Abstract:
Borderless vias (55) are formed in electrical connection with a lower metal feature of a metal pattern gap filled with HSQ (52). Heat treatment in an inert atmosphere is conducted before filling the through-hole to outgas water absorbed during solvent cleaning of the through-hole, thereby reducing via void formation and improving via integrity.
Abstract:
Spin-on HSQ (52) is employed to gap fill metal layers in manufacturing a high density, multimetal layer semiconductor device. The degradation of deposited HSQ layers during formation of borderless vias (55), as from photoresist stripping using an O2-containing plasma, is overcome by treating the degraded HSQ layer (52) with an H2-containing plasma to restore the dangling Si-H bonds, thereby passivating the surface and preventing moisture absorption, before filling the via opening with conductive material (56, 57), such as a barrier layer (57).