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公开(公告)号:DE69514396D1
公开(公告)日:2000-02-17
申请号:DE69514396
申请日:1995-03-07
Applicant: AGENCY IND SCIENCE TECHN
Inventor: MAEDA KAZUYUKI , KIYOZUMI YOSHIMICHI , MIZUKAMI FUJIO
IPC: B01J20/18 , B01J20/22 , B01J20/281 , B01J27/14 , B01J29/83 , B01J31/02 , C01B37/08 , C07F9/09 , C07F9/38
Abstract: There is disclosed a crystalline aluminum organophosphate stable against heating, composed of a skeleton structure having micropores therein and represented by the following formula (I) in chemical composition: formula (I) [(Al2O3).(RPO2)x] wherein R represents an alkyl group, and x is such a number that 2.0
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公开(公告)号:CA2029024C
公开(公告)日:1996-07-09
申请号:CA2029024
申请日:1990-10-31
Applicant: AGENCY IND SCIENCE TECHN
Inventor: MAEDA KAZUYUKI , MIZUKAMI FUJIO , NIWA SHUICHI , TOBA MAKOTO , SHIMIZU KAZUO
IPC: C01B33/26 , C04B35/195 , C04B35/624 , C07F7/02 , C04B35/18 , C04B35/20 , C04B35/64
Abstract: A process for preparing a cordierite, which comprises dissolving a silicon compound, an aluminum compound and a magnesium compound in a molar ratio of 1:0.7 to 1:0.3 to 0.5 in a complexing agent represented by the formula R(OCH2CH2) nOH, wherein R is an alkyl group and n is an integer of 1 to 4; heating the resulting solution to bring about a ligand exchange reaction of the silicon compound, aluminum compound and magnesium compound with the complexing agent; conducting hydrolysis to form a gel; drying the gel and sintering the dried gel at 800 to 1450 C.
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公开(公告)号:DE68918038T2
公开(公告)日:1995-01-05
申请号:DE68918038
申请日:1989-10-10
Applicant: AGENCY IND SCIENCE TECHN , NISSAN MOTOR
Inventor: MIZUKAMI FUJIO , MAEDA KAZUYUKI , NIWA SHUICHI , TOBA MAKOTO , MINE JUNICHI
Abstract: A process for the production of alumina includes a method for controlling the specific surface area of alumina. Control of specific surface area is performed by controlling the porous structure of alumina. In the process, an aluminium alkoxide is subjected to hydrolysis for forming an alumina gel. Before hydrolysis a polyether is used as an organic solvent in order to control the porous structure of produced alumina.
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公开(公告)号:DE68910780T2
公开(公告)日:1994-03-31
申请号:DE68910780
申请日:1989-09-06
Applicant: NISSAN MOTOR , AGENCY IND SCIENCE TECHN
Inventor: MIZUKAMI FUJIO , MAEDA KAZUYUKI , NIWA SHUICHI , MINE JUNICHI
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公开(公告)号:DE69514396T2
公开(公告)日:2000-08-31
申请号:DE69514396
申请日:1995-03-07
Applicant: AGENCY IND SCIENCE TECHN
Inventor: MAEDA KAZUYUKI , KIYOZUMI YOSHIMICHI , MIZUKAMI FUJIO
IPC: B01J20/18 , B01J20/22 , B01J20/281 , B01J27/14 , B01J29/83 , B01J31/02 , C01B37/08 , C07F9/09 , C07F9/38
Abstract: There is disclosed a crystalline aluminum organophosphate stable against heating, composed of a skeleton structure having micropores therein and represented by the following formula (I) in chemical composition: formula (I) [(Al2O3).(RPO2)x] wherein R represents an alkyl group, and x is such a number that 2.0
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公开(公告)号:DE68910780D1
公开(公告)日:1993-12-23
申请号:DE68910780
申请日:1989-09-06
Applicant: NISSAN MOTOR , AGENCY IND SCIENCE TECHN
Inventor: MIZUKAMI FUJIO , MAEDA KAZUYUKI , NIWA SHUICHI , MINE JUNICHI
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公开(公告)号:CA2029024A1
公开(公告)日:1991-05-07
申请号:CA2029024
申请日:1990-10-31
Applicant: AGENCY IND SCIENCE TECHN
Inventor: MAEDA KAZUYUKI , MIZUKAMI FUJIO , NIWA SHUICHI , TOBA MAKOTO , SHIMIZU KAZUO
IPC: C01B33/26 , C04B35/195 , C04B35/624 , C07F7/02
Abstract: A process for preparing a cordierite, which includes dissolving a silicon compound, an aluminum compound and a magnesium compound in a molar ratio of 1:0.7 to 1:0.3 to 0.5 in a complexing agent represented by the formula R(OCH2CH2)nOH, wherein R is an alkyl group and n is an integer of 1 to 4; heating the resulting solution to bring about a ligand exchange reaction of the silicon compound, aluminum compound and magnesium compound with the complexing agent; conducting hydrolysis to form a gel; drying the gel and sintering the dried gel at 800 DEG to 1450 DEG C.
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公开(公告)号:DE68918038D1
公开(公告)日:1994-10-13
申请号:DE68918038
申请日:1989-10-10
Applicant: AGENCY IND SCIENCE TECHN , NISSAN MOTOR
Inventor: MIZUKAMI FUJIO , MAEDA KAZUYUKI , NIWA SHUICHI , TOBA MAKOTO , MINE JUNICHI
Abstract: A process for the production of alumina includes a method for controlling the specific surface area of alumina. Control of specific surface area is performed by controlling the porous structure of alumina. In the process, an aluminium alkoxide is subjected to hydrolysis for forming an alumina gel. Before hydrolysis a polyether is used as an organic solvent in order to control the porous structure of produced alumina.
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公开(公告)号:JPH02102117A
公开(公告)日:1990-04-13
申请号:JP25383588
申请日:1988-10-11
Applicant: AGENCY IND SCIENCE TECHN , NISSAN MOTOR
Inventor: MIZUKAMI FUJIO , MAEDA KAZUYUKI , NIWA SHUICHI , TOBA MAKOTO , MINE JUNICHI
IPC: C01F7/36
Abstract: PURPOSE:To obtain high-uniformity alumina of a wide range in its specific surface area including controlled pores by allowing aluminum alkoxide to react with polyether, then drying and calcining the gel formed by hydrolysis of the product. CONSTITUTION:An aluminum alkoxide is dissolved in an organic solvent and allowed to react with a polyether, then hydrolyzed to obtain a gel from the sol. Further the gel is further dried and calcined to give the objective alumina. In this process, polyether is used as a solvent to control the pores of the alumina product. The reaction temperature of the aluminum alkoxide in poly ether ranges from 10 deg.C to the boiling point of the polyether, preferably from 40 to 190 deg.C. The polyether used in the process is generally represented by the formula: R1(OR2),(OR3)m,(OR4)n,OR5 (R1 is alkyl; R2 through R4 are alkylene; R5 is alkyl; 1 is integer including 1).
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10.
公开(公告)号:JPH0826720A
公开(公告)日:1996-01-30
申请号:JP16426094
申请日:1994-07-15
Applicant: AGENCY IND SCIENCE TECHN
Inventor: KIYOZUMI YOSHIMICHI , MAEDA KAZUYUKI , MIZUKAMI FUJIO
Abstract: PURPOSE:To easily produce a film having a smooth surface made of an inorg. crystalline porous body having a zeolite structure. CONSTITUTION:When starting materials for hydrothermal synthesis charged into a reactor are converted into an inorg. crystalline porous body having a zeolite structure by a hydrothermal synthesis reaction, a liq. metal surface is allowed to exist in the reactor and utilized as a crystal growth field.
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