公开(公告)号：KR1020010037883A

公开(公告)日：2001-05-15

申请号：KR1019990045621

申请日：1999-10-20

Applicant: 한국화학연구원

Inventor： 박상언 ,  장종산 ,  전명원 ,  이철위 ,  박진남 ,  김균

IPC: B01J23/44

CPC classification number: B01J37/0009 ,  B01J23/8926 ,  B01J23/8986 ,  B01J29/126 ,  B01J29/146 ,  B01J29/46 ,  B01J35/04 ,  B01J37/0215

Abstract: PURPOSE: Disclosed is a honeycomb monolith catalyst for the elimination of VOCs, which is characterized in that a hydrophobic zeolite being supported with palladium ion (Pd¬2+) and transition metals is mixed with a binder, and then washcoated on a cordierite honeycomb monolith. This honeycomb monolith catalyst shows an excellent catalytic activation at a temperature range of 260deg.C or lower, especially even in the presence of excess moisture. CONSTITUTION: This honeycomb monolith catalyst is prepared by supporting metal salts comprising palladium ion and transition metals such as Cu, Mn, Ni, Cr, and Co on a hydrophobic zeolite selected from USY-zeolite(SiO2/Al2O3=10 - 1000), ZSM-5 zeolite (SiO2/Al2O3=20 - 1000); adding a binder selected from bentonite, silica colloid, and methylcellulose for obtaining slurry-phase catalyst; washcoating prepared slurry-phase catalyst on a cordierite honeycomb monolith. In this method, palladium ion of 0.1 to 2.0wt.% and transition metal of 5 to 30wt.% (based on the weight of hydrophobic zeolite) are supported on the hydrophobic zeolite respectively, and it is characterized in that the amount of palladium and the amount of transition metal applied on the cordierite honeycomb monolith are respectively 0.03 to 0.8g/L-honeycomb and 2.0 to 15.0g/L-honeycomb.

Abstract translation: 本发明公开了一种用于消除VOC的蜂窝状整体式催化剂，其特征在于用钯离子（Pd 2 +）和过渡金属负载的疏水性沸石与粘合剂混合，然后用堇青石蜂窝单块 。 该蜂窝状整体式催化剂在260℃或更低的温度范围内显示出优异的催化活性，特别是即使在过量水分存在下。 构成：该蜂窝状整体式催化剂是通过在选自USY-沸石（SiO 2 / Al 2 O 3 = 10-1000），ZSM-5的疏水性沸石上负载包含钯离子和过渡金属如Cu，Mn，Ni，Cr和Co的金属盐而制备的。 -5沸石（SiO 2 / Al 2 O 3 = 20-1000）; 加入选自膨润土，二氧化硅胶体和甲基纤维素的粘合剂以获得淤浆相催化剂; 在堇青石蜂窝整料上涂覆制备的淤浆相催化剂。 在该方法中，分别在疏水性沸石上负载0.1至2.0重量％的钯离子和5至30重量％的过渡金属（基于疏水性沸石的重量），并且其特征在于钯和 施加在堇青石蜂窝单块上的过渡金属的量分别为0.03〜0.8g / L蜂窝和2.0〜15.0g / L蜂窝。

公开(公告)号：KR100336967B1

公开(公告)日：2002-05-17

申请号：KR1019990045621

申请日：1999-10-20

Applicant: 한국화학연구원

Inventor： 박상언 ,  장종산 ,  전명원 ,  이철위 ,  박진남 ,  김균

IPC: B01J23/44

Abstract: 본발명은휘발성유기화합물제거용하니컴형일체식촉매의제조방법에관한것으로서, 더욱상세하게는팔라듐이온(Pd)과전이금속이온을함유한금속염을제올라이트와같은다공성담체에담지시켜서만들어진촉매분말을소정의바인더와배합하여슬러리형태로제조한후, 이를하니컴형담체표면에습윤코팅하여제조한것으로화학산업의생산과정에서발생하는배가스중의휘발성유기화합물을저온완전연소시켜제거하는데유용한하니컴형일체식촉매의제조방법에관한것이다.