加到调整后的不饱和酸的共聚物胶乳中30分钟至3小时。 阴离子乳化剂选自松香酸皂，月桂基硫酸钠，油酸钠等，非离子乳化剂选自环氧乙烷 - 环氧丙烷共聚物，聚氧乙烯辛基苯基醚，聚氧乙烯壬基苯基醚，并且选择消泡剂 来自脂肪醇，脂肪酸酯，磷酸酯和硅油乳液。