公开(公告)号：KR1020120007113A

公开(公告)日：2012-01-20

申请号：KR1020100067684

申请日：2010-07-14

Applicant: 충남대학교산학협력단

Inventor： 손영아 ,  김병순

IPC: C09B59/00 ,  C09B62/00

CPC classification number: C09B55/002 ,  C07C211/54 ,  C09B55/007 ,  G01N21/00

Abstract: PURPOSE: A triphenylamine based dye for detecting heavy metal ions is provided to synthesis a dye chromophore on the basis of triphenylamine derivatives. CONSTITUTION: A triphenylamine based dye compound A is in the chemical formula 1, which is manufactured by reacting a benzoxazole group compound into triphenylamine monoaldehyde. A triphenylamine based dye compound B is in the chemical formula 2, which is manufactured by reacting a benzoxazole group compound into triphenylamine dialdehyde.

Abstract translation: 目的：提供用于检测重金属离子的三苯胺系染料，以三苯胺衍生物为基础合成染料发色团。 构成：三苯胺系染料化合物A为化学式1，其通过使苯并恶唑基化合物与三苯胺单醛反应制造。 三苯胺系染料化合物B为化学式2，其通过使苯并恶唑基化合物与三苯基胺二醛反应制造。

公开(公告)号：KR101219472B1

公开(公告)日：2013-01-11

申请号：KR1020100067684

申请日：2010-07-14

Applicant: 충남대학교산학협력단

Inventor： 손영아 ,  김병순

IPC: C09B59/00 ,  C09B62/00

Abstract: 본 발명은 중금속 이온 검출용 트리페닐아민계 염료 화합물 및 이를 활성 성분으로 포함하는 중금속 이온 검출용 염료 센서에 관한 것이다. 더욱 상세하게는 상기 트리페닐아민계 염료 화합물이 수은 +2가 이온, 구리 +2가 이온 또는 아연 +2가 이온과 결합하여 염료 금속 복합체를 형성함으로써 이에 따른 염료 화합물의 흡광 및 발광 스펙트럼의 변화를 통한 중금속 이온 검출용 염료 센서에 관한 것이다.

公开(公告)号：KR1020120007112A

公开(公告)日：2012-01-20

申请号：KR1020100067681

申请日：2010-07-14

Applicant: 충남대학교산학협력단

Inventor： 손영아 ,  김병순 ,  김영성

IPC: C09B59/00 ,  C09B62/00

CPC classification number: C09B55/005 ,  G01N21/00

Abstract: PURPOSE: A benz-X-azole dye for detecting heavy metal ions, and a producing method thereof are provided to apply the benz-X-azole dye to a dye chemical sensor for the heavy metal ions. CONSTITUTION: A producing method of benz-X-azole dye A and B marked with chemical formula 1 or 2, respectively comprises the following steps: reacitng p-aminosalicylic acid with o-aminophenol or o-aminothiophenol to obtain a first benz-X-azole based intermediate and a second benz-X-azole based intermediate; reacting the first benz-X-azole based intermediate with terephthaldehyde to obtain the benz-X-azole dye A; and reacting the second benz-X-azole based intermediate with the terephthaldehyde to obtain the benz-X-azole dye B.

Abstract translation: 目的：提供一种用于检测重金属离子的苯并噻唑染料及其制备方法，以将苯并吡唑染料施用于重金属离子的染料化学传感器。 构成：以化学式1或2表示的苯并吡唑染料A和B的制备方法分别包括以下步骤：用邻氨基苯酚或邻氨基苯硫酚反应对氨基水杨酸，得到第一次苯 - 基于唑基的中间体和第二苯并咪唑基中间体; 使第一基于苯并噻唑的中间体与对苯二甲醛反应得到苯并-Z-吡唑染料A; 并使第二苯基-N-唑基中间体与对苯二甲醛反应，得到苯并-Z-吡唑染料B.