Abstract:
본 발명은 식물병원균에 대하여 우수한 살균활성을 갖는 다음 구조식(I)로 표시되는 신규한 4H, 6H-피롤로[3,4-c]이소옥사졸 유도체와 이를 제조하는 방법에 관한 것이다.
상기식에서, R 1 은 페닐기 또는 할로겐원자나 C 1 ~C 3 알킬기로 치환된 페닐기이고, R 2 는 C 1 ~C 5 알킬기, 페닐기, 치환된 페닐기 또는 C 1 ~C 3 알콕시기이며, 이때 치환된 페닐기의 치환기는 할로겐원자, C 1 ~C 3 알킬기 또는 C 1 ~C 3 알콕시기이다.
Abstract:
The preparation method of isooxazol (I) dervatives which has antifungal activity consists of 1) reacting nitro-olefin and alcohol with basic catalyst to form nitro compounds, 2) dehydrating nitro compounds with triethylamine and phenylisocyanate to form cycles as (I) in benzene or dichlromethane. Derivatives of (I) are R1 = propyl or isopropyl, R2 = H or methyl, R3 = H, methyl, ethyl, phenyl, phenyl chloride, aldehyde, or oxime.
Abstract:
Halo alcohol compound is halogenated by trihalophosphate in diethylether as solvent to yield dihalogented compound, thereafter, yielded compound is reacted with amines of R2-NH2 in the presence of base such as sodium carbonate and potassium carbonate in organic solvent such as ethanol, dimethyl formamide and dimethyl sulfoxide to yield compound represented by general formula(I). In general formula(I), R1 represents phenyl group or halogen atoms, R2 represents alkyl group having 1 to 5 of carbon atoms.
Abstract:
2-Oxyamino alkylidene-cyclohexane-1,3-dione derivs. of formula (I) are prepd. by reacting a cpd. of formula (II) with a substd. alkoxy amine or its acid addn. salt of formula H2N-OR4. In the formulas, R and R1 are each H, C1-3 lower alkoxy, OH, acetoxy or halogen; R2 is H; R3 is C2-3 alkyl or alkenyl; R4 is C1-3 lower alkyl or alkenyl. (I) have a good herbicidal effect.