公开(公告)号：WO1995005353A1

公开(公告)日：1995-02-23

申请号：PCT/US1994008986

申请日：1994-08-10

Applicant: ALLIEDSIGNAL INC.

Inventor： ALLIEDSIGNAL INC. ,  JOHNSON, Russell, Ward ,  MOELLER, Wendy, Christine ,  VAN DER PUY, Michael ,  KAISER, Mark ,  WANG, Li

IPC: C07C19/08

CPC classification number: C07C19/01 ,  C07C19/08 ,  C07C19/10 ,  C07C21/18

Abstract: Alternatives to chlorofluorocarbons are provided by the inventive process for synthesizing fluorine-containing products RCFbHc+a-1Hf+d-1FeCR' which may optionally be carried out without the isolation of any intermediate in a single reactor or a series of reactors. The process comprises combining chlorine-containing reactants RCClaFbHc and R'CCldFeHf in the presence of hydrogen and at least one catalyst. R and R' are chosen from the group consisting of halogens, halogenated hydrocarbons, and hydrocarbons, and at least one of R and R' contains fluorine, a and d are integers from 1 to 3, b, c, e, and f are integers from 0 to 2, the sum of a, b, and c is 3, and the sum of d, e, and f is 3, and further treating the coupled products in the presence of an optional catalyst with hydrogen or a fluorinating agent.

Abstract translation: 通过本发明的合成含氟产物RCFbHc + a-1Hf + d-1FeCR'的方法提供氯氟烃的替代方案，其可以任选地在单个反应器或一系列反应器中分离任何中间体的情况下进行。 该方法包括在氢气和至少一种催化剂的存在下混合含氯反应物RCClaFbHc和R'CCldFeHf。 R和R'选自卤素，卤代烃和烃，R和R'中的至少一个含有氟，a和d为1至3的整数，b，c，e和f为 0至2的整数，a，b和c的和为3，d，e和f的和为3，并在任选的催化剂存在下用氢或氟化剂进一步处理偶联产物 。

公开(公告)号：EP1115470B1

公开(公告)日：2005-11-16

申请号：EP99946992.7

申请日：1999-09-17

Applicant: AlliedSignal Inc.

Inventor： REHG, Timothy, J. ,  LIU, Di-Jia ,  WILLIAMS, James, C. ,  KAISER, Mark

IPC: B01D53/32 ,  H01M8/06 ,  C01B3/50 ,  C01B3/58 ,  C10K3/04

CPC classification number: H01M8/0662 ,  B01D53/326 ,  C01B3/50 ,  C01B3/583 ,  C01B2203/044 ,  C01B2203/047 ,  C10K1/32

公开(公告)号：EP1115470A1

公开(公告)日：2001-07-18

申请号：EP99946992.7

申请日：1999-09-17

Applicant: AlliedSignal Inc.

Inventor： REHG, Timothy, J. ,  LIU, Di-Jia ,  WILLIAMS, James, C. ,  KAISER, Mark

IPC: B01D53/32 ,  H01M8/06 ,  C01B3/50 ,  C01B3/58 ,  C10K3/04

CPC classification number: H01M8/0662 ,  B01D53/326 ,  C01B3/50 ,  C01B3/583 ,  C01B2203/044 ,  C01B2203/047 ,  C10K1/32

Abstract: A method and apparatus removes carbon monoxide from hydrogen rich fuel by means of a catalytic material that preferentially adsorbs carbon monoxide. The catalytic material is regenerated by an oxidizing agent that reacts with the carbon monoxide absorbed by the catalytic material. The reaction is initiated by an electrical current is generated either galvanically or electrolytically through the catalytic material. The carbon monoxide free gas thus produced may then be passed into a fuel cell in order to provide D.C. power.

公开(公告)号：EP0714384A1

公开(公告)日：1996-06-05

申请号：EP94925790.0

申请日：1994-08-10

Applicant: AlliedSignal Inc.

Inventor： JOHNSON, Russell, Ward ,  MOELLER, Wendy, Christine ,  VAN DER PUY, Michael ,  KAISER, Mark ,  WANG, Li

IPC: B01J23 ,  C07B61 ,  C07C17 ,  C07C19 ,  C07C21

CPC classification number: C07C19/01 ,  C07C19/08 ,  C07C19/10 ,  C07C21/18

Abstract: Alternatives to chlorofluorocarbons are provided by the inventive process for synthesizing fluorine-containing products RCFbHc+a-1Hf+d-1FeCR' which may optionally be carried out without the isolation of any intermediate in a single reactor or a series of reactors. The process comprises combining chlorine-containing reactants RCClaFbHc and R'CCldFeHf in the presence of hydrogen and at least one catalyst. R and R' are chosen from the group consisting of halogens, halogenated hydrocarbons, and hydrocarbons, and at least one of R and R' contains fluorine, a and d are integers from 1 to 3, b, c, e, and f are integers from 0 to 2, the sum of a, b, and c is 3, and the sum of d, e, and f is 3, and further treating the coupled products in the presence of an optional catalyst with hydrogen or a fluorinating agent.