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公开(公告)号:JP2001026573A
公开(公告)日:2001-01-30
申请号:JP2000169520
申请日:2000-06-06
Applicant: KUMAMOTO PREFECTURE , AGENCY IND SCIENCE TECHN
Inventor: NAGAOKA SHOJI , NAGATA MASANORI , KISHI RYOICHI , UENO KATSUHIKO
IPC: C07D233/64 , C07C227/16 , C07C229/22 , C07C231/02 , C07C233/49 , C07D207/16 , C07D209/26 , C08F20/36 , C08F20/38 , C08F20/60
Abstract: PROBLEM TO BE SOLVED: To provide a synthetic method of an amino acid acryloyl monomer or an amino acid methacryloyl monomer that can protect an optically active site sufficiently exhibiting the properties of amino acid by formation of a copper complex and can permit inexpensive and safe acryloylation or meth-acryloylation and can be resinified through radical polymerization as in the same way in the syntheses of polyvinyl chloride, polystyrene, or the like. SOLUTION: Copper ion is added to an amino acid to form a copper complex at room temperature, then the substitution reaction with an acid chloride is carried out in an aqueous mixed solvent to form an amino acid acryloyl-copper complex or metharyloyl-copper complex, then the copper is removed from the organic solvent phase with a chelating agent at room temperature in a neutral region. The resultant amino acid acryloyl monomer or amino acid methacryloyl monomer is radically polymerized to synthesize a telomer or a polymer.
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公开(公告)号:JP2000281726A
公开(公告)日:2000-10-10
申请号:JP25089199
申请日:1999-09-03
Applicant: KUMAMOTO PREFECTURE , AGENCY IND SCIENCE TECHN
Inventor: NAGAOKA SHOJI , NAGATA MASANORI , KISHI RYOICHI , UENO KATSUHIKO
IPC: C07D233/64 , C07C231/02 , C07C233/49 , C07C327/34 , C07D207/16 , C07D209/20 , C08F20/36 , C08F20/60 , C08L101/16
Abstract: PROBLEM TO BE SOLVED: To provide a synthetic method of an amino acid acryloyl monomer or amino acid methacryloyl monomer and its telomer or polymer wherein an optically active site which sufficiently expresses property of an amino acid is protected by formation of a copper complex, acryloylation or methacryloylation can be also performed inexpensively and safely in water, and they can be resinified by a radical polymerization method similarly to a synthetic method of polyvinyl chloride or polystyrene. SOLUTION: After forming a copper complex at room temperature by adding a copper ion to an amino acid, an amino acid acryloyl-copper complex or methacryloyl-copper complex is produced by a substituting reaction of acid chloride in aqueous mixed solvents, and the copper is extracted from the organic layer with a chelating agent at room temperature and at a neutral region to be removed. Further, the telomer or polymer is synthesized by radically polymerizing the obtained amino acid acryloyl monomer or amino acid methacryloyl monomer.
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公开(公告)号:JP2000281830A
公开(公告)日:2000-10-10
申请号:JP8966999
申请日:1999-03-30
Applicant: KUMAMOTO PREFECTURE , AGENCY IND SCIENCE TECHN
Inventor: SUGATA TAKESHI , SAKO TAKESHI , OTAKE KATSUTO , NAGAOKA SHOJI , NAGATA MASANORI
Abstract: PROBLEM TO BE SOLVED: To provide the methods for separating and purifying carbon material that comprises the removal of resol resin or novolak resins from the carbon material without damage to the carbon material at a low temperature efficiently without occurrence of injurious or harmful substance on the outside of the system and provide the purification of the carbon material. SOLUTION: A carbon material-containing resin of crushed resol resin or novolak resin is allowed to react in a basic organic solvent of >=0.5 M of alkali concentration and contains 20 to 100 vol.% of water at 300-400 deg.C in the reactor to remove the resol resin or novolak resin component from the carbon material. Then, the carbon material is washed and purified whereby the carbon material is recovered from the carbon material-containing resin.
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公开(公告)号:JPH1087872A
公开(公告)日:1998-04-07
申请号:JP26124096
申请日:1996-09-09
Applicant: AGENCY IND SCIENCE TECHN , KUMAMOTO PREFECTURE
Inventor: SUGATA TAKESHI , NAKANE TAKASHI , SAKO TAKESHI , OTAKE KATSUTO , UENO KATSUHIKO , SATO SHINJI , NAGAOKA SHOJI , NAGATA MASANORI , NAGAYAMA SANPEI , KAMIMURA MAKOTO
IPC: C08J11/10
Abstract: PROBLEM TO BE SOLVED: To enable reinforcing fibers to be separated, recovered, and reused efficiently without damaging the fibers by bringing a fiber-reinforced plastic into contact and reaction with (sub)supercritical water. SOLUTION: After a fiber-reinforced plastic is charged into a reactor 1 and water supplied from a water cylinder 2 to a water tank 3 is charged into the reator 1 through a high-pressure pump 4 so that water occupies 1-50vol.% of the reactor 1, valves 5, 6 are closed and the reactor 1 is hermetically sealed. Then, a heat exchanger 8 and the reactor 1 are heated to 320-500 deg.C with a constant temp. bath 7 to bring water in the reactor 1 into a (sub)supercritical state. The reinforced plastic is brought into contact with the water in a (sub) supercritical state and thus is reacted. The reactor 1 is then returned to normal temp. and the valve 6 is opened to separate and recover a gaseous part contg. hydrocarbons, carbon dioxide, nitrogen, etc., through a trap 9.
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公开(公告)号:JPS61176359A
公开(公告)日:1986-08-08
申请号:JP1440085
申请日:1985-01-30
Applicant: AGENCY IND SCIENCE TECHN
Inventor: NAGAOKA SHOJI , KURUMAYA HAJIME , MORI YUICHI
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公开(公告)号:JPS6185958A
公开(公告)日:1986-05-01
申请号:JP20806284
申请日:1984-10-05
Applicant: Agency Ind Science Techn
Inventor: NAGAOKA SHOJI , TAKIUCHI HIDEYUKI , TANZAWA HIROSHI
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公开(公告)号:JP2014095032A
公开(公告)日:2014-05-22
申请号:JP2012247188
申请日:2012-11-09
Applicant: Kumamoto Prefecture , 熊本県 , Kumamoto Univ , 国立大学法人 熊本大学 , Sumitomo Seika Chem Co Ltd , 住友精化株式会社
Inventor: HORIKAWA MAKI , NAGAOKA SHOJI , SHIROSAKI TOMOHIRO , IHARA HIROTAKA , TAKATO MAKOTO , SAKURAI HIDEO , YAMAMOTO KATSUMASA , AKEMI HIDEHIKO
Abstract: PROBLEM TO BE SOLVED: To provide a conductive material that can be formed into a film by a simple method and also has good conductivity.SOLUTION: A complex obtained by complexing of polythiophene having a repeating unit represented by the formula (1), and anionic polysaccharide is superior in film forming properties and conductivity, and can be used as conductive materials.
Abstract translation: 要解决的问题:提供可以通过简单的方法形成膜的导电材料并且还具有良好的导电性。溶液:通过使具有由式(1)表示的重复单元的聚噻吩和阴离子 多糖的成膜性和导电性优异,可以用作导电材料。
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公开(公告)号:JP2009083027A
公开(公告)日:2009-04-23
申请号:JP2007254794
申请日:2007-09-28
Applicant: Kumamoto Prefecture , Kumamoto Univ , Nishinihon Nagase Co Ltd , 国立大学法人 熊本大学 , 熊本県 , 西日本長瀬株式会社
Inventor: NAGAOKA SHOJI , NAGATA MASANORI , IHARA HIROTAKA , TAKATO MAKOTO , SATO MASARU , HIRAKAWA KAZUNARI
IPC: B24B37/00 , H01L21/304
Abstract: PROBLEM TO BE SOLVED: To provide a polishing method for enabling highly uniform polishing by considerably reducing scratches, damages and waviness, and also enabling high speed polishing. SOLUTION: A polishing device 100 provided with a rotary surface plate 111 having a smooth surface and a weight 112 arranged oppositely to the surface of the rotary surface plate 111 to add pressing force to a workpiece M via the surface of the rotary surface plate 111 is prepared. After the workpiece M is mounted between the rotary surface plate 111 and the weight 112, and the pressing force is added to the workpiece M, at least one of the rotary surface plate 111 and the weight 112 is displaced in a direction orthogonal to an opposite direction of the rotary surface plate 111 and the weight 112. A polishing liquid 1 in which compound particles 2 having base materials 11 and abrasive grains 12 made of one or a plurality of kinds of inorganic materials and deposited on the surface of at least the base material 11 are dispersed in a dispersant 3, is supplied between the workpiece M and the rotary surface plate 111, to polish the surface on the rotary surface plate 111 side of the workpiece M. COPYRIGHT: (C)2009,JPO&INPIT
Abstract translation: 要解决的问题:提供一种抛光方法,通过显着减少划痕,损伤和波纹,并且还能够进行高速抛光,从而能够进行高度均匀的抛光。 解决方案:抛光装置100设置有具有平滑表面的旋转表面板111和与旋转表面板111的表面相对设置的重物112,以通过旋转表面的表面向工件M增加压力 制备板111。 在工件M安装在旋转表面板111和重物112之间,并且将加压力附加到工件M上之后,旋转表面板111和配重112中的至少一个在与相反的方向正交的方向上移位 旋转面板111和重物112的方向。一种抛光液体1,其中具有基材11的复合颗粒2和由一种或多种无机材料制成并且沉积在至少基体的表面上的磨粒12 材料11分散在分散剂3中,被供给到工件M和旋转面板111之间,以对工件M的旋转面板111侧的表面进行抛光。版权所有(C)2009,JPO&INPIT
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公开(公告)号:JP2014220164A
公开(公告)日:2014-11-20
申请号:JP2013099720
申请日:2013-05-09
Applicant: 熊本県 , Kumamoto Prefecture , 国立大学法人熊本大学 , Kumamoto Univ , 国立大学法人 熊本大学
Inventor: NAGAOKA SHOJI , SHIROSAKI TOMOHIRO , HORIKAWA MAKI , IHARA HIROTAKA , TAKATO MAKOTO
CPC classification number: Y02E10/542
Abstract: 【課題】色素増感型太陽電池の光電変換効率を向上する。【解決手段】色素増感型太陽電池は、透明電極18と、この透明電極18に積層された酸化物半導体層20と、この酸化物半導体層20の対向電極側に積層され、透明電極18側から入射する光を散乱する光散乱層22とからなる光電極12を備えている。光散乱層22は、例えばポリマーからなる母粒子26と該母粒子26の表面に担持された光散乱性を有する無機微粒子28とからなるコアシェル型の複合粒子24で構成されている。【選択図】図1
Abstract translation: 要解决的问题:提高染料敏化太阳能电池的光电转换效率。解决方案:染料敏化太阳能电池包括光电极12,其包括:透明电极18; 层叠在透明电极18上的氧化物半导体层20; 以及层叠在氧化物半导体层20的对电极侧的光散射层22,散射从透明电极18侧入射的光。 光散射层22由核 - 壳型复合颗粒24构成,其包括:由例如聚合物制成的基础颗粒26; 和载体在基础颗粒26的表面上并具有光散射性的无机细颗粒28。
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公开(公告)号:JP2005194176A
公开(公告)日:2005-07-21
申请号:JP2004357450
申请日:2004-12-09
Applicant: Hirotaka Ihara , Inoac Corp , Kumamoto Prefecture , 博隆 伊原 , 株式会社イノアックコーポレーション , 熊本県
Inventor: HAMAOKA SHIGENORI , NAGAOKA SHOJI , MORITA MASARU , SATO TAKAO , NAGATA MASANORI , IHARA HIROTAKA
Abstract: PROBLEM TO BE SOLVED: To provide a spherical carbon particle fixed with a titanium oxide and an iron oxide which is suitable for a wide range of uses such as a deodorant, an antimicrobial agent and a coating material because it is excellent in adsorbability of a harmful organic matter, it has decomposability of an organic matter by a photocatalytic function and it has a specified red color and to provide its manufacturing method.
SOLUTION: A metal mixture where the titanium oxide 14 and the iron oxide 16 are mechanically mixed beforehand is mixed with an organic raw material and a spherical matter having a specified diameter is formed. The spherical matter is heated and then the organic raw material is carbonized. The titanium oxide 14 and the iron oxide 16 are dispersed on the surface and inside of the carbon particle 12.
COPYRIGHT: (C)2005,JPO&NCIPIAbstract translation: 待解决的问题:提供固定有氧化钛和氧化铁的球形碳颗粒,其适用于各种用途,如除臭剂,抗菌剂和涂料,因为它具有优异的吸附性能 的有机物质,其通过光催化功能具有有机物质的分解性,并且具有特定的红色并提供其制造方法。 解决方案:将氧化钛14和氧化铁16预先机械混合的金属混合物与有机原料混合,形成具有特定直径的球形物质。 将球状物加热,然后将有机原料碳化。 氧化钛14和氧化铁16分散在碳颗粒12的表面和内部。版权所有(C)2005,JPO&NCIPI
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