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公开(公告)号:US11414770B2
公开(公告)日:2022-08-16
申请号:US16497883
申请日:2018-03-28
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Krzysztof A. Lewinski , Sean M. Luopa , Jiyoung Park , Attila Molnar
Abstract: Water electrolyzer comprising a membrane having first and second opposed major surfaces, a thickness extending between the first and second major surfaces, and first, second, and third regions equally spaced across the thickness, wherein the first region is the closest region to the first major surface, wherein the second region is the closest region to the second major surface, wherein the third region is located between the first and second regions, wherein the first and third regions are each essentially free of both metallic Pt and Pt oxide, and wherein the second region comprises at least one of metallic Pt or Pt oxide; a cathode comprising a first catalyst on the first major surface of the membrane; and an anode comprising a second catalyst on the second major surface of the membrane.
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公开(公告)号:US20210013521A1
公开(公告)日:2021-01-14
申请号:US15733644
申请日:2019-03-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Andrew J. L. Steinbach , Krzysztof A. Lewinski , Andrew T. Haug , Amy E. Hester , Sean M. Luopa , Grant M. Thoma
IPC: H01M4/92 , H01M8/1004 , H01M4/86 , H01M4/90
Abstract: Catalysts comprising nanostructured elements comprising microstructured whiskers having an outer surface at least partially covered by a catalyst material comprising at least 90 atomic percent collectively Pt, Ni, and Ta, wherein the Pt is present in a range from 32.0 to 35.7 atomic percent, the Ni is present in a range from 57.2 to 64.0 atomic percent, and the Ta is present in a range from 0.26 to 10.8 atomic percent, and wherein the total atomic percent of Pt, Ni, and Ta equals 100. Catalyst described herein are useful, for example, in fuel cell membrane electrode assemblies.
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公开(公告)号:US20210260989A1
公开(公告)日:2021-08-26
申请号:US17274670
申请日:2019-09-20
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Raymond P. Johnston , Andrew J.L. Steinbach , Krzysztof A. Lewinski , Fuxia Sun , Andrew T. Haug , John E. Abulu , Sean M. Luopa , Jiyoung Park , Attila Molnar , Cedric Bedoya
IPC: B60K15/03 , C25B1/04 , C25B9/23 , C25B11/055 , C25B11/081 , F17C5/06
Abstract: A hydrogen fueling system for generating hydrogen on demand is described. The system includes an electrolyzer configured to generate at least a predetermined quantity of hydrogen in a predetermined time when operated at no less than a predetermined current density and provided with at least a predetermined electrical energy over the predetermined time, where the predetermined quantity of hydrogen is at least 1 kg of hydrogen, the predetermined time is no more than 30 minutes, and the predetermined current density is at least 5 A/cm2. The system may further include an electrical energy storage system electrically connected to the electrolyzer and capable of supplying at least 20% of the predetermined electrical energy over the predetermined time. The electrolyzer may include an anode including a plurality of acicular particles dispersed in an ionomer binder, where the acicular particles include iridium.
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公开(公告)号:US20200149172A1
公开(公告)日:2020-05-14
申请号:US16741038
申请日:2020-01-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tyler S. Matthews , Steven J. Hamrock , Marina M. Kaplun , Krzysztof A. Lewinski , Sean M. Luopa
Abstract: Described herein is a process for the reduction of carbon dioxide comprising: providing an electrochemical device comprising an anode, a cathode, and a polymeric anion exchange membrane therebetween, wherein the polymeric anion exchange membrane comprises an anion exchange polymer, wherein the anion exchange polymer comprises at least one positively charged group selected from a guanidinium, a guanidinium derivative, an N-alkyl conjugated heterocyclic cation, or combinations thereof; introducing a composition comprising carbon dioxide to the cathode; and applying electrical energy to the electrochemical device to effect electrochemical reduction of the carbon dioxide.
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公开(公告)号:US11973232B2
公开(公告)日:2024-04-30
申请号:US17045101
申请日:2019-03-27
Applicant: 3M Innovative Properties Company
Inventor: Andrew J. L. Steinbach , Andrew T. Haug , Amy Hester , Krzysztof A. Lewinski , Sean M. Luopa , Grant M. Thoma , Jonah D. Erlebacher
CPC classification number: H01M4/9058 , C22C5/04 , H01M4/926
Abstract: Nanoporous oxygen reduction catalyst material comprising at least 90 collectively Pt, Ni, and Ta. The nanoporous oxygen reduction catalyst material is useful, for example, in fuel cell membrane electrode assemblies.
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公开(公告)号:US11094953B2
公开(公告)日:2021-08-17
申请号:US15575454
申请日:2016-05-04
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Krzysztof A. Lewinski , Sean M. Luopa
IPC: H01M8/1004 , C25B1/04 , C25B9/23 , C25B9/73 , C25B11/031 , H01M4/88 , H01M4/90 , B82Y40/00
Abstract: Electrode membrane assembly having an oxygen evolution reaction electrodes, the electrode membrane assembly comprising nanostructured whiskers with at least one of metallic Ir or Ir oxide thereon. These oxygen evolution reaction electrodes when paired with suitable hydrogen evolution electrodes are useful, for example, in generating H2 and O2 from water.
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公开(公告)号:US20220059849A1
公开(公告)日:2022-02-24
申请号:US17309508
申请日:2019-10-28
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Andrew J. L. Steinbach , Amy E. Hester , Sean M. Luopa , Andrew T. Haug , Krzysztof A. Lewinski , Grant M. Thoma
Abstract: Catalyst material comprising nanoparticles dispersed within a metal oxide layer, the metal oxide layer comprises metal oxide comprising at least one metal cation, wherein the nanoparticles comprise Pt, wherein the nanoparticles comprise less than 10 atom % of oxygen, and wherein the metal oxide layer has an average thickness not greater than 50 nanometers. The catalyst material comprising nanoparticles dispersed within a metal oxide layer can be converted, for example, to nanoporous catalyst layer comprising nanoparticles fused together, wherein the nanoparticles comprise Pt, wherein the nanoparticles comprise less than 10 atom % of oxygen, and wherein the layer has an average thickness not greater than 50 nanometers. The nanoporous catalyst layer is useful, for example, in fuel cell membrane electrode assemblies.
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公开(公告)号:US11118274B2
公开(公告)日:2021-09-14
申请号:US16741038
申请日:2020-01-13
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tyler S. Matthews , Steven J. Hamrock , Marina M. Kaplun , Krzysztof A. Lewinski , Sean M. Luopa
Abstract: Described herein is a process for the reduction of carbon dioxide comprising: providing an electrochemical device comprising an anode, a cathode, and a polymeric anion exchange membrane therebetween, wherein the polymeric anion exchange membrane comprises an anion exchange polymer, wherein the anion exchange polymer comprises at least one positively charged group selected from a guanidinium, a guanidinium derivative, an N-alkyl conjugated heterocyclic cation, or combinations thereof; introducing a composition comprising carbon dioxide to the cathode; and applying electrical energy to the electrochemical device to effect electrochemical reduction of the carbon dioxide.
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公开(公告)号:US10570524B2
公开(公告)日:2020-02-25
申请号:US15327404
申请日:2015-08-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tyler S. Matthews , Steven J. Hamrock , Marina M. Kaplun , Krzysztof A. Lewinski , Sean M. Luopa
IPC: C25B3/00 , C25B1/10 , C25B9/10 , C25B13/08 , C25B9/08 , C25B13/02 , C25B1/00 , C25B3/04 , B01J41/13 , C08J5/22
Abstract: Described herein is a process for the reduction of carbon dioxide comprising: providing an electrochemical device comprising an anode, a cathode, and a polymeric anion exchange membrane therebetween, wherein the polymeric anion exchange membrane comprises an anion exchange polymer, wherein the anion exchange polymer comprises at least one positively charged group selected from a guanidinium, a guanidinium derivative, an N-alkyl conjugated heterocyclic cation, or combinations thereof; introducing a composition comprising carbon dioxide to the cathode; and applying electrical energy to the electrochemical device to effect electrochemical reduction of the carbon dioxide.
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公开(公告)号:US20170183789A1
公开(公告)日:2017-06-29
申请号:US15327404
申请日:2015-08-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Tyler S. Matthews , Steven J. Hamrock , Marina M. Kaplun , Krzysztof A. Lewinski , Sean M. Luopa
Abstract: Described herein is a process for the reduction of carbon dioxide comprising: providing an electrochemical device comprising an anode, a cathode, and a polymeric anion exchange membrane therebetween, wherein the polymeric anion exchange membrane comprises an anion exchange polymer, wherein the anion exchange polymer comprises at least one positively charged group selected from a guanidinium, a guanidinium derivative, an N-alkyl conjugated heterocyclic cation, or combinations thereof; introducing a composition comprising carbon dioxide to the cathode; and applying electrical energy to the electrochemical device to effect electrochemical reduction of the carbon dioxide.
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