公开(公告)号：KR1020010046624A

公开(公告)日：2001-06-15

申请号：KR1019990050460

申请日：1999-11-13

Applicant: 한국화학연구원

Inventor： 유영문 ,  정석종 ,  이성영 ,  아게예프알렉산더유

IPC: C30B29/00

CPC classification number: C01F17/0012 ,  C30B15/203 ,  C30B29/10

Abstract: PURPOSE: A crystalline solid material, a method for growing its crystal, an optical device prepared by using the crystal, and a method for preparing the optical device are provided, which solid material is erbium and ytterbium ions-doped ytterbium calcium oxyborate. CONSTITUTION: The crystalline solid material is represented by the formula: (Er(x)Yb(y)Y(1-x-y))Ca(4+z)B3O(10+z), wherein x is 0.005-0.10, y is 0.005-0.30 and z is 0.00-0.5. The crystal of the solid material is grown with the temperature gradient of 5-300 deg.C/cm by Czochralski method with the increasing velocity of 0.1-10mm/hr and the rotation velocity of 0-70 rpm. A YCa4O(BO3)3 crystal is used as a crystal seed. The solid material crystal is single crystal or thin film crystal. The optical device is a 1.5-1.6 micrometers laser generating device, a nonlinear optical device, a self frequency doubling device or a range finding device.

Abstract translation: 目的：提供一种结晶固体材料，其晶体生长方法，使用晶体制备的光学器件，以及制备该光学器件的方法，该固体材料是铒和镱离子掺杂的硼酸镱钙矾土。 结构：结晶固体材料由下式表示：（Er（x）Yb（y）Y（1-xy））Ca（4 + z）B3O（10 + z），其中x为0.005-0.10，y为 0.005-0.30，z为0.00-0.5。 固体材料的晶体通过Czochralski法以5-300摄氏度/厘米的温度梯度生长，其速度为0.1-10毫米/小时，旋转速度为0-70转/分钟。 使用YCa4O（BO3）3晶体作为晶种。 固体材料晶体是单晶或薄膜晶体。 光学装置是1.5-1.6微米的激光产生装置，非线性光学装置，自倍频装置或测距装置。

公开(公告)号：KR100351634B1

公开(公告)日：2002-09-11

申请号：KR1019990050460

申请日：1999-11-13

Applicant: 한국화학연구원

Inventor： 유영문 ,  정석종 ,  이성영 ,  아게예프알렉산더유

IPC: C30B29/00

Abstract: 본발명은에르븀과이터비움이온이주입된이트리움칼슘옥시보레이트화합물및 이의결정성장방법, 그리고이러한결정을사용하여제조된광기능소자에관한것이다. 더욱상세하게는 YCaO(BO)의화학식으로표현되는공간군 Cm의단사결정구조의이트륨칼슘옥시보레이트화합물(이하, 'YCOB'라함)에서의산소 6배위를갖는결정학적자리에놓여져있는 Y을가장우수한물성을가질수 있는적절한치환양만큼 Er및 Yb이온으로각각치환시켜얻은신규결정성고체화합물과, Er및 Yb이온을결정격자속에서균일하게분산되고안정하게존재하도록하면서상기한고체화합물을낮은밀도의결정결함을가지는높은품질의결정으로성장시키는방법, 그리고상기한결정이나타내는레이저및 분광학적물성을활용함으로써얻어질수 있는 1.5 ∼ 1.6 ㎛레이저발진봉소자, 비선형광학소자, 자기반주파수변조(self frequency doubling) 소자, 측거기(range finding) 소자등의광기능소자에관한것이다.