公开(公告)号：KR1020010037774A

公开(公告)日：2001-05-15

申请号：KR1019990045462

申请日：1999-10-20

Applicant: 한국과학기술연구원

Inventor： 박대원 ,  손성호 ,  정도원 ,  장원석

IPC: C02F1/461

Abstract: PURPOSE: Disclosed is an apparatus for treating wastewater electrochemically, in particular for treating high concentration wastewater by using electrolytic oxidation reaction adopting insoluble catalytic electrodes and a conductive floating catalyst, thereby free of additional chemicals or processes. CONSTITUTION: A reactor mainly consists of a power supplying means (1), an aerator (6), a plurality of air injection holes (10), a plurality of cathodes (4), a plurality of anodes (2). Wastewater which is stored in a storage basin (5) flows into the reactor (9) through an inlet port (8), and discharged through an outlet port (7) after contacting with anodes, cathodes, and conductive floating catalyst (3). The anode made by immobilizing Ru-Ir-Sn oxides on the surface of titanium plate decomposes organics and color-causing materials, dissolved heavy metals in wastewater are electrodeposited on the surface of cathode made of iron or nickel plate. Also, the floating titanium/iron catalyst coated with iron oxides accelerates organics decomposition through chemical reaction with hydrogen peroxide generated in the surface of anodes. In the reactor, anodes and cathodes are installed to be different height each other for maximizing contacting area between wastewater and each electrode, and aeration is accompanied to both separate bubbles generated in the each electrode and maintain wastewater flow stable.

Abstract translation: 目的：公开了一种电化学处理废水的设备，特别是通过采用不溶性催化电极和导电浮动催化剂的电解氧化反应处理高浓度废水，从而无需额外的化学品或工艺。 构成：电抗器主要由供电装置（1），曝气器（6），多个空气注入孔（10），多个阴极（4），多个阳极（2）组成。 存储在储存池（5）中的废水通过入口（8）流入反应器（9），并在与阳极，阴极和导电浮动催化剂（3）接触后通过出口（7）排出。 通过将Ru-Ir-Sn氧化物固定在钛板表面上制成的阳极分解有机物和着色材料，将废水中溶解的重金属电沉积在由铁或镍板制成的阴极表面。 此外，用铁氧化物涂覆的浮动钛/铁催化剂通过与在阳极表面产生的过氧化氢的化学反应加速有机物分解。 在反应器中，阳极和阴极安装成彼此不同的高度，以使废水和每个电极之间的接触面积最大化，并且曝气伴随着在每个电极中产生的两个分离的气泡并且维持废水流动稳定。

公开(公告)号：KR100310272B1

公开(公告)日：2001-11-14

申请号：KR1019990045462

申请日：1999-10-20

Applicant: 한국과학기술연구원

Inventor： 박대원 ,  손성호 ,  정도원 ,  장원석

IPC: C02F1/461

Abstract: 본발명은불용성산화물촉매전극의전해산화반응을이용한폐수내의유기물, 중금속, 암모니아, 질소및 폐수의색도및 냄새등을제거하기위한전기화학적폐수처리장치에관한것이다. 본발명의전기화학적폐수처리장치는반응의효율성을높이기위해음극과양극이서로높이를달리하여교차배열되고, 반응기하부에는폭기장치가설치되며, 전극사이에는입상또는판상촉매가유동되도록설계되어있다. 상기양극은오염물질의산화효율을보다촉진할수 있도록이리듐-주석, 루테늄-주석, 루테늄-이리듐-주석또는루테늄-이리듐-주석-안티몬등으로이루어진산화물층을티타늄에형성시켜제조한다. 또한, 전해산화처리시간을단축하고효율성을높이기위해티타늄및 탄소에철산화물층을형성시킨입상또는판상촉매를사용한다.