公开(公告)号：JPS62207249A

公开(公告)日：1987-09-11

申请号：JP4936486

申请日：1986-03-06

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KAWABATA KOJIRO ,  NAKAMURA TAKAYOSHI ,  TANAKA MOTOO ,  SEKIGUCHI TATSUO ,  MANDA EIICHIRO ,  NUMAJIRI KAZUYA

IPC: H01B1/12 ,  C07C67/00 ,  C07C253/00 ,  C07C255/31 ,  C07D339/06

Abstract: NEW MATERIAL:An electron acceptor shown by formula I (R is long-chain alkyl). EXAMPLE:Octadecyl tetracyanoquinodimethane. USE:An intermediate for synthesizing an electric charge transfer complex compound. The electron acceptor is reacted with an electron donor and a stable monomolecular layer is formed on the surface of water to give an electric charge transfer complex compound having improved electrical conductivity and stability. PREPARATION:A 2-ocatadecyl-1,4-bis(dicyanomethylene)cyclohexane shown by formula II is stirred with triethylamine and bromine in a solvent such as chloroform, etc., to give a compound shown by formula I. Tetrathiafulvalene is perferable as an electron donor to be combined with the electron donor and an electric charge transfer complex compound is shown by formula III.