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公开(公告)号：KR100957378B1
公开(公告)日：2010-05-11
申请号：KR1020080079752
申请日：2008-08-14
Applicant: 현대자동차주식회사 , 순천대학교 산학협력단
Abstract: 본 발명은 연료전지 열화 방지 방법에 관한 것으로서, 운행 중인 연료전지 차량에서 스택 유출수의 불소이온농도 또는 pH 값을 실시간으로 측정하여 스택의 전해질막 상태를 확인하고, 전해질막의 열화 가능성이 있는 것으로 판단되면 현재의 열화 가속화 인자를 확인하여 해당 인자에 대한 막 안정화 조건이 유지될 수 있도록 인자별 설정된 제어 과정에 따라 차량 및 스택의 운전 조건을 제어함으로써, 전해질막의 열화를 효과적으로 방지하고, 스택의 성능 및 내구성을 향상시킬 수 있는 연료전지 열화 방지 방법에 관한 것이다.
연료전지, 스택, MEA, 전해질막, 열화, 불소이온, 불소유출속도-
公开(公告)号：KR1020100133698A
公开(公告)日：2010-12-22
申请号：KR1020090052383
申请日：2009-06-12
Applicant: 현대자동차주식회사 , 순천대학교 산학협력단
Abstract: PURPOSE: A method for testing electrolyte membrane endurance of fuel cell is provided to form pinhole and cracks on a film in a short time, and to accurately perform the lifetime of an electrolyte film. CONSTITUTION: A method for testing electrolyte membrane endurance of fuel cell comprises the steps of: performing electrochemical deterioration acceleration operation to create cracks or pin holes on a weak portion of an electrolyte film; accelerating generation of pinhole while inducing contraction and expansion of the electrolyte film by repeating humidification/drying cycle; confirming the formation of pinhole on the electrolyte film; and predicting a lifetime while evaluating durability.
Abstract translation: 目的：提供一种用于测量燃料电池电解质膜耐久性的方法，以在短时间内在膜上形成针孔和裂纹，并准确地实现电解质膜的寿命。 构成：对燃料电池的电解质膜耐久性进行检测的方法包括以下步骤：进行电化学劣化加速操作，在电解质薄膜的弱部产生裂缝或针孔; 加速产生针孔，同时通过重复加湿/干燥循环引起电解质膜的收缩和膨胀; 确认在电解质膜上形成针孔; 并在评估耐久性的同时预测一生。
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公开(公告)号：KR101021121B1
公开(公告)日：2011-03-14
申请号：KR1020080032963
申请日：2008-04-10
Applicant: 현대자동차주식회사 , 순천대학교 산학협력단
Abstract: 본 발명은 고분자 전해질 막의 핀홀 위치 확인 방법 및 장치에 관한 것으로서, 더욱 상세하게는 연료전지 시스템에 적용되는 고분자 전해질 막에 열화 현상에 의하여 핀홀이 형성된 위치를 용이하게 확인할 수 있도록 한 고분자 전해질 막의 핀홀 위치 확인 방법 및 장치에 관한 것이다.
이를 위해, 본 발명은 서로 다른 pH 용액이 각 내부에 저장되는 상부블럭 및 하부블럭과; 상기 상부블럭의 상부에 관통 형성된 지시약 주입구와; 상부블럭 및 하부블럭의 사이에 배열되는 한 쌍의 중간판과; 상기 한 쌍의 중간판의 중앙부분에 지지망 설치구에 부착되는 격자형 지지망과; 상기 한 쌍의 중간판 사이에 테두리단이 고정되는 동시에 그 중앙부는 상기 지지망에 안착되는 고분자 전해질 막; 을 포함하여 구성된 것을 특징으로 하는 고분자 전해질 막의 핀홀 위치 확인 장치 및 방법을 제공한다.
연료전지, 고분자 전해질 막, 핀홀, pH, 지시약, 변색-
公开(公告)号：KR1020100021048A
公开(公告)日：2010-02-24
申请号：KR1020080079751
申请日：2008-08-14
Applicant: 현대자동차주식회사 , 순천대학교 산학협력단
IPC: G01R31/36
CPC classification number: G01R31/3679 , G01N27/302 , G01R31/3606 , H01M8/04313 , Y02T10/7005
Abstract: PURPOSE: A device and a method for determining deterioration of a fuel cell is provided to rapidly deal with the deterioration of an electrolyte film by checking the state of the electrolyte film with regard to a fuel cell stack of the vehicle in real time. CONSTITUTION: A fluorine ion concentration measuring unit(162,167) detects the fluorine ion concentration of a stack effluent exhausted from a fuel cell stack(110). A condenser is installed on the pipe(110c,110d) of the fuel cell stack to condense the exhaust gas from the gas outlet of an anode and a cathode. A pH meter(161,166) detects the pH. A velocity measuring unit measures the velocity of the stack effluent. A controller(140) confirms an electrolyte film of the stack by calculating a fluorine flow velocity. The controller determines the deterioration of the electrolyte film if the fluorine flow velocity is out of the normal range.
Abstract translation: 目的：提供一种用于确定燃料电池劣化的装置和方法，以通过实时检查关于车辆的燃料电池堆的电解质膜的状态来快速地处理电解质膜的劣化。 构成：氟离子浓度测量单元（162,167）检测从燃料电池堆（110）排出的堆流体的氟离子浓度。 在燃料电池堆的管道（110c，110d）上安装有冷凝器，以将来自阳极和阴极的气体出口的废气冷凝。 pH计（161,166）检测pH值。 速度测量单元测量堆流出物的速度。 控制器（140）通过计算氟流速确认堆叠的电解质膜。 如果氟流速超出正常范围，则控制器确定电解质膜的劣化。
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公开(公告)号：KR1020090107610A
公开(公告)日：2009-10-14
申请号：KR1020080032963
申请日：2008-04-10
Applicant: 현대자동차주식회사 , 순천대학교 산학협력단
Abstract: PURPOSE: A device for confirming the position of a pin hole of polymer electrolyte membrane is provided to be used for total inspection of a membrane electrode assembly(MEA) of a fuel battery, endurance evaluation and analysis of solid polymer electrolyte membrane for a fuel battery. CONSTITUTION: A device for confirming the position of a pin hole of polymer electrolyte membrane includes an upper block(10), a lower block(12), an indicator inlet(16), a pair of center plates(14a,14b), a supporting net(22), and a solid polymer electrolyte membrane. Different pH solution is stored in the upper block and the lower block. The indicator inlet is formed at the upper part of the upper block. A pair of center plates are arranged between the upper block and the lower block.
Abstract translation: 目的：提供一种用于确认聚合物电解质膜的针孔位置的装置，用于燃料电池的膜电极组件（MEA）的全面检查，用于燃料电池的固体聚合物电解质膜的耐久性评估和分析 。 构成：用于确认聚合物电解质膜的针孔的位置的装置包括上部块（10），下部块（12），指示器入口（16），一对中心板（14a，14b）， 支撑网（22）和固体聚合物电解质膜。 不同的pH溶液存储在上部块和下部块中。 指示器入口形成在上部块的上部。 一对中心板布置在上部块和下部块之间。
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Patent Agency Ranking
公开(公告)号：KR101567079B1
公开(公告)日：2015-11-09
申请号：KR1020090052383
申请日：2009-06-12
Applicant: 현대자동차주식회사 , 순천대학교 산학협력단
Abstract: 본발명은연료전지용전해질막수명예측을위한내구성평가방법에관한것으로서, 더욱상세하게는전기화학적열화가속운전에따른전기화학적열화과정과가습/건조사이클에따른기계적강도열화과정을병행함으로써, 전해질막의약한부위에핀홀형성을촉진시키면서전해질막의수명예측을위한내구성을정확하게평가할수 있도록한 연료전지용전해질막수명예측을위한내구성평가방법에관한것이다. 이를위해, 본발명은전해질막의약한부위에흠집또는핀홀이생성되도록전기화학적열화가속운전을실시하는단계와; 소정의가습/건조사이클을반복하여전해질막의수축및 팽창을유도하는동시에핀홀생성을가속화시키는단계와; 전해질막에핀홀이형성된것을정확하게확인하고자, 전해질막에대한수소투과전류를측정하는단계와; 핀홀이생성된것으로확인된전해질막과, 평가기준이되는전해질막을비교하여내구성을평가하는동시에수명을예측하는단계; 를포함하는것을특징으로하는연료전지용전해질막수명예측을위한내구성평가방법을제공한다.
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公开(公告)号：KR100993657B1
公开(公告)日：2010-11-10
申请号：KR1020080079751
申请日：2008-08-14
Applicant: 현대자동차주식회사 , 순천대학교 산학협력단
IPC: G01R31/36
Abstract: 본 발명은 연료전지 열화 판정 장치 및 방법에 관한 것으로서, 연료전지 차량에서 운전 중인 연료전지 스택의 유출수에 대해 불소이온농도 또는 pH 값을 실시간으로 측정하여 그로부터 불소유출속도를 산출한 뒤 산출된 불소유출속도가 설정된 정상 범위를 벗어나는 경우 스택의 전해질막 열화를 판정 및 경보해주는 장치와 방법에 관한 것이다.
연료전지, 스택, MEA, 전해질막, 열화, 불소이온, 불소유출속도-
公开(公告)号：KR1020100021049A
公开(公告)日：2010-02-24
申请号：KR1020080079752
申请日：2008-08-14
Applicant: 현대자동차주식회사 , 순천대학교 산학협력단
CPC classification number: H01M8/04679 , B60L11/1883 , H01M8/04365 , H01M8/04395 , H01M8/045 , H01M8/04559 , H01M2250/20 , Y02E60/50 , Y02T90/34
Abstract: PURPOSE: A method for preventing the deterioration of a fuel cell is provided to effectively prevent the deterioration of an electrolyte film in a fuel cell stack loaded in a fuel cell vehicle and to improve the performance and durability of a stack. CONSTITUTION: A method for preventing the deterioration of a fuel cell comprises the following steps of: (S101) measuring the fluoride concentration and pH value forlevel of stack effluent coming outexpelled from a fuel cell stack and measuring the flux of stack effluent; (S105) determining the deterioration possibility of the electrolyte film by producing a fluorine flow rate based on the measured fluorine ion concentration or pH value level and flow velocity data of stack effluent; (S109) confirming a deterioration acceleration factor by measuring operation voltage and temperature of a stack, relative humidity of reaction gas provided to the stack, and oxygen partial pressure among air provided to the stack, through sensors; and (S113) controlling the driving condition of the stack and vehicles.
Abstract translation: 目的：提供一种防止燃料电池劣化的方法，以有效地防止燃料电池车辆中装载的燃料电池堆中的电解质膜的劣化，提高堆叠的性能和耐久性。 构成：用于防止燃料电池劣化的方法包括以下步骤：（S101）测量从燃料电池堆排出的堆流出物的水平的氟化物浓度和pH值，并测量堆流出物的通量; （S105）基于所测量的氟离子浓度或pH值水平和堆流出物的流速数据产生氟流量来确定电解质膜的劣化可能性; （S109），通过传感器测量堆叠的工作电压和温度，提供给堆叠的反应气体的相对湿度和提供给堆叠的空气中的氧分压，确认劣化加速因子; （S113）控制堆垛和车辆的行驶状态。
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公开(公告)号：KR1020140002923A
公开(公告)日：2014-01-09
申请号：KR1020120069875
申请日：2012-06-28
Applicant: 순천대학교 산학협력단 , 주식회사 해림후코이단
IPC: A61K31/737 , A61K36/03
CPC classification number: A61K31/737 , A61K31/336 , A61K36/03 , A61K2236/33
Abstract: The present invention relates to a method for extracting fucoxanthin and fucoidan from seaweed. The method of the present invention comprises: a first step of pulverizing seaweed; a second step of wrapping the pulverized seaweed in a non-woven fabric; a third step of inserting ethanol into the seaweed to perform room-temperature extraction; a fourth step of extracting the extract from the third step at a temperature of 50 to 60°C; a fifth step of extracting fucoxanthin from a filtered solution in the extract from the fourth step; and a sixth step of extracting fucoidan from the residual seaweed in the extract from the fourth step. [Reference numerals] (A1) Fucoxanthin extracting·purifying; (A2) Fucoidan extracting·purifying; (BB) Pulverize dried seaweed; (CC) Wrap in a non-woven fabric; (D1) Insert ethanol; (D2) First room-temperature extraction (stirring or immersing); (EE,HH) Extract at 50°C-60°C; (FF,II,RR,TT) Filter; (G1) Put new seaweed into filtrate; (G2) Secondary room-temperature extraction (stirring or immersing); (JJ) Fucoxanthin extract; (KK) Ethanol vacuum-evaporation; (LL) Mix with excipient; (MM) Freeze-dry; (NN) Fucoxanthin powder; (OO) Residual seaweed; (PP) Insert water and organic acid; (QQ) First extracting at 90-100°C; (SS) Insert water, Second extracting at 100~110°C; (UU) Filtrate; (VV) Add CaCl_2; (WW) Remove alginic acid; (XX) Ultrafiltrating; (YY) Vacuum concentrating; (ZZ) Fucoidan liquid
Abstract translation: 本发明涉及从海藻中提取岩藻聚糖和岩藻依聚糖的方法。 本发明的方法包括：将海藻粉碎的第一步骤; 将粉碎的海藻包裹在无纺织物中的第二步骤; 将乙醇插入海藻进行室温萃取的第三步; 在50〜60℃的温度下从第三步骤提取提取物的第四步骤; 从第四步骤的提取物中的过滤溶液中提取岩藻黄素的第五步骤; 以及从第四步骤的提取物中从剩余海藻中提取岩藻多糖的第六步骤。 [A1]富果黄素提取·净化; （A2）岩藻聚糖提取·净化; （BB）粉碎干海藻; （CC）包裹在无纺布中; （D1）插入乙醇; （D2）第一次室温萃取（搅拌或浸渍）; （EE，HH）在50°C-60°C时提取; （FF，II，RR，TT）过滤器; （G1）将新的海藻放入滤液中; （G2）二次室温萃取（搅拌或浸渍）; （JJ）岩藻黄素提取物; （KK）乙醇真空蒸发; （LL）与赋形剂混合; （MM）冷冻干燥; （NN）岩藻黄素粉末; （OO）残留海藻; （PP）插入水和有机酸; （QQ）首先在90-100°C提取; （SS）插入水，第二次提取在100〜110℃; （UU）过滤; （VV）加入CaCl_2; （WW）去除海藻酸; （XX）超滤; （YY）真空浓缩; （ZZ）岩藻依聚糖液体
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公开(公告)号：KR1020130017964A
公开(公告)日：2013-02-20
申请号：KR1020110080726
申请日：2011-08-12
Applicant: 순천대학교 산학협력단 , 주식회사 해림후코이단
Abstract: PURPOSE: A method for preparing a kelp root extract and a composition containing the extract are provided to effectively extract useful ingredients from kelp roots and to treat constipation. CONSTITUTION: A method for preparing a kelp root extract comprises: a step of washing and drying kelp roots; a step of cutting and pulverizing the dried kelp roots and sorting by each size; a step of adding an organic acid solution and extracting the pulverized kelp roots; and a step of filtering the extract. The method also comprises a step concentrating the extract. The organic acid includes citric acid, malic acid, acetic acid, or a mixture thereof. The organic acid solution contains 0.05-0.5 wt% of organic acid and 99.5-99.95 wt% of water. A composition for treating constipation contains the extract as an active ingredient. [Reference numerals] (AA) Kelp root; (BB) Cutting; (CC) Washing and drying; (DD) Pulverizing and sorting; (EE) Extracting; (FF) Concentrating; (GG) Kelp root extract; (HH) Separating and filtering; (II) Kelp root residues
Abstract translation: 目的：提供一种制备海带根提取物和含有提取物的组合物的方法，以有效地从海带根中提取有用成分并治疗便秘。 构成：一种制备海带根提取物的方法，包括：洗涤和干燥海带根的步骤; 切割并粉碎干海带根并按各种尺寸进行分选的步骤; 加入有机酸溶液并提取粉状海带根的步骤; 以及过滤提取物的步骤。 该方法还包括浓缩提取物的步骤。 有机酸包括柠檬酸，苹果酸，乙酸或其混合物。 有机酸溶液含有0.05-0.5重量％的有机酸和99.5-99.95重量％的水。 用于治疗便秘的组合物含有提取物作为活性成分。 （标号）（AA）海带根; （BB）切割; （CC）洗涤和干燥; （DD）粉碎和分选; （EE）提取; （FF）集中; （GG）海带根提取物; （HH）分离和过滤; （二）海带根残渣
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