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公开(公告)号:CA2029481A1
公开(公告)日:1991-05-09
申请号:CA2029481
申请日:1990-11-07
Applicant: AGENCY IND SCIENCE TECHN , JSP CORP
Inventor: TOKIWA YUTAKA , IWAMOTO AKIRA , TAKEDA KIYOSHI
IPC: C08J5/00 , B29C47/00 , B29K67/00 , C08L67/00 , C08L67/04 , C08L101/00 , C08L101/16
Abstract: Biodisintegratable thermoplastic resin moldings and a process for producing same are disclosed, the biodisintegratable thermoplastic resin moldings being comprised of a thermoplastic aliphatic polyester resin as a matrix resin having dispersed therein another type of thermoplastic resin in a proportion of 40-75 weight % based on the whole resin. The biodisintegratable thermoplastic resin moldings are easily disintegratable after disposal in an environment where microorganisms exist so that the moldings can be reduced in bulkiness and give no harmful effect on the life of natural plants and animals. Thus, the present invention affords an effective means for solving various problems in the treatment of disposed plastic articles.
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2.
公开(公告)号:CA2029747A1
公开(公告)日:1991-05-15
申请号:CA2029747
申请日:1990-11-13
Applicant: AGENCY IND SCIENCE TECHN , JSP CORP
Inventor: TOKIWA YUTAKA , IWAMOTO AKIRA , TAKEDA KIYOSHI
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3.
公开(公告)号:CA2029747C
公开(公告)日:1997-11-11
申请号:CA2029747
申请日:1990-11-13
Applicant: AGENCY IND SCIENCE TECHN , JSP CORP
Inventor: IWAMOTO AKIRA , TOKIWA YUTAKA , TAKEDA KIYOSHI
Abstract: A biodegradable plastic composition is disclosed which includes a polycaprolactone and a poly-.beta.-hydroxybutyrate. Disclosed also is a biodegradable plastic shaped body formed of such a composition. The shaped body may be produced by melt-mixing a blend of a polycaprolactone, a poly-.beta.-hydroxybutyrate and a copolymerization catalyst to copolymerize a portion of the polycaprolactone with a portion of the poly-.beta.-hydroxy butyrate, thereby to obtain a caprolactone/.beta.-hydroxybutyric acid copolymer-containing melt, which is subsequently shaped into a desired form.
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公开(公告)号:BE1004007A5
公开(公告)日:1992-09-08
申请号:BE9001051
申请日:1990-11-08
Applicant: AGENCY IND SCIENCE TECHN , JSP CORP
Inventor: TOKIWA YUTAKA , IWAMOTO AKIRA , TAKEDA KIYOSHI
IPC: C08J5/00 , B29C47/00 , B29K67/00 , C08L67/00 , C08L67/04 , C08L101/00 , C08L101/16
Abstract: L'invention concerne des matières moulées en résines thermoplastiques biodégradables, caractérisées en ce qu'elles comprennent une résine de polyester aliphatique servant de résine-matrice dans laquelle est uniformément dispersée un autre type de résine thermoplastique, en une proportion de 40 à 75% en poids, sur base de la résine entière. On les obtient par l'extrusion d'un mélange malaxé à l'état fondu de 25-60% en poids d'une résine de polyester aliphatique et de 75 à 40% en poids d'une autre résine thermoplastique à travers une filière.
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5.
公开(公告)号:JPH04182112A
公开(公告)日:1992-06-29
申请号:JP28131790
申请日:1990-10-19
Applicant: AGENCY IND SCIENCE TECHN , JSP CORP
Inventor: TOKIWA YUTAKA , IWAMOTO AKIRA , TAKEDA KIYOSHI
IPC: C08J5/00 , B29C47/00 , B29K67/00 , C08L67/00 , C08L67/04 , C08L101/00 , C08L101/16
Abstract: PURPOSE:To obtain a molded item of resin capable of breaking microorganism and also having excellent mechanical property and secondary workability by using aliphatic polyester resin as matrix resin and mixing and dispersing thermoplastic resin in said matrix at a predetermined ratio. CONSTITUTION:Aliphatic polyester resins are polycondensation product of polyhydric carboxylic acid and polyhydric alcohol, polycondensation product of hydroxy acid and ring-opening polymerization product of lactone, which are hydrolyzed by the action of lipase. Thermoplastic resins are those of olefin, styrene, vinyl, acryl, amide, etc. A mixture of 25-60wt.% of said aliphatic polyester and 75-40wt.% of thermoplastic resins is extruded under conditions satisfying the formulas I, II. Extrusion is difficult to perform where etaA =10 and molded items wherein polyester resin is used as matrix cannot be obtained where etaB/etaA
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公开(公告)号:JPH03157450A
公开(公告)日:1991-07-05
申请号:JP29576589
申请日:1989-11-14
Applicant: AGENCY IND SCIENCE TECHN , JSP CORP
Inventor: TOKIWA YUTAKA , IWAMOTO AKIRA , TAKEDA KIYOSHI
Abstract: PURPOSE:To prepare a plastic molding capable of being perfectly decomposed with microorganism by molding a kneaded product prepared by thermally melting and mixing polycaprolactone with poly beta-hydroxybutyric acid in the presence of a catalyst into a desired shape. CONSTITUTION:A kneaded product prepared by thermally melting and mixing (A) 90-20wt.%, preferably 80-30wt.%, of polycaprolactone having a number- average mol.wt. of 1000-120000, preferably 10000-100000, with (B) 10-80wt.%, preferably 20-70wt.%, of poly beta-hydroxybutyric acid having a number-average mol.wt. of 10000-1000000, preferably 20000-200000, in the presence of (C) a catalyst (e.g. anhydrous zinc acetate) capable of copolymerizing the having A and B in an amount of 0.05-5wt.%, preferably 0.1-1wt.%, based on the total amount of the components A and B and containing the copolymer of caprolactone and beta-hydroxybutyric acid as a compatibilizing agent is molded into a desired shape to provide a microorganism-decomposable plastic molding.
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公开(公告)号:JPH0276575A
公开(公告)日:1990-03-15
申请号:JP22884488
申请日:1988-09-14
Applicant: AGENCY IND SCIENCE TECHN , FUJI LATEX CO
Inventor: DOI AKIO , TAKEDA KIYOSHI , SUZUKI TOMOO , KAJIKAWA SHINICHI
Abstract: PURPOSE:To enable the highly efficient and massive treatment of an isoprenic rubber by semi-continuously decomposing the isoprenic rubber with rubber- decomposing microorganisms belonging to the genus Nocardia or Rhodococcus under a non-sterilizing condition. CONSTITUTION:A reaction vessel provided with a ventilating equipment and/or a stirrer and with equipments for controlling the temperature and pH thereof, such as a jar fomenter for culturing microorganisms is charged with a nitrogen source, a phosphorus source, etc., as additive sources except the rubber according to an ordinary culturing method of aerobic microorganisms and subsequently maintained at a temperature of approximately 30 deg.C and at a pH of approximately 7. The wastes of an isoprenic rubber such as natural rubber are semi- continuously added in a load amount of 0.17-0.7g/l.day under a non-sterilizing condition and decomposed while culturing rubber-decomposing microorganisms belonging to the genus Nocardia or Rhodococcus. Since the rubber-decomposing ability of the microorganisms can be maintained even after operated for a long period, the method can be expected to be widely utilized as a readily controllable, biologically decomposing treatment method.
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公开(公告)号:JPS62195289A
公开(公告)日:1987-08-28
申请号:JP3602386
申请日:1986-02-20
Applicant: AGENCY IND SCIENCE TECHN
Inventor: KURANE RYUICHIRO , TAKEDA KIYOSHI , SUZUKI TOMOO
Abstract: PURPOSE:To produce a flocculant excellent in both environmental protection and safety with a high efficiency, by selecting a specific cultivation pH and air flow rate and cultivating a microorganism of the grenus Nocardia and having flocculating ability. CONSTITUTION:A microorganism of the genus Nocardia having the ability to produce a flocculant represented by Nocardia restrictus KR-I-3 (FERM-P No.4169) is cultivated. In the process, an organic nitrogen source containing at least one selected from yeat extract, casamino acid and peptone is added to a culture medium and the initial pH is adjusted to a neutral - alkaline region. The air flow ratio to the culture fluid is limited to
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公开(公告)号:JPH09194624A
公开(公告)日:1997-07-29
申请号:JP880796
申请日:1996-01-23
Applicant: AGENCY IND SCIENCE TECHN
Inventor: DOI AKIO , TAKEDA KIYOSHI , TOKIWA YUTAKA
Abstract: PROBLEM TO BE SOLVED: To provide a method for efficiently decomposing a hard rubber product, particularly a tire having a high natural rubber content by conducting treatment with a microorganism belonging to a particular genus in the presence of a soft rubber product. SOLUTION: A hard rubber product is treated with a microorganism belonging to the genus Nocardia in the presence of a soft rubber. Microorganisms belonging to the genus Nocardia include Nocardia NR-35A (stipulation number FERM P-7266 with National Institute of Bioscience and Human-Technology, Agency of Industrial Science &Technology). Soft rubber products as a substrate for growing of rubber degrading bacteria include natural and synthetic isoprene rubber products. Hard rubber products include tires. Regarding degradative reaction conditions, e.g. culture media usable herein include one containing a rubber as the substrate for the microorganism and, in addition, inorg. salts, containing such as nitrogen and phosphorus. The reaction may be conducted under the conditions of a temp. of 20 to 37 deg.C and a pH value of 6.0 to 8.0.
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公开(公告)号:JPH0196230A
公开(公告)日:1989-04-14
申请号:JP25505687
申请日:1987-10-09
Applicant: AGENCY IND SCIENCE TECHN
Inventor: DOI AKIO , TAKEDA KIYOSHI , SUZUKI TOMOO
Abstract: PURPOSE:To easily recover decomposed liquid of an isoprene rubber without causing side reactions, using an agent exhibiting strong rubber-decomposition activity, by contacting an isoprene rubber with cultured cell of a specific microorganism belonging to genus Xanthomonas or filtrate of cultured product, etc. CONSTITUTION:An isoprene rubber is decomposed by culturing a microbial strain belonging to genus Xanthomonas and capable of decomposing isoprene rubber and contacting an isoprene rubber with the cultured cell, filtrate of cultured product or their treated product. The microbial strain is preferably Xanthomonas NR-35Y (FERM 9640).
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