公开(公告)号：KR1020130040653A

公开(公告)日：2013-04-24

申请号：KR1020110105560

申请日：2011-10-14

Applicant: 한남대학교 산학협력단

Inventor： 최성호 ,  김상겸 ,  김윤섭

IPC: C08K9/04 ,  C08L25/04 ,  C08L33/04 ,  C08J3/28

CPC classification number: C08K3/346 ,  C08K5/17 ,  C08K5/3445 ,  C08K9/04 ,  C08K2201/008 ,  C08K2201/011 ,  C08L25/08 ,  C08L2201/02

Abstract: PURPOSE: A manufacturing method of a vinyl polymer-clay nanocomposite is provided to prevent the generation of by-products, and to obtain a vinyl polymer-clay nanocomposite with excellent physical and chemical properties without using a chemical initiator. CONSTITUTION: A manufacturing method of a vinyl polymer-clay nanocomposite comprises: a step of mixing imidazole salt with a vinyl group or quaternary amine salt with sodium clay(Na^+-montmorillonite), to manufacture reactive organic clay with a vinyl group; a step of manufacturing a reaction solution by dispersing the reactive organic clay and a vinyl monomer into an organic solvent; and a step of gamma ray-irradiating the reaction solution. The imidazole salt with a vinyl group is 1-[(4-ethylphenyl)methyl]-3-butyl-imidazolium chloride.

Abstract translation: 目的：提供乙烯基聚合物 - 粘土纳米复合材料的制造方法，以防止副产物的产生，并且获得具有优异的物理和化学性质的乙烯基聚合物 - 粘土纳米复合材料，而不使用化学引发剂。 构成：乙烯基聚合物 - 粘土纳米复合材料的制造方法包括：将咪唑盐与乙烯基或季铵盐与钠粘土（Na + - 蒙脱土）混合，制备具有乙烯基的反应性有机粘土的步骤; 通过将反应性有机粘土和乙烯基单体分散在有机溶剂中来制备反应溶液的步骤; 和伽马射线照射反应溶液的步骤。 具有乙烯基的咪唑盐为1 - [（4-乙基苯基）甲基] -3-丁基 - 咪唑鎓氯化物。