PRODUCTION OF READILY REACTIVE MONOMER

    公开(公告)号:JP2000169412A

    公开(公告)日:2000-06-20

    申请号:JP34876598

    申请日:1998-12-08

    Inventor: WATANABE SHOJI

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing 2-iodoethyl vinyl ether having high reactivity, useful as a functional monomer for providing an adhesive, lacquer, etc., by polymerization. SOLUTION: 2-Chloroethyl vinyl ether of the formula CH2=CHOCH2CH2Cl is reacted with a metal iodide compound of the formula MI (M is an alkali metal compound) to give 2-iodoethyl vinyl ether of the formula CH2=CHOCH2 CH2I.

    3.
    发明专利
    失效

    公开(公告)号:JPH05301914A

    公开(公告)日:1993-11-16

    申请号:JP7719491

    申请日:1991-03-18

    Inventor: WATANABE SHOJI

    Abstract: PURPOSE:To obtain a new compound having cationic polymerization activity and useful as a component of a functional block copolymer to be compounded to an adhesive, etc., to improve the water-resistance, etc., of the adhesive by reacting a polystyryl dianion with 2-iodoethyl vinyl ether. CONSTITUTION:The objective polymer compound of formula II having a number- average molecular weight of 3,000-110,000 can be produced by reacting a polystyryl dianion of formula I n is positive integer) with 2-iodoethyl vinyl ether and adding a medium such as an alcohol to the obtained solution.

    READILY REACTIVE MONOMER AND PRODUCTION THEREOF

    公开(公告)号:JPH0446134A

    公开(公告)日:1992-02-17

    申请号:JP15309690

    申请日:1990-06-12

    Abstract: NEW MATERIAL:2-Iodoethyl vinyl ether expressed by formula I. USE:A monomer, having high reactivity and capable of readily introducing functional groups such as amino, alkyl, aryl or alkoxy group in polymerization thereof. PREPARATION:2-Chloroethyl vinyl ether expressed by formula II is reacted with a metallic iodide compound expressed by formula III (M is alkali metallic atom) to afford the objective 2-iodoethyl vinyl ether expressed by formula I.

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