公开(公告)号：KR100435512B1

公开(公告)日：2004-06-10

申请号：KR1020010046592

申请日：2001-08-01

Applicant: 한국화학연구원

Inventor： 최길영 ,  이미혜 ,  이재흥 ,  원종찬 ,  이선순

IPC: C01B33/26

Abstract: PURPOSE: Organic aluminosilicate based lamellar inorganic materials which are usefully used as a core material of various ultramodern industries such as electric, electronic, space and aviation industries by having superior heat resistance and organic affinity and low hygroscopic, and a method for preparing the same are provided. CONSTITUTION: In organic lamellar inorganic materials in which organic polymers are introduced between layers of aluminosilicate based lamellar inorganic materials, the organic aluminosilicate based lamellar inorganic materials are characterized in that the organic polymers introduced between layers of the aluminosilicate based lamellar inorganic materials are low polarity siloxane amine oligomer selected from siloxane amine oligomers represented as in chemical formulae 1a and 1b and siloxane amine oligomer in which alkyl group produced by reaction of alkyl carbonyl chloride is substituted represented as in chemical formula 2, where R1 and R2 are -(CH2)pX1(CH2)q- or formula 3 respectively, wherein X1 is -CH2- or -O-; R is -(CH2)nX2(CH2)k-, wherein X2 is -CH2- or -CH=CH-; l and m are an integral number between 1 to 300 respectively, and p, q, n and k are an integral number between 1 to 30 respectively.

Abstract translation: 目的：有机铝硅酸盐基片状无机材料由于具有优异的耐热性和有机亲和性以及低吸湿性而被有效地用作各种超现代工业如电力，电子，航天和航空工业的核心材料，以及其制备方法是 提供。 组成：在有机层状无机材料中，有机聚合物被引入到硅铝酸盐基层状无机材料层之间，有机硅酸铝基层状无机材料的特征在于，引入硅铝酸盐基层状无机材料层之间的有机聚合物是低极性硅氧烷 选自如化学式1a和1b所示的硅氧烷胺低聚物的胺低聚物和其中由烷基碳酰氯的反应产生的烷基被取代的硅氧烷胺低聚物，如化学式2所示，其中R1和R2是 - （CH2）pX1（ CH2）q-或式3，其中X1是-CH2-或-O-; R是 - （CH2）nX2（CH2）k-，其中X2是-CH2-或-CH = CH-; l和m分别是1到300之间的整数，p，q，n和k分别是1到30之间的整数。

公开(公告)号：KR1020020065776A

公开(公告)日：2002-08-14

申请号：KR1020010005957

申请日：2001-02-07

Applicant: 한국화학연구원

Inventor： 최길영 ,  이미혜 ,  이선순 ,  김은경

IPC: C08K3/36

Abstract: PURPOSE: Provided are an organized, inorganic material having improved heat resistance and organizing property, which can be used as a key composite material of high-tech industry such as various electric, electronic, (aero)space industry, aero industries. CONSTITUTION: The organized, layered inorganic material consists of a layered inorganic material based on aluminosilicate, and an organic polymer positioned between layers of the inorganic material. The organic polymer is a low-polar siloxane amine oligomer selected from polysiloxane amine represented by formula 1a, 1b and 1c. In the formulae, each of R1 and R2 is -(CH2)nX(CH2)k-; X is -CH2- or -O-; each of l, m, k is an integer of 1-300. The siloxane amine oligomer has weight average molecular weight(Mw) of 1,000-50,000 g/mol, and equivalent weight of functionality of 500-25,000 g/eq.

Abstract translation: 目的：提供具有改善的耐热性和组织性的有组织的无机材料，可用作各种电气，电子，（航空）航天工业，航空工业等高科技行业的关键复合材料。 构成：有组织的层状无机材料由基于硅铝酸盐的层状无机材料和位于无机材料层之间的有机聚合物组成。 有机聚合物是选自由式1a，1b和1c表示的聚硅氧烷胺的低极性硅氧烷胺低聚物。 在该式中，R 1和R 2各自为 - （CH 2）n X（CH 2）k - ; X是-CH 2 - 或-O-; l，m，k中的每一个为1-300的整数。 硅氧烷胺低聚物的重均分子量（Mw）为1,000-50,000g / mol，官能度当量为500-25,000g / eq。

公开(公告)号：KR1020030012536A

公开(公告)日：2003-02-12

申请号：KR1020010046592

申请日：2001-08-01

Applicant: 한국화학연구원

Inventor： 최길영 ,  이미혜 ,  이재흥 ,  원종찬 ,  이선순

IPC: C01B33/26

CPC classification number: C01B33/26 ,  C01P2002/20

Abstract: PURPOSE: Organic aluminosilicate based lamellar inorganic materials which are usefully used as a core material of various ultramodern industries such as electric, electronic, space and aviation industries by having superior heat resistance and organic affinity and low hygroscopic, and a method for preparing the same are provided. CONSTITUTION: In organic lamellar inorganic materials in which organic polymers are introduced between layers of aluminosilicate based lamellar inorganic materials, the organic aluminosilicate based lamellar inorganic materials are characterized in that the organic polymers introduced between layers of the aluminosilicate based lamellar inorganic materials are low polarity siloxane amine oligomer selected from siloxane amine oligomers represented as in chemical formulae 1a and 1b and siloxane amine oligomer in which alkyl group produced by reaction of alkyl carbonyl chloride is substituted represented as in chemical formula 2, where R1 and R2 are -(CH2)pX1(CH2)q- or formula 3 respectively, wherein X1 is -CH2- or -O-; R is -(CH2)nX2(CH2)k-, wherein X2 is -CH2- or -CH=CH-; l and m are an integral number between 1 to 300 respectively, and p, q, n and k are an integral number between 1 to 30 respectively.

Abstract translation: 目的：通过具有优异的耐热性和有机亲和力以及低吸湿性有机地用作电气，电子，空间和航空工业等各种超现代工业的核心材料的有机铝硅酸盐基层状无机材料及其制备方法 提供。 构成：在硅酸铝基层状无机材料层之间引入有机聚合物的有机层状无机材料中，有机硅铝酸盐层状无机材料的特征在于，在硅铝酸盐基层状无机材料层之间引入的有机聚合物是低极性硅氧烷 选自由化学式1a和1b表示的硅氧烷胺低聚物的胺低聚物和其中取代由烷基碳酰氯反应生成的烷基的硅氧烷胺低聚物如化学式2表示，其中R1和R2是 - （CH2）pX1（ CH 2）q-或式3，其中X 1是-CH 2 - 或-O-; R是 - （CH 2）n X 2（CH 2）k - ，其中X 2是-CH 2 - 或-CH = CH-; 1和m分别为1至300之间的整数，p，q，n和k分别为1至30之间的整数。

公开(公告)号：KR100379758B1

公开(公告)日：2003-04-10

申请号：KR1020010005957

申请日：2001-02-07

Applicant: 한국화학연구원

Inventor： 최길영 ,  이미혜 ,  이선순 ,  김은경

IPC: C08K3/36

Abstract: PURPOSE: Provided are an organized, inorganic material having improved heat resistance and organizing property, which can be used as a key composite material of high-tech industry such as various electric, electronic, (aero)space industry, aero industries. CONSTITUTION: The organized, layered inorganic material consists of a layered inorganic material based on aluminosilicate, and an organic polymer positioned between layers of the inorganic material. The organic polymer is a low-polar siloxane amine oligomer selected from polysiloxane amine represented by formula 1a, 1b and 1c. In the formulae, each of R1 and R2 is -(CH2)nX(CH2)k-; X is -CH2- or -O-; each of l, m, k is an integer of 1-300. The siloxane amine oligomer has weight average molecular weight(Mw) of 1,000-50,000 g/mol, and equivalent weight of functionality of 500-25,000 g/eq.

Abstract translation: 用途：提供具有改善的耐热性和组织性的有组织的无机材料，其可用作各种电气，电子，（航空）航天工业，航空工业等高科技工业的关键复合材料。 构成：有组织的层状无机材料由基于铝硅酸盐的层状无机材料和位于无机材料层之间的有机聚合物组成。 有机聚合物是选自由式1a，1b和1c表示的聚硅氧烷胺的低极性硅氧烷胺低聚物。 在式中，R1和R2各自为 - （CH2）nX（CH2）k-; X是-CH 2 - 或-O-; l，m，k中的每一个是1-300的整数。 硅氧烷胺低聚物具有1,000-50,000g / mol的重均分子量（Mw）和500-25,000g / eq的官能度当量。