公开(公告)号：WO2008109733A1

公开(公告)日：2008-09-12

申请号：PCT/US2008/056021

申请日：2008-03-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  HO, Charlie C. ,  STARK, Stephen M. ,  HALFORD, Kenneth J. ,  STEWART, Dale R.

Inventor： HO, Charlie C. ,  STARK, Stephen M. ,  HALFORD, Kenneth J. ,  STEWART, Dale R.

IPC: C09J7/02

CPC classification number: C09J7/0282 ,  C08L75/02 ,  C08L75/04 ,  C09J7/22 ,  C09J7/25 ,  C09J7/38 ,  C09J2203/306 ,  C09J2475/006 ,  Y10T428/1471 ,  Y10T428/1476 ,  C08L2666/20

Abstract: An adhesive-backed polymeric film assembly that comprises: a polymeric film having one layer or multiple layers, a back surface and a front surface, with an adhesive bonded to the back surface; and a release liner having an outer surface and an inner surface releaseably bonded to the adhesive, wherein the assembly is wound into a roll, with the outer surface of the release liner facing outwardly and the front surface of the polymeric film facing inwardly.

Abstract translation: 一种粘合剂背衬聚合物膜组件，其包括：具有一层或多层的聚合物膜，后表面和前表面，其粘合剂粘合到所述背面; 以及释放衬垫，其具有可释放地粘合到所述粘合剂的外表面和内表面，其中所述组件被卷绕成卷，其中所述释放衬片的外表面朝外并且所述聚合物膜的前表面面向内。

公开(公告)号：WO2021209871A1

公开(公告)日：2021-10-21

申请号：PCT/IB2021/052958

申请日：2021-04-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LU, Yongshang ,  HO, Charlie C. ,  BRAUN, Ryan M. ,  JAROS, John J. ,  NIWAS, Shri ,  XIA, Ying

IPC: C08J7/043 ,  C08J7/046 ,  B32B27/08 ,  B32B27/40

Abstract: Described herein is a multilayered article and methods of making and using such articles. The multilayered article comprises: • (a) a microsphere layer comprising a plurality of microspheres (11) disposed in a monolayer; • (b) a bead bonding layer (12) comprising a first major surface and a second opposing major surface wherein the plurality of microspheres is at least partially embedded in the first major surface of the bead bonding layer, and wherein the bead bonding layer comprises a thermoset polyurethane, and wherein the thermoset polyurethane is derived from one or more liquid polyols; and • (c) an elastomeric layer (14) disposed on the second opposing major surface of the bead bonding layer.

公开(公告)号：WO2018138588A1

公开(公告)日：2018-08-02

申请号：PCT/IB2018/050105

申请日：2018-01-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LIU, Tao ,  OSTLIE, Brian W. ,  HEDDING, Brent A. ,  HO, Charlie C. ,  LU, Yongshang ,  JENNEN, Jay M. ,  MERCORD, David C. ,  WILLIAMS, Johnnie L.

IPC: F21V8/00

Abstract: A display system including a lightguide and first and second reflective layers disposed on opposite sides of the lightguide is provided. The lightguide has opposing first and second major surfaces and includes a light extraction pattern for extracting light that would otherwise be confined and propagate within the lightguide primarily by total internal reflection. Light extracted by the light extraction pattern exits the lightguide through at least one of the first and second major surfaces of the lightguide. Each of the first and second reflective layers has an average specular reflectance of at least 50% in a predetermined wavelength range. The light extraction pattern may be repeatedly imaged by the first and second reflective layers to produce three-dimensional stacked images of the light extraction pattern.

公开(公告)号：WO2021205311A1

公开(公告)日：2021-10-14

申请号：PCT/IB2021/052785

申请日：2021-04-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LU, Yongshang ,  HO, Charlie C.

IPC: B32B7/12 ,  B32B27/08 ,  B32B27/18 ,  B32B27/34 ,  B32B27/36 ,  B32B27/40 ,  B32B27/42

Abstract: A multilayer film is described comprising a first film layer comprising an organic polymeric material, wherein the first film layer has an elongation of at least 250%; and a second film layer comprising a crosslinked polyurethane wherein the polyurethane comprises polymerized units of a polyamide. In some embodiments, the organic polymeric material of the first film layer comprises polyurethane. Also described is a method of protecting a surface of a motor vehicle and a method of making a multilayer protective film.

公开(公告)号：WO2016118399A1

公开(公告)日：2016-07-28

申请号：PCT/US2016/013368

申请日：2016-01-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LU, Yongshang ,  CHEN, Zhong ,  MA, Jingjing ,  HO, Charlie C.

IPC: C09J175/04 ,  C08G18/06 ,  C08G18/72 ,  C09J175/06

CPC classification number: C09J175/06 ,  C08G18/10 ,  C08G18/42 ,  C08G18/4277 ,  C08G18/6625 ,  C08G18/724 ,  C08G18/73 ,  C08G18/755 ,  C08G18/7642 ,  C08G18/7671 ,  C08G2170/40 ,  C09J7/38 ,  C09J11/00 ,  C09J2201/606 ,  C09J2201/622 ,  C09J2475/00 ,  C08G18/3206

Abstract: A pressure sensitive adhesive composition includes a polyurethane polymer that includes the reaction product of a polyisocyanate component and a polyol component. The polyol component has a total solubility parameter ranging from 10 to 14 (cal/cm 3 ) 1/2 .

Abstract translation: 压敏粘合剂组合物包括包含多异氰酸酯组分和多元醇组分的反应产物的聚氨酯聚合物。 多元醇组分的总溶解度参数为10-14（cal / cm 3）1/2。

公开(公告)号：WO2014055828A1

公开(公告)日：2014-04-10

申请号：PCT/US2013/063392

申请日：2013-10-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  WALKER, Christopher B. Jr. ,  RULE, Joseph D. ,  KRISHNAN, Vivek ,  CLARK, John C. ,  MCMAN, Steven J. ,  ALABI, Bola T. ,  HO, Charlie C. ,  MARX, Ryan E. ,  KUGEL, Alexander J.

Inventor： WALKER, Christopher B. Jr. ,  RULE, Joseph D. ,  KRISHNAN, Vivek ,  CLARK, John C. ,  MCMAN, Steven J. ,  ALABI, Bola T. ,  HO, Charlie C. ,  MARX, Ryan E. ,  KUGEL, Alexander J.

IPC: B44C5/04 ,  C09D7/12

CPC classification number: C08J5/18 ,  B32B3/085 ,  B32B27/08 ,  B32B27/20 ,  B32B27/306 ,  B32B27/308 ,  B32B27/36 ,  B32B27/40 ,  B32B2037/243 ,  B32B2255/00 ,  B32B2260/025 ,  B32B2260/046 ,  B32B2264/101 ,  B32B2264/104 ,  B32B2307/418 ,  B32B2451/00 ,  B44C5/0476 ,  C08J2375/04 ,  C08K3/08 ,  C08K3/22 ,  C08K3/40 ,  C08K7/18 ,  C08K7/20 ,  C09D7/70 ,  C09D183/04 ,  Y10T428/24893 ,  Y10T428/252 ,  Y10T428/254

Abstract: There is provided an article comprising at least a first surface having a first binder layer selected from at least one of linear resins and resins having low cross link densities, where the first binder layer has a first major surface opposite a second major surface; and a plurality of microspheres at least partially embedded in the first major surface of the first binder layer. For at least a portion of the first major surface, the plurality of micro spheres may cover 30% to 50% of that portion, and the microspheres may be substantially uniformly spaced.

Abstract translation: 提供了一种制品，其至少包括具有选自线性树脂和交联密度低的树脂中的至少一种的第一粘合剂层的第一表面，其中第一粘合剂层具有与第二主表面相对的第一主表面; 以及至少部分地嵌入第一粘合剂层的第一主表面中的多个微球。 对于第一主表面的至少一部分，多个微球体可以覆盖该部分的30％至50％，并且微球体可以基本均匀地间隔开。

公开(公告)号：WO2022003447A1

公开(公告)日：2022-01-06

申请号：PCT/IB2021/054838

申请日：2021-06-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： LU, Yongshang ,  HO, Charlie C.

IPC: B32B27/40 ,  C08G18/10 ,  C08G18/24 ,  C08G18/32 ,  C08G18/42 ,  C08G18/75 ,  C09D175/06 ,  B32B2255/10 ,  B32B2255/26 ,  B32B27/08 ,  B32B7/12 ,  C08G18/246 ,  C08G18/3212 ,  C08G18/4213 ,  C08G18/758

Abstract: Disclosed herein are hard coat compositions and composite films including a thermoplastic polyurethane. A hard coat composition includes a thermoplastic polyurethane having a hard segment content of 80 percent by weight or greater. The thermoplastic polyurethane is a reaction product of a) a diisocyanate; b) a polyol optionally comprising a cyclic structure; and c) a chain extender. At least one of the polyol or the chain extender comprises at least one side chain and at least one of the diisocyanate or the chain extender comprises a cyclic structure. A composite film includes 1) a hard coat layer having opposing first and second major surfaces; and 2) a second layer disposed on at least a portion of the hard coat layer. These materials can serve decorative and/or protective functions while displaying both good elongation at moderate temperatures and high hardness.

公开(公告)号：WO2020234697A1

公开(公告)日：2020-11-26

申请号：PCT/IB2020/054532

申请日：2020-05-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： CLARK, John C. ,  BAETZOLD, John P. ,  HO, Charlie C. ,  KUGEL, Alexander J. ,  LU, Yongshang ,  POMMER, Chris A. ,  JENNEN, Jay M.

IPC: B32B33/00 ,  B32B5/16 ,  B32B27/40 ,  B44C1/00 ,  B32B27/14

Abstract: Described herein is a multilayered article (10) and methods of making and using such articles. The multilayered article (10) comprises: • (a) a microsphere layer (11) comprising a plurality of microspheres disposed in a monolayer; • (b) a bead bonding layer (12) comprising a first major surface and a second opposing major surface and the plurality of microspheres is partially embedded in the first major surface of the bead bonding layer, and comprises a thermoset polyurethane having a glass transition temperature of at least 35°C; • (c) a primer layer (14) disposed on the second major surface of the bead bonding layer wherein the primer layer comprises a copolymer of polyurea and polyurethane and wherein the primer layer is covalently attached to the bead bonding layer via urea linkages; and • (d) an elastomeric layer (16) disposed on the primer layer opposite the bead bonding layer, wherein the elastomeric layer comprises a polyurethane thermoplastic elastomer.

公开(公告)号：WO2020129024A1

公开(公告)日：2020-06-25

申请号：PCT/IB2019/061223

申请日：2019-12-20

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： HO, Charlie C. ,  LU, Yongshang

IPC: C08G18/24 ,  C08G18/40 ,  C08G18/42 ,  C08G18/62 ,  C08G18/73 ,  C09D175/06 ,  C09D175/14 ,  B05D7/00

Abstract: Surfacing films and related processes are provided. These films include a first clear coat layer comprising a first crosslinked polyurethane that is the reaction product of an isocyanate; a polyol selected from the group consisting of: a caprolactone polyol, polycarbonate polyol, a polyester polyol, acrylic polyol, polyether polyol, polyolefin polyol, and mixtures thereof; and a hydroxy-functional silicone poly(meth)acrylate; a second clear coat layer comprising a crosslinked polymer that is essentially free of hydroxy-functional silicone poly(meth)acrylate; a bulk layer comprising a thermoplastic polyurethane; and an adhesive layer. The provided films overcome the problem of migration of solvents and other impurities into the polyurethane bulk layer because the clear coat layer is cured, and solvents removed, prior to the coating of the polyurethane bulk layer. Manufacturing of these films can provide substantially faster line speeds and reduced waste.

公开(公告)号：WO2016018749A1

公开(公告)日：2016-02-04

申请号：PCT/US2015/041981

申请日：2015-07-24

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： HO, Charlie C. ,  HAUMANN, Robert D. ,  GUNDALE, Jeremy P. ,  RAJAMANI, Vijay ,  EGASHIRA, Ken ,  LIN, Chia Hui ,  KUO, His Shou

IPC: C08G18/66 ,  B32B7/12 ,  B32B27/40 ,  C08G18/75 ,  C08G18/42 ,  C09J7/02 ,  B29C51/14

CPC classification number: C09D175/06 ,  B29C47/0004 ,  B29C47/0021 ,  B29C51/10 ,  B29C51/14 ,  B29K2075/00 ,  B29K2995/007 ,  B29K2995/0077 ,  B29L2009/00 ,  B29L2031/3005 ,  B29L2031/722 ,  B32B7/12 ,  B32B27/08 ,  B32B27/304 ,  B32B27/308 ,  B32B27/36 ,  B32B27/40 ,  B32B2250/24 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2307/30 ,  B32B2307/50 ,  B32B2307/536 ,  B32B2307/54 ,  B32B2307/546 ,  B32B2307/554 ,  B32B2307/558 ,  B32B2307/5825 ,  B32B2307/712 ,  B32B2307/714 ,  B32B2451/00 ,  B32B2605/00 ,  C08G18/4238 ,  C08G18/4277 ,  C08G18/664 ,  C08G18/758 ,  C09J7/25 ,  C09J2201/606 ,  C09J2475/006

Abstract: Disclosed herein are improved thermoplastic polyurethane compositions, articles, and related methods. These compositions include aliphatic thermoplastic polyurethanes having a hard segment content ranging from 57 percent to 80 percent by weight. The hard coat compositions have a Shore D hardness of at least 70 and can display an Elongation at Break test result at 25 degrees Celsius of at least 150 percent. These materials, when hardened, can serve decorative and/or protective functions while displaying both a high degree of elongation at moderate temperatures and high hardness.

Abstract translation: 本文公开了改进的热塑性聚氨酯组合物，制品和相关方法。 这些组合物包括硬链段含量为57重量％至80重量％的脂族热塑性聚氨酯。 硬涂层组合物的肖氏D硬度至少为70，并且可以在25摄氏度下显示至少150％的断裂伸长率测试结果。 这些材料在硬化时可以提供装饰和/或保护功能，同时在中等温度和高硬度下显示高伸长率。