Abstract:
A supported catalyst for propylene polymerization is provided to ensure high molecular weight and high melting point through interaction without a catalyst of a complicated structure and to control the stereoregularity of the propylene polymer by controlling catalyst structure and polymerization condition. A supported catalyst for propylene polymerization comprises a catalyst and a carrier supporting the catalyst. The catalyst comprises (a) a transition metal compound represented by chemical formula 1 and (b) a compound selected from the group consisting of an aluminoxane compound represented by chemical formula 2 and an organic aluminum compound by chemical formula 3. A method for manufacturing the propylene polymer comprises a step for polymerizing propylene single or copolymerizing a compound having a double bond and propylene.
Abstract:
본 발명은 (i) (a) 화학식 Cp 1 Cp 2 MX p 로 표시되는 메탈로센계 전이금속 화합물; 및 (b) 알루미녹산 화합물 및/또는 유기 알루미늄 화합물을 포함하는 촉매; 및 (ii) 상기 (i)의 촉매가 담지되는 담체를 포함하는 프로필렌 중합용 담지 촉매에 관한 것이다. 또한, 본 발명은 상기 프로필렌 중합용 담지 촉매 또는 비담지 촉매의 존재 하에서, 프로필렌을 단독 중합시키거나 또는 이중 결합을 포함하는 화합물과 프로필렌을 공중합시키는 것을 포함하는 프로필렌 중합체의 제조방법 및 이에 따라 제조되는 프로필렌 중합체에 관한 것이다.
Abstract:
폴리올레핀계 트리아릴아민 고분자가 제공된다. 본 발명에 의하면, 유기금속촉매를 이용한 중합법에 의해, 우수한 열적 안정성과 정공수송능력 및 유연성을 가지기 때문에 플렉시블 기판에 적용가능한 폴리올레핀계 트리아릴아민 고분자를 제공할 수 있으며, 이러한 고분자 물질을 이용하여 제조된 유기발광 다이오드와 태양전지 등의 전자소자는 높은 효율과 안정성을 가진다.
Abstract:
하기화학식 1 로표시되는카보레인화합물이제공된다. (R1)-CB-[Ar]-CB-(R)상기식 중, CB는카보레인이고, Ar은치환또는비치환된페닐렌기이고, R, R, a, b 및 n은상세한설명을참조한다. 상기카보레인화합물을포함하는유기층을구비한유기발광소자는높은발광효율을가진다.
Abstract:
An olefinic triarylamine monomer is provided to ensure excellent thermal stability and flexibility, and to prepare polyolefin-based triarylamine polymer applicable to a flexible substrate. An olefinic triarylamine monomer has a structure of chemical formula 1 or 2. In chemical formulas, n1 is an integer of 1-20 and n2 is an integer of 0-20; Z is methylene, methylether, methylthioether, carbonyl, carboxyl or amide; and Ar1~Ar3 are any one selected from C6-40 aryl group, arylalkyl group, alkylaryl group, arylsilyl group, arylalkylsilyl group, haloaryl group, aryloxy group, aryloxoalkyl group, thioaryloxoalkyl group, aryloxoaryl group, arylamino group, arylaminoalkyl group, arylaminoaryl group, arylphosphinoalkyl group, diarylamido group, and triarylamido group.
Abstract translation:提供烯烃三芳基胺单体以确保优异的热稳定性和柔韧性,并制备适用于柔性基材的聚烯烃基三芳基胺聚合物。 烯烃三芳基胺单体具有化学式1或2的结构。在化学式中,n1为1-20的整数,n2为0〜20的整数。 Z是亚甲基,甲基醚,甲硫醚,羰基,羧基或酰胺; Ar 1〜Ar 3为选自C 6〜40芳基,芳烷基,烷基芳基,芳基甲硅烷基,芳烷基甲硅烷基,卤代芳基,芳氧基,芳氧基烷基,硫代芳氧基烷基,芳氧基芳基,芳基氨基,芳基氨基烷基,芳基氨基芳基 ,芳基膦基烷基,二芳基酰氨基和三芳基酰胺基。
Abstract:
A metallocene catalyst absorbed into carbon nanotube is provided to be used for preparing a polymer compound having a very high molecular weight in accordance with the polymerization condition using an aluminoxane compound and an organoaluminum compound as a co-catalyst. A metallocene catalyst adsorbed into carbon nanotube is represented by the formula(1), wherein CNT is at least one carbon nanotube selected from the group consisting of a single-walled carbon nanotube, a double-walled carbon nanotube and a multi-walled carbon nanotube, Cp1 is a ligand having a cyclopentadienyl skeleton which is unsubstituted or substituted by at least one substituent selected from the group consisting of C1-20 alkyl, C3-20 cycloalkyl, C1-20 alkylsily, C1-20 haloalkyl, C6-20 aryl, C6-20 arylalkyl, C6-20 arylsilyl, C6-20 alkylaryl, C1-20 alkoxy, C1-20 alkylsiloxy, C6-20 aryloxy, halogen and amino, provided that a cyclic compound may be formed by binding between the substituents when the ligand is substituted by at least two substituents, M is an element of group III to X in a periodic table, each X, Y and Z is independently one kind selected from the group consisting of C1-20 alkyl, C3-20 cycloalkyl, C1-20 alkylsily, C1-20 haloalkyl, C6-20 aryl, C6-20 arylalkyl, C6-20 arylsilyl, C6-20 alkylaryl, C1-20 alkoxy, C1-20 alkylsiloxy, C6-20 aryloxyl, halogen, amino, tetrahydroborate and the Cp1, provided that the CNT and Cp1 are linked by absorption. A method for polymerizing olefin comprises the steps of: (a) dissolving a metallocene main catalyst absorbed into carbon nanotube and a co-catalyst thereof in a solvent; and (b) injecting olefin gas into the reaction solution obtained from the step (a) and subjecting it under a polymerization reaction under a temperature of -50-200 deg.C and a pressure of 1.0-3,000.
Abstract:
PURPOSE: A carborane compound with high luminous efficiency, organic electroluminescent device including the same and a flat panel display device including the organic electroluminescent device are provided to enhance product efficiency and light emitting efficiency. CONSTITUTION: A carborane compound is represented by chemical formula 1. The chemical formula 1 is as follows: (R1) a-CB - [Ar] n-CB - (R2) b. Here, CB is carborane, R1 and R2 are respectively selected from hydrogen, deuterium, halogen, hydroxyl, cyano, nitro, nitrile, carboxy, substitution or non-substituted C1-30 alkyl, substituted or non-substituted C2-30 alkenyl, substituted or non-substituted C2-30 alkynyl, substituted or non-substituted C1-30 alkoxy, substituted or non-substituted C3-30 cycloalkyl, substituted or non-substituted C3-30 cycloalkenyl, substituted or non-substituted C5-30 aryl, substituted or non-substituted C2-30 heteroaryl, substituted or non-substituted C5-30 aryloxy, substituted or non-substituted C1-30 acyl, substituted or non-substituted C1-30 amide, substituted or non-substited C2-30 ester, substituted or non-substituted C5-30 arylthio and N (Q1) (Q2). [Reference numerals] (AA) Wavelength(nm)
Abstract:
PURPOSE: A dinuclear metallocene catalyst is provided to easily control the molecular weight of high activity through the formation of a polymer chain in the center of two metals in the catalyst. CONSTITUTION: A dinuclear metallocene catalyst comprises a main catalyst and a co-catalyst. The main catalyst is the metallocene compound of chemical formula 1 comprising chemical formula 2: Ar-B^2-Ar. The co-catalyst, which is an alkylaluminoxane compound, an organic aluminum compound, or a weekly coordinated Lewis acid aluminum compound, or weekly coordinated Lewis acid compound, is a compound for obtaining catalyst activity by reacting with the main catalyst. In the chemical formula 2, Ar is C6-20 arylene group which directly bonds to Cp, B^2 is a C1-20 alkylene group, a C3-20 cycloalkenylene group, a C1-20 alkylsilylene group, a C1-20 haloalkylene group, a C6-20 arylalkylene group, or a C6-20 arylsilylene group.