Abstract:
The method of making a three-dimensional article includes heating a composition comprising a polymer and hollow ceramic microspheres, extruding the composition in molten form from an extrusion head to provide at least a portion of a first layer of the three-dimensional article, and extruding at least a second layer of the composition in molten form from the extrusion head onto at least the portion of the first layer to make at least a portion of the three-dimensional article. Three-dimensional articles are also described. A composition including a polymer and hollow ceramic microspheres is also described. The composition may be a filament. The polymer is at least one of a low-surface-energy polymer or polyolefin. The composition can be useful, for example, in melt extrusion additive manufacturing, for example, fused filament fabrication.
Abstract:
A composition that includes a polyolefin having first repeating units, hollow glass microspheres, a polyolefin impact modifier that is chemically non-crosslinked and free of polar functional groups, and a compatibilizer comprising the first repeating units and second repeating units, which are the first repeating units modified with polar functional groups. Articles made from the composition and methods of making an article by injection molding the composition are also disclosed.
Abstract:
The present disclosure provides a plurality of glass bubbles having an average true density of up to about 0.55 grams per cubic centimeter and a size distribution including a median size in a range from about 15 micrometers to 40 micrometers. A hydrostatic pressure at which ten percent by volume of the plurality of glass bubbles collapses is at least about 100 megapascals. In some embodiments, the plurality of glass bubbles is a graded fraction preparable by classifying a second plurality of glass bubbles, wherein the second plurality of glass bubbles has a higher percentage of glass bubbles with a size of up to ten micrometers than the first plurality of glass bubbles. Composites including the plurality of glass bubbles are also disclosed.
Abstract:
A composition that includes a polyolefin having first repeating units, hollow glass microspheres, a polyolefin impact modifier that is chemically non-crosslinked and free of polar functional groups, and a compatibilizer comprising the first repeating units and second repeating units, which are the first repeating units modified with polar functional groups. Articles made from the composition and methods of making an article by injection molding the composition are also disclosed.