公开(公告)号：JPH0482851A

公开(公告)日：1992-03-16

申请号：JP19547190

申请日：1990-07-24

Applicant: AGENCY IND SCIENCE TECHN

Inventor： MIZUKAMI FUJIO ,  NIWA SHUICHI ,  TOBA MAKOTO ,  CHIEA KIEN YOO ,  TAN TEIN SUU ,  CHIYUU YUN MEI

IPC: B01J23/36 ,  C07B61/00 ,  C07C29/149 ,  C07C33/025

Abstract: PURPOSE:To easily obtain the subject compound useful as a raw material for surfactant, etc., under low hydrogen pressure at a low cost by hydrogenating oleic acid in the presence of a rhenium/tin solid catalyst exhibiting high catalytic activity and stability and produced by a specific reproducible process. CONSTITUTION:The objective compound can be produced in high selectivity by hydrogenating oleic acid with H2 under a pressure of 1-200kg/cm at 50-400 deg.C using a rhenium/tin solid catalyst prepared by using a rhenium compound and a tin compound as essential elements, adding aluminum, silicon or titanium compound to the elements, mixing the components in an organic solvent as necessary under heating to obtain a uniform solution, adding water to the solution, stirring the mixture as necessary under heating to effect the hydrolysis of the components, drying the gel produced by using the above procedures as essential procedures and, as necessary, subjecting the dried gel to calcination, reduction, etc. The above compound of aluminum, silicon or titanium is preferably alkoxide.

公开(公告)号：JPH0482852A

公开(公告)日：1992-03-16

申请号：JP19547290

申请日：1990-07-24

Applicant: AGENCY IND SCIENCE TECHN

Inventor： MIZUKAMI FUJIO ,  NIWA SHUICHI ,  TOBA MAKOTO ,  CHIEA KIEN YOO ,  TAN TEIN SUU ,  CHIYUU YUN MEI

IPC: B01J23/62 ,  C07B61/00 ,  C07C29/149 ,  C07C33/025

Abstract: PURPOSE:To easily obtain the subject compound useful as a raw material for surfactant, etc., under low hydrogen pressure at a low cost by hydrogenating oleic acid in the presence of a ruthenium/tin solid catalyst exhibiting high catalytic activity and stability and produced by a specific reproducible process. CONSTITUTION:The objective compound can be produced in high selectivity by hydrogenating oleic acid with H2 under a hydrogen pressure of 1-200kg/cm at 50-400 deg.C using a ruthenium/tin solid catalyst prepared by using a ruthenium compound and a tin compound as essential elements, adding aluminum or silicon compound to the elements, mixing the components in an organic solvent as necessary under heating to obtain a uniform solution, adding water to the solution, stirring the mixture as necessary under heating to effect the hydrolysis of the components, drying the gel produced by using the above procedures as essential procedures and, as necessary, subjecting the dried get to calcination, reduction, etc. The above compound of aluminum or silicon is preferably alkoxide.