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    RUBBER-BASED MULTILAYER PRESSURE-SENSITIVE ADHESIVE ASSEMBLY
    1.
    发明申请
    RUBBER-BASED MULTILAYER PRESSURE-SENSITIVE ADHESIVE ASSEMBLY 审中-公开
    基于橡胶的多层压敏粘合剂组件

    公开(公告)号：WO2016077133A1

    公开(公告)日：2016-05-19

    申请号：PCT/US2015/059151

    申请日：2015-11-05

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： BIEBER, Pierre R. ,  STEGMAIER, Petra M. ,  OVERBECK, Janina R. ,  GOEB, Siegfried R.

    IPC: C09J7/02 ,  C09J153/02

    CPC classification number: B32B37/12 ,  B32B5/18 ,  B32B7/12 ,  B32B27/065 ,  B32B27/22 ,  B32B37/15 ,  B32B2266/02 ,  C09J7/22 ,  C09J7/38 ,  C09J125/02 ,  C09J153/02 ,  C09J2201/622 ,  C09J2400/243 ,  C09J2425/00 ,  C09J2453/00

    Abstract: The present disclosure relates to a multilayer pressure sensitive adhesive assembly comprising a polymeric foam layer and a first pressure sensitive adhesive layer adjacent to the polymeric foam layer, wherein first the pressure sensitive adhesive comprises: a) a multi-arm block copolymer of the formula Q n -Y, wherein: (i) Q represents an arm of the multi-arm block copolymer and each arm independently has the formula G-R, (ii) n represents the number of arms and is a whole number of at least 3, and (iii) Y is the residue of a multifunctional coupling agent, wherein each R is a rubbery block comprising a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or combinations thereof; and each G is a glassy block comprising a polymerized monovinyl aromatic monomer; b) a polymeric plasticizer having a weight average molecular weight Mw of at least 10.000 g/mol; c) at least one hydrocarbon tackifier, wherein the hydrocarbon tackifier(s) have a Volatile Organic Compound (VOC) value of less than 1000 ppm, when measured by thermogravimetric analysis according to the weight loss test methods described in the experimental section; and d) optionally, a linear block copolymer of the formula L-(G) m , wherein L is a rubbery block comprising a polymerized olefin, a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or any combinations thereof; and wherein m is 1 or 2; wherein the multilayer pressure sensitive adhesive assembly is obtained by hotmelt co-extrusion of the polymeric foam layer and the first pressure sensitive adhesive layer. The present disclosure also relates to a method of manufacturing such a multilayer pressure sensitive adhesive assembly and uses thereof.

    Abstract translation: 本公开涉及一种多层压敏粘合剂组合物，其包含聚合物泡沫层和邻近聚合物泡沫层的第一压敏粘合剂层，其中首先压敏粘合剂包括：a）式Qn的多臂嵌段共聚物 -Y，其中：（i）Q表示多臂嵌段共聚物的臂，每个臂独立地具有式GR，（ii）n表示臂数，并且是至少3的整数，（iii ）Y是多官能偶联剂的残基，其中每个R是包含聚合的共轭二烯的橡胶嵌段，聚合的共轭二烯的氢化衍生物或其组合; 并且每个G是包含聚合的单乙烯基芳族单体的玻璃质块; b）重均分子量Mw至少为10.000g / mol的聚合物增塑剂; c）至少一种烃增粘剂，其中当通过根据实验部分中描述的重量损失测试方法的热重分析测量时，烃增粘剂具有小于1000ppm的挥发性有机化合物（VOC）值; 和d）任选地，式L-（G）m的线性嵌段共聚物，其中L是包含聚合烯烃的橡胶嵌段，聚合共轭二烯，聚合共轭二烯的氢化衍生物或其任何组合; 并且其中m为1或2; 其中所述多层压敏粘合剂组件通过所述聚合泡沫层和所述第一压敏粘合剂层的热熔共挤出获得。 本公开还涉及制造这种多层压敏粘合剂组合物的方法及其用途。

    RUBBER-BASED PRESSURE-SENSITIVE ADHESIVE HAVING LOW VOC CHARACTERISTICS
    2.
    发明申请
    RUBBER-BASED PRESSURE-SENSITIVE ADHESIVE HAVING LOW VOC CHARACTERISTICS 审中-公开
    橡胶基压敏胶粘剂具有低挥发性特性

    公开(公告)号：WO2017196560A1

    公开(公告)日：2017-11-16

    申请号：PCT/US2017/030138

    申请日：2017-04-28

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： BIEBER, Pierre R. ,  STEGMAIER, Petra M. ,  MATZEIT, Niklas M. ,  OVERBECK, Janina R. ,  GOEB, Siegfried R. ,  BUETTNER, Joern ,  PARYS, Claudia ,  KLÜNKER, Eike H. ,  SATRIJO, Andrew ,  GONCALVES PIMENTEL, Nelson ,  STRERATH, Christiane

    IPC: C09J7/02 ,  C09J153/02

    CPC classification number: C09J7/383 ,  C08L23/22 ,  C08L53/02 ,  C08L71/12 ,  C08L91/00 ,  C08L2205/02 ,  C09J153/02 ,  C09J153/025 ,  C09J2205/11 ,  C09J2205/31

    Abstract: The present disclosure relates to a pressure sensitive adhesive comprising: a) a multi-arm block copolymer of the formula Q n -Y, wherein: (i) Q represents an arm of the multi-arm block copolymer and each arm independently has the formula G-R, (ii) n represents the number of arms and is a whole number of at least 3, and (iii) Y is the residue of a multifunctional coupling agent, wherein each R is a rubbery block comprising a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or combinations thereof; and each G is a glassy block comprising a polymerized monovinyl aromatic monomer; b) a polymeric plasticizer having a weight average molecular weight M w comprised between 10.000 and 100.000 g/mol; c) at least one hydrocarbon tackifier which is primarily compatible with the rubbery blocks; d) a glassy block compatible aromatic resin having a softening point value (RBSP) of at least 150C, when measured by the ring and ball test method described in the experimental section; and e) optionally, a linear block copolymer of the formula L-(G) m , wherein L is a rubbery block comprising a polymerized olefin, a polymerized conjugated diene, a hydrogenated derivative of a polymerized conjugated diene, or any combinations thereof; and wherein m is 1 or 2. The present disclosure also relates to a method of manufacturing such a pressure sensitive adhesive and uses thereof.

    Abstract translation: 本发明涉及压敏粘合剂，其包含：a）式Q n -Y的多臂嵌段共聚物，其中：（i）Q表示 多臂嵌段共聚物的臂和各臂独立地具有式GR，（ii）n表示臂的数量并且是至少3的整数，并且（iii）Y是多官能偶联剂的残基， 其中每个R为包含聚合的共轭二烯，聚合的共轭二烯的氢化衍生物或其组合的橡胶状嵌段; 并且每个G是包含聚合的单乙烯基芳族单体的玻璃状嵌段; b）重均分子量M w为10.000至100.000g / mol的聚合物增塑剂; c）至少一种主要与橡胶块相容的烃增粘剂; d）当通过实验部分中描述的环球试验方法测量时，软化点值（RBSP）至少为150℃的玻璃状嵌段相容性芳族树脂; 和e）任选地，式L-（G）m-1的线型嵌段共聚物，其中L为包含聚合烯烃，聚合共轭二烯，聚合共轭二烯的氢化衍生物 ，或其任何组合; 并且其中m是1或2.本公开还涉及制造这种压敏粘合剂的方法及其用途。

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