公开(公告)号：KR1020040110642A

公开(公告)日：2004-12-31

申请号：KR1020030040045

申请日：2003-06-20

Applicant: 한국과학기술연구원

Inventor： 박송자 ,  표희수 ,  홍지은 ,  윤소희

IPC: G01N30/00

Abstract: PURPOSE: A method for determination of amitrole is provided to analyze amitrole in a water sample to the extent in extremely small quantities rapidly and economically. CONSTITUTION: The method for determination of amitrole in a water sample comprises the step of: concentration of the water sample, derivatization by isobutyl chloroformate and analysis of amitrole by a gas chromatography or a gas chromatography/mass spectrometer. In the method, the concentration step is carried out by employing a rotary vacuum evaporator, the derivatization step comprises adding 40-60 l of isobutyl chloroformate to the concentrated sample to react the resultant at room temperature for 15 to 20 min. or comprises dissolving the concentrated sample in 150-250 l of methylene chloride and then adding thereto, 40-60 l of isobutyl chloroformate to react the resultant at room temperature for 15 to 20 min.

Abstract translation: 目的：提供一种测定阿米罗的方法，用于在水样中分析阿米曲坦，其数量极快，经济。 构成：在水样中测定阿米洛尔的方法包括以下步骤：浓缩水样品，用氯甲酸异丁酯衍生化，用气相色谱或气相色谱/质谱仪分析阿米洛尔。 在该方法中，通过使用旋转式真空蒸发器进行浓缩步骤，该衍生步骤包括向浓缩样品中加入40-60升氯甲酸异丁酯，使反应物在室温下反应15至20分钟。 或者将浓缩的样品溶解在150-250μl二氯甲烷中，然后向其中加入40-60μl氯甲酸异丁酯，使所得物在室温下反应15至20分钟。

公开(公告)号：KR100537402B1

公开(公告)日：2005-12-19

申请号：KR1020030044460

申请日：2003-07-02

Applicant: 한국과학기술연구원

Inventor： 박송자 ,  표희수 ,  홍지은

IPC: G01N30/00

Abstract: 본 발명은 뇨 시료 중에 함유된 히드록시 PCBs (hydroxy polychlorinated biphenyls)를 동시 분석하기 위하여, 고상 미량추출 (SPME, solid-phase microextraction)을 이용하여 추출하는 방법을 사용하여 추출 후 연속적으로 SPME 파이버 (fiber) 상에서 TMS 유도체화하여 분석하는 것을 특징으로 한다. 본 발명에서 기체 크로마토그래피 또는 기체 크로마토그래피/질량 분석기를 사용하여 히드록시 PCBs의 농도를 분석한다. 본 발명의 방법에 의해 뇨 시료을 분석할 경우 우수한 감도, 분석 시간의 단축, 간편성 및 경제성을 얻을 수 있을 뿐만 아니라, 추출용매 사용시 발생되는 2차 오염을 방지할 수 있다.

公开(公告)号：KR1020030078097A

公开(公告)日：2003-10-08

申请号：KR1020020016909

申请日：2002-03-28

Applicant: 한국과학기술연구원

Inventor： 박송자 ,  표희수 ,  신혜승 ,  홍지은

IPC: G01N33/18

Abstract: PURPOSE: A simultaneous detection method of Glyphosate, Endothall and Chloramben as herbicides in water samples is provided, thereby easily, accurately and cheaply detecting the herbicides at one time. CONSTITUTION: A simultaneous detection method of Glyphosate, Endothall and Chloramben as herbicides in water samples comprises the steps of: concentrating Glyphosate, Endothall and Chloramben and forming their derivatives with anhydrous trifluoroacetic acid and trifluoroethanol; analyzing their derivatives to prepare a measuring curve for determination of the concentrations of three herbicides; forming derivatives of three herbicides in various environmental samples; and determining the concentrations of three herbicides, wherein the concentration is carried out by using vaporization under vacuum; the formation of derivatives of three herbicides is carried out by heating the mixture of herbicides with trifluoroacetic acid and trifluoroethanol at 60 to 90 deg. C for 30 to 120 minutes; and the concentration of three herbicides is determined by using gas chromatography/mass spectrometer.

Abstract translation: 目的：提供水样中草甘膦，Endothall和Chloramben作为除草剂的同时检测方法，从而同时容易，准确，廉价地检测除草剂。 构成：水样中草甘膦，Endothall和Chloramben作为除草剂的同时检测方法包括以下步骤：浓缩草甘膦，Endothall和Chloramben，并用无水三氟乙酸和三氟乙醇形成其衍生物; 分析其衍生物以制备测定三种除草剂浓度的测量曲线; 在各种环境样品中形成三种除草剂的衍生物; 并确定三种除草剂的浓度，其中浓度通过在真空下蒸发进行; 通过将除草剂与三氟乙酸和三氟乙醇的混合物在60至90℃加热来进行三种除草剂的衍生物的形成。 C为30〜120分钟; 并通过使用气相色谱/质谱仪测定三种除草剂的浓度。

公开(公告)号：KR100537403B1

公开(公告)日：2005-12-19

申请号：KR1020030040045

申请日：2003-06-20

Applicant: 한국과학기술연구원

Inventor： 박송자 ,  표희수 ,  홍지은 ,  윤소희

IPC: G01N30/00

Abstract: 본 발명은 수질 시료 내에 잔류하는 제초제인 아미트롤을 분석하는 방법에 관한 것으로, 보다 구체적으로는 수질 시료를 직접 진공회전증발기로 완전히 증발 및 농축시킨 후, 이소부틸 클로로포르메이트를 사용해서 실온에서 15분 내지 20분간 반응시켜 유도체화하고, 기체 크로마토그래피(GC) 또는 기체 크로마토그래피(GC)/질량 분석기(MS)를 사용하여 아미트롤의 농도를 분석하는 단계를 포함하는 이미트롤의 검출법에 관한 것이다. 본 발명의 방법에 따라 수질 시료에서 아미트롤의 농도를 분석할 경우 우수한 감도, 분석 시간의 단축, 간편성 및 경제성을 동시에 얻을 수 있다.

公开(公告)号：KR1020050004322A

公开(公告)日：2005-01-12

申请号：KR1020030044460

申请日：2003-07-02

Applicant: 한국과학기술연구원

Inventor： 박송자 ,  표희수 ,  홍지은

IPC: G01N30/00

Abstract: PURPOSE: Provided is a method for determining hydroxy polychlorinated biphenyls in urine, which is excellent in sensitivity, accuracy, convenience and economical efficiency of time and cost. CONSTITUTION: The method for determining a concentration of hydroxy polychlorinated biphenyls(PCBs) in urine comprises the steps of: adsorption of hydroxy polychlorinated biphenyls in urine onto fibers of solid-phase microextraction(SPME); derivatization of the hydroxy polychlorinated biphenyls adsorbed on the fibers of solid-phase microextraction using trimethylsilyl; and analysis of trimethylsilyl-derived hydroxy polychlorinated biphenyls by gas chromatography or gas chromatography/mass spectrometer. The adsorption step is carried out at a position of headspace at a temperature of 90 deg.C or above for at least 60 minutes and the derivatization step is carried out at the position of headspace at a temperature of 60 deg.C for 5 to 30 minutes.

Abstract translation: 目的：提供尿液中羟基多氯联苯的测定方法，灵敏度，准确度，方便性和经济效益均优于时间和成本。 构成：尿中羟基多氯联苯（PCBs）浓度测定方法包括以下步骤：将尿中的羟基多氯联苯吸附到固相微萃取（SPME）纤维上; 使用三甲基甲硅烷基吸附在固相微萃取纤维上的羟基多氯联苯的衍生化; 并通过气相色谱或气相色谱/质谱仪分析三甲基甲硅烷基衍生的羟基多氯联苯。 吸附步骤在90℃或更高温度的顶部空间位置进行至少60分钟，衍生步骤在60℃的顶部空间位置进行5至30 分钟。

公开(公告)号：KR100461702B1

公开(公告)日：2004-12-14

申请号：KR1020020016909

申请日：2002-03-28

Applicant: 한국과학기술연구원

Inventor： 박송자 ,  표희수 ,  신혜승 ,  홍지은

IPC: G01N33/18

Abstract: PURPOSE: A simultaneous detection method of Glyphosate, Endothall and Chloramben as herbicides in water samples is provided, thereby easily, accurately and cheaply detecting the herbicides at one time. CONSTITUTION: A simultaneous detection method of Glyphosate, Endothall and Chloramben as herbicides in water samples comprises the steps of: concentrating Glyphosate, Endothall and Chloramben and forming their derivatives with anhydrous trifluoroacetic acid and trifluoroethanol; analyzing their derivatives to prepare a measuring curve for determination of the concentrations of three herbicides; forming derivatives of three herbicides in various environmental samples; and determining the concentrations of three herbicides, wherein the concentration is carried out by using vaporization under vacuum; the formation of derivatives of three herbicides is carried out by heating the mixture of herbicides with trifluoroacetic acid and trifluoroethanol at 60 to 90 deg. C for 30 to 120 minutes; and the concentration of three herbicides is determined by using gas chromatography/mass spectrometer.

Abstract translation: 目的：提供了草甘膦，Endothall和Chloramben在水样中作为除草剂的同时检测方法，从而容易，准确且便宜地检测除草剂。 本发明涉及草甘膦，Endothall和Chloramben在水样中作为除草剂的同时检测方法，包括以下步骤：浓缩草甘膦，Endothall和Chloramben并用无水三氟乙酸和三氟乙醇形成它们的衍生物; 分析它们的衍生物以制备用于测定三种除草剂浓度的测量曲线; 在各种环境样品中形成三种除草剂的衍生物; 并测定三种除草剂的浓度，其中浓缩通过在真空下蒸发进行; 三种除草剂的衍生物的形成通过在60至90℃加热除草剂与三氟乙酸和三氟乙醇的混合物来进行。 C 30至120分钟; 并且通过使用气相色谱/质谱仪确定三种除草剂的浓度。