Abstract:
The invention relates to A curable composition for producing dental composite crowns, the composition comprising a resin matrix comprising polymerizable (meth)acrylate(s) not comprising a urethane moiety, polymerizable urethane(meth)acrylate(s), wherein the polymerizable (meth)acrylate(s) not comprising an urethane moiety are used in excess over the polymerizable urethane(meth)acrylate(s), a filler matrix comprising nanocluster(s), fumed silica in an amount below 8 wt. % with respect to the weight of the whole composition, an initiator system comprising photoinitiator(s), organic dye(s), the curable composition not comprising softener in an amount of more than 5 wt. % with respect to the weight of the whole composition, the curable composition having a viscosity below 150 Pa*s at 23° C. and a shear rate of 1 s−1. The invention also relates to a cured article obtained by radiation curing this curable composition by use of an additive-manufacturing method.
Abstract:
An additive manufacturing system has a light permeable base (2), a build carrier (4) for holding a workpiece (100) and a light source (5) which is arranged to emit light through the light permeable base (2). The light permeable base (2) and the build carrier (4) are positionable relative to each other in a build dimension in which the workpiece (100) is built up. The system further has a resin vat (3) in which the light permeable base (2) forms a wall portion thereof. The system further comprises a plurality of resin supplies (13, 15) for supplying different light hardenable resins in direct contact with each other in said vat (3). The system facilitates the rapid manufacturing of a dental restoration having a color gradation.
Abstract:
A device for progressively building up an object from a light hardenable material. The device has a perforated build platform for the object. The build platform forms a build surface that faces a light source. The build platform and the light source are positionable relative to each other by computer control. The device is further configured for supplying the light hardenable material through the perforation of the build platform for building up the object. The invention enables the making of colored objects by stereolithography.
Abstract:
The invention relates to a dental composition comprising polymerizable monomer (1), initiator component(s), filler component(s) in an amount of more than about 20 wt.-%, wt.-% with respect to the whole weight of the composition, the polymerizable monomer (1) being characterized as follows: having exactly two (meth)acrylate reactive moieties, having an unsymmetrical backbone as linkage between the (meth)acrylate reactive moieties, the two (meth)acrylate reactive moieties being attached onto the unsymmetrical monomer backbone as alkyl esters, the unsymmetrical backbone comprising one aromatic moiety of the phenolic type, the polymerizable monomer (1) not containing an acidic moiety, other atoms than carbon, hydrogen, and oxygen, bisphenol moieties. The invention also relates to the use of the dental composition as or for producing a dental filling material, crown and bridge material, inlay, onlay, veneer or dental mill blank.
Abstract:
An additive manufacturing system has a light permeable base, a build carrier for holding a workpiece and a light source which is arranged to emit light through the light permeable base. The light permeable base and the build carrier are positionable relative to each other in a build dimension in which the workpiece is built up. The system further has a resin vat in which the light permeable base forms a wall portion thereof. The system further comprises a plurality of resin supplies for supplying different light hardenable resins in direct contact with each other in said vat. The system facilitates the rapid manufacturing of a dental restoration having a color gradation.
Abstract:
An additive manufacturing system has a light permeable base (2), a build carrier (4) for holding a workpiece (100) and a light source (5) which is arranged to emit light through the light permeable base (2). The light permeable base (2) and the build carrier (4) are positionable relative to each other in a build dimension in which the workpiece (100) is built up. The system further has a resin vat (3) in which the light permeable base (2) forms a wall portion thereof. The system further comprises a plurality of resin supplies (13, 15) for supplying different light hardenable resins in direct contact with each other in said vat (3). The system facilitates the rapid manufacturing of a dental restoration having a color gradation.
Abstract:
The invention relates to a dental composition comprising filler (F1) comprising aggregated nano-sized particles in an amount of from about 30 to about 70 wt. %, filler (F2) comprising agglomerated nano-sized particles in an amount from about 1 to about 20 wt. %, hardenable component (A1) being an urethane(meth)acrylate with a functionality of at least 2 and having a molecular weight from about 400 to about 3,000 g/mol,-hardenable component (A2) being a radically polymerizable (meth)acrylate with a functionality of at least 2 being different from component (A1), redox curing initiator system, the dental composition not comprising non-agglomerated nano-sized filler in an amount above about 10 wt. %, wt. % with respect to the weight of the whole composition. The dental composition is in particular useful as or for production of permanent crown and bridges, inlays, onlays and veneers.
Abstract:
The invention relates to a dental composition comprising—filler (F1) comprising aggregated nano-sized particles in an amount of from about 30 to about 70 wt. %, —filler (F2) comprising agglomerated nano-sized particles in an amount from about 1 to about 20 wt. %, —hardenable component (A1) being an urethane(meth)acrylate with a functionality of at least 2 and having a molecular weight from about 400 to about 3,000 g/mol, —hardenable component (A2) being a radically polymerizable (meth)acrylate with a functionality of at least 2 being different from component (A1), —redox curing initiator system, the dental composition not comprising non-agglomerated nano-sized filler in an amount above about 10 wt. %, wt. % with respect to the weight of the whole composition. The dental composition is in particular useful as or for production of permanent crown and bridges, inlays, onlays and veneers.
Abstract:
A device for progressively building up an object from a light hardenable material. The device has a perforated build platform for the object. The build platform forms a build surface that faces a light source. The build platform and the light source are positionable relative to each other by computer control. The device is further configured for supplying the light hardenable material through the perforation of the build platform for building up the object. The invention enables the making of colored objects by stereolithography.
Abstract:
The invention relates to a preformed dental composite crown being characterized by its shape and chemical composition, the shape being characterized as follows: having an occlusal top surface and depending buccal, mesial, distal and lingual side surfaces, the side surfaces being connected to each other and forming a crown cervix, the wall thickness of the crown at the crown cervix being lower than 0.6 mm; at least two of opposing depending side surfaces having a concave shape; the chemical composition of the material the preformed dental composite crown is made of being a hardened composition comprising the following components: nano-filler(s) in an amount from 20 to 70 wt. %, resin matrix in an amount from 20 to 75 wt. %, wt. % with respect to the weight of the chemical composition, the resin matrix comprising urethane(meth)acrylate(s) and (meth)acrylate(s) not comprising a urethane moiety. The invention also relates to a kit of parts comprising such a preformed dental composite crown, processes for producing such crowns and the use of such a crown for treating a dental tooth.