公开(公告)号：JP2001143718A

公开(公告)日：2001-05-25

申请号：JP32098399

申请日：1999-11-11

Applicant: AGENCY IND SCIENCE TECHN ,  SUMITOMO METAL MINING CO

Inventor： MITARAI MASAAKI ,  FUNATO KEIRO ,  NARITA HIDEO ,  YOSHIDA TADASHI ,  CHO SENKOKU

IPC: H01M8/00 ,  H01M8/06

Abstract: PROBLEM TO BE SOLVED: To provide a method of generating electrical energy, which has a reduced carbon gas mission per unit electrical energy. SOLUTION: Disclosed herein is a method of generating electrical energy, which comprises the process of generating electrical energy from natural gas; adding methane to combustion exhaust gas containing carbon gas from the electrical energy-generating process, and reacting the methane with the carbon gas to reform the exhaust gas; and a process of generating electrical energy with a fuel cell using the reformed gas from the reforming process as a fuel.

公开(公告)号：JPH10292180A

公开(公告)日：1998-11-04

申请号：JP11754197

申请日：1997-04-21

Applicant: AGENCY IND SCIENCE TECHN

Inventor： YAMAMOTO MITSUYOSHI ,  KOTANIGAWA TAKESHI ,  YOSHIDA TADASHI

IPC: B01J27/187 ,  B01J37/28 ,  C10G1/06 ,  C10G45/06 ,  C10G45/48 ,  C10G49/04

Abstract: PROBLEM TO BE SOLVED: To provide a denitification and hydrogenating ring-opening reaction of a polycyclic aromatic compound, by using a phosphoric acid-loaded metal oxide catalyst. SOLUTION: This method for performing a denitrification and a hydrogenating ring-opening reaction of a polycyclic aromatic compound, is to perform a hydrogenation, a hetero atom removal and an aromatic ring-opening reaction of a polycyclic aromatic compound such as a liquefied coal oil, a heavy crude petroleum, etc., by using a phosphoric acid-loaded metal oxide catalyst. A method of direct liquefaction of coal, is to produce a high quality liquefied product by directly hydrogenating the aromatic compounds of the coal in low temperature reaction range of 350-430 deg.C by using the phosphoric acid-loaded metal oxide catalyst. The phosphoric acid-loaded metal oxide catalyst is a phosphoric acid-loaded manganese oxide/nickel oxide catalyst.

公开(公告)号：JPH0867880A

公开(公告)日：1996-03-12

申请号：JP22729594

申请日：1994-08-29

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KOTANIGAWA TAKESHI ,  YAMAMOTO MITSUYOSHI ,  YOSHIDA TADASHI ,  SASAKI MASAHIDE

IPC: B01J27/053 ,  C10G1/06

Abstract: PURPOSE: To efficiently and economically liquefy coal, by using a specific supported iron-based catalyst capable of reducing an amount of a catalyst added and advancing activation of coal itself without requiring addition of sulfur having troubles in treatment after reaction. CONSTITUTION: Coal is liquefied by using a supported type iron catalyst such as a supported sulfate type iron catalyst obtained by impregnating coal with ferric sulfate, neutralizing ferric sulfate with ammonia generated by urea decomposition in an aqueous solution to form a sulfate type iron catalyst and supporting the catalyst on coal. For example, pulverized coal is mixed with an aqueous solution having dissolved ferric sulfate and urea and the stirred coal is impregnated with ferric sulfate and heated to 96-98 deg.C. Urea in the aqueous solution is decomposed, ammonia is generated, ferric sulfate is neutralized to form sulfate type iron catalyst, which is supported on coal to give a sulfate type iron catalyst. By using this catalyst and tetralin as a circulating solvent, coal is liquefied under 100-300 atmospheric pressure and charging H2 gas to reaction system.

公开(公告)号：JPS62127391A

公开(公告)日：1987-06-09

申请号：JP26664585

申请日：1985-11-26

Applicant: AGENCY IND SCIENCE TECHN

Inventor： NARITA HIDEO ,  HASEGAWA YOSHIHISA ,  YOSHIDA RYOICHI ,  YOKOYAMA SHINICHI ,  YOSHIDA TADASHI ,  MAEKAWA WAKINORI ,  GOTO FUJITARO

IPC: C10G1/06

Abstract: PURPOSE:To streamline and promote coal liquefaction reaction by drawing out the gas phase within the reaction vessel besides the coal liquefaction product and condensing the same. CONSTITUTION:A preheated coal slurry in a paste form consisting of pulverized coal and an org. solvent is fed through a high pressure paste pump 1 and lines 14 and 16 into a reaction vessel 4, where it is reacted with the recycle gas circulated from a gas liq. separator 7 through a line 17 and a compressor 3 and pressurized hydrogen supplied from a compressor 2, thereby effecting liquefaction of the coal. The coal liquefaction product is transferred through a line 18 to the gas liq. separator 7. A vale 8 is opened, and hydrogen is pressed by means of the compressor 2 into a condenser 6 having a buffle plate 23, thereby causing the pressure of the condenser to reach a pressure higher by 5-10kg/cm than that of the reaction vessel 4. A valve 9 is opened and the liq. within a line 26, and a high-temp. separator 5 is discharged on the side of the reaction vessel 4. A valve 10 is opened, and the gas phase component within the reaction vessel 4 is introduced through the separator 5 and lines 26 and 27 into the condenser 6, thereby effecting condensation of the gas phase component.

公开(公告)号：JPH09194849A

公开(公告)日：1997-07-29

申请号：JP2579496

申请日：1996-01-19

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KOTANIGAWA TAKESHI ,  YAMAMOTO MITSUYOSHI ,  YOSHIDA TADASHI ,  SASAKI MASAHIDE ,  NAGAISHI HIROSHI

IPC: B01J23/46 ,  B01J23/656 ,  B01J23/89 ,  C07B61/00 ,  C07C5/10 ,  C07C15/20 ,  C10G1/06 ,  C10G45/52 ,  C10G47/14

Abstract: PROBLEM TO BE SOLVED: To liquefy coal efficiently by a ruthenium carrying metal oxide catalyst. SOLUTION: This method comprises directly hydrogenating aromatic nuclei of coal in the presence of a ruthenium-carrying metal oxide catalyst having the activity of selectively hydrogenating aromatic nuclei in a reaction zone at a temperature as low as 350-425 deg.C to produce a high-quality liquid product. The metal oxide is a compound double oxide comprising oxides of nickel, manganese, zinc and/or lanthanum. This catalyst has an excellent activity of nucleus hydrogenation under the conditions of direct liquefaction reaction. In a reaction zone at a temperature as low as 375-400 deg.C, the yields of products having a high depth of hydrogenation can be attained. A ruthenium-carrying metal oxide catalyst having a high activity of highly selective nucleus hydrogenation is provided.

公开(公告)号：JPH0491192A

公开(公告)日：1992-03-24

申请号：JP20890490

申请日：1990-08-06

Applicant: AGENCY IND SCIENCE TECHN

Inventor： YOSHIDA TADASHI ,  MAEKAWA WAKANORI ,  YOSHIDA RYOICHI ,  KOTANIGAWA TAKESHI ,  YOKOYAMA SHINICHI ,  YAMAMOTO MITSUYOSHI ,  NAGAISHI HIROSHI

IPC: C10G29/10

Abstract: PURPOSE:To effectively and selectively extract and separate polar compounds such as phenols and nitrogen compounds by hydrogenating a fossil fuel such as coal or petroleum and mixing the obtained naphtha distillate with an aqueous solution of an anionic surfactant. CONSTITUTION:A fossil fuel such as coal, petroleum or tar sand bitumen is hydrogenated in a bench scale liquefaction plant and subsequently distilled. The obtained naphtha fraction is mixed with the aqueous solution of an anionic surfactant such as a sodium alkylbenzene sulfonate to readily, efficiently and selectively extract and separate polar compounds such as phenol compounds and nitrogen compounds.

公开(公告)号：JPH03243691A

公开(公告)日：1991-10-30

申请号：JP4058090

申请日：1990-02-20

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KOTANIGAWA TAKESHI ,  NAGAISHI HIROSHI ,  MAEKAWA WAKINORI ,  YAMAMOTO MITSUYOSHI ,  YOKOYAMA SHINICHI ,  YOSHIDA TADASHI ,  YOSHIDA RYOICHI

IPC: B01J23/745 ,  B01J23/74 ,  C10G1/06

Abstract: PURPOSE:To obtain the low-boiling compounds from coal and bituminous material in high efficiency and to improve the effective use of the H2 gas to be consumed, by cracking the high-boiling compounds such as preasphaltene in the coal and bituminous materials using an acid-type iron oxide catalyst. CONSTITUTION:A raw material comprising (A) 100 pts.wt. of coal and (B) 100-2,000 (pref. 150-1,000) pts.wt. of bituminous materials is reacted, using an acid-type iron oxide catalyst, at 350 - 527 (pref. 400 - 450) deg.C under a hydrogen pressure of 10 -30 (pref. 15 - 30) MPa for 30 - 90 (pref. 40 - 60) min to carry out a coliquefaction. The above-mentioned catalyst can be prepared by the following process: urea is mixed with ferric sulfate and the mixture is dissolved in water followed by heating, and the resultant precipitate is washed with water and dried, and then calcined at 350 - 750 (pref. 400 - 500) deg.C.

公开(公告)号：JPH02170048A

公开(公告)日：1990-06-29

申请号：JP32515188

申请日：1988-12-23

Applicant: AGENCY IND SCIENCE TECHN ,  KANDA GIKEN SERVICE KK

Inventor： YOSHIDA TADASHI ,  MAEKAWA WAKUNORI ,  HASEGAWA YOSHIHISA ,  YOKOYAMA SHINICHI ,  YOSHIDA RYOICHI ,  NARITA HIDEO ,  NAGAISHI HIROSHI ,  KANDA YASUO

IPC: G01N31/00 ,  G01N31/12

Abstract: PURPOSE:To directly determine trace oxygen by thermally cracking a sample, bringing the thermally cracked gas into contact reaction with carbon to form a gas contg. carbon monoxide, separating the carbon monoxide from the formed gas, bringing the carbon monoxide into reaction with hydrogen to form methane and using the methane in a hydrogen flame ionizer, then making determination. CONSTITUTION:A thermally cracking section 1 and CO converter section 2 of the apparatus for analyzing trace oxygen are formed in the same reaction vessel and a sample injecting port 7 is added to the top end of the reaction tube. A thermal conductivity detector 4 is attached behind the formed gas separating section 3 of the apparatus. High-purity gaseous helium is branched to two systems as a carrier gas at the time of analyzing the gaseous sample with this apparatus. One of these gases is introduced to a reference side of a TCD and the other one is introduced to the thermally cracking section 1 side and is passed in the apparatus system until finally the gas is introduced to a detecting section 6. Various gases are formed by thermal cracking and the soln. sample is introduced from the sample injecting port 7 into the thermally cracking section1 by using a microsyringe. The thermally cracked gas is introduced into the converter section 2.

公开(公告)号：JPH04120192A

公开(公告)日：1992-04-21

申请号：JP24167690

申请日：1990-09-11

Applicant: AGENCY IND SCIENCE TECHN

Inventor： YOSHIDA TADASHI ,  MAEKAWA WAKINORI ,  YOSHIDA RYOICHI ,  KOTANIGAWA TAKESHI ,  YOKOYAMA SHINICHI ,  YAMAMOTO MITSUYOSHI ,  NAGAISHI HIROSHI ,  FUKUDA TAKASHI ,  IDOKAWA KIYOSHI ,  HIRAMA TOSHIMASA

IPC: B01J27/051 ,  C10G47/02 ,  C10G47/34

Abstract: PURPOSE:To improve heat efficiency of process and to efficiently improve light oil fraction yield by adding a hydrogen donative solvent to a heavy oil fraction and subjecting the fraction to hydrogenolysis reaction in the presence of a hydrogenating catalyst under a specific condition. CONSTITUTION:A hydrogen donative solvent such as tetralin, dihydroanthracene or dihydropyrene is added to a heavy oil fraction such as petroleum, tar sand bitumen or shale oil and subjected to hydrogenolysis reaction in the presence of a hydrogenating catalyst at 400-460 deg.C (preferably 420-450 deg.C) under 100-300kg/ cm G (preferably 100-200kg/cm G) hydrogen pressure to give a light oil fraction.

公开(公告)号：JPH03242243A

公开(公告)日：1991-10-29

申请号：JP4057990

申请日：1990-02-20

Applicant: AGENCY IND SCIENCE TECHN

Inventor： KOTANIGAWA TAKESHI ,  YOKOYAMA SHINICHI ,  YAMAMOTO MITSUYOSHI ,  MAEKAWA WAKINORI ,  YOSHIDA RYOICHI ,  YOSHIDA TADASHI ,  NAGAISHI HIROSHI

IPC: B01J23/46 ,  B01J27/02 ,  B01J27/10 ,  C10G1/06

Abstract: PURPOSE:To perform a reaction with a high degree of hydrogenation under mild conditions with a small amt. of a catalyst and to increase the efficiency of coal liquefaction by using an Ru-contg. catalyst as the catalyst for coal liquefaction. CONSTITUTION:An Ru-contg. catalyst obtd. by impregnating a soln. of an Ru compd. in an org. solvent or water into the oxide or sulfide of a metal such as Fe or Zr and drying the oxide or sulfide is used as a catalyst for coal liquefaction. Coal is allowed to react with hydrogen in the presence of a solvent and the Ru-contg. catalyst at about 350-520 deg.C under about 10-30MPa pressure for about 0-90min. Liquefaction with a high degree of hydrogenation is performed under such mild conditions with a very small amt. of the catalyst.