公开(公告)号：WO1994014917A1

公开(公告)日：1994-07-07

申请号：PCT/US1993011835

申请日：1993-12-06

Applicant: ALLIEDSIGNAL INC.

Inventor： ALLIEDSIGNAL INC. ,  SINGH, Rajiv, R. ,  THOMAS, Raymond, H., P. ,  WILSON, D., P. ,  ROBINSON, R.

IPC: C09K05/06

CPC classification number: C09K5/063 ,  C09K5/066 ,  F28D20/003 ,  Y02E60/142

Abstract: An improved thermal energy storage system and a process for thermal energy storage and transfer are disclosed. The cooling medium, a clathrate forming mixture, comprises water, and a hydrofluorocarbon having at least carbon atoms and a molecular diameter less than about 7 ANGSTROM . Preferably the hydrofluorocarbon is selected from hydrofluoropropanes and more preferably is selected from the group consisting of CHF2CHFCHF2, CF2HCF2CH2F, CF3CHFCH2F, CF3CH2CF2H, CF3CF2CH3, CF3CHFCF2H, CF3CH2CF3, CF3CF2CF2H, CH2FCF2CF3, CHF2CF2CH3, CF3CF2CF2CH3, CF3CF2CF2CF2H, and CF3CFHCFHCF3.

Abstract translation: 公开了一种改进的热能存储系统和用于热能储存和转移的方法。 冷却介质，形成包合物的混合物包含水和具有至少碳原子且分子直径小于约7 ANGSTROM的氢氟烃。 优选地，氢氟烃选自氢氟丙烷，更优选选自CHF 2 CHFCHF 2，CF 2 HCF 2 CH 2 F，CF 3 CHFCH 2 F，CF 3 CH 2 CF 2 H，CF 3 CF 2 CH 3，CF 3 CHFCF 2 H，CF 3 CH 2 CF 3，CF 3 CF 2 CF 2 H，CH 2 CF 2 CF 3，CHF 2 CF 2 CH 3，CF 3 CF 2 CF 2 CH 3，CF 3 CF 2 CF 2 CF 2 H和CF 3 CFHCFHCF 3。

公开(公告)号：EP0675935A1

公开(公告)日：1995-10-11

申请号：EP94902506.0

申请日：1993-12-06

Applicant: AlliedSignal Inc.

Inventor： SINGH, Rajiv, R. ,  THOMAS, Raymond, H., P. ,  WILSON, D., P. ,  ROBINSON, R.

IPC: C09K5 ,  F28D20

CPC classification number: C09K5/063 ,  C09K5/066 ,  F28D20/003 ,  Y02E60/142

Abstract: An improved thermal energy storage system and a process for thermal energy storage and transfer are disclosed. The cooling medium, a clathrate forming mixture, comprises water, and a hydrofluorocarbon having at least carbon atoms and a molecular diameter less than about 7 ANGSTROM . Preferably the hydrofluorocarbon is selected from hydrofluoropropanes and more preferably is selected from the group consisting of CHF2CHFCHF2, CF2HCF2CH2F, CF3CHFCH2F, CF3CH2CF2H, CF3CF2CH3, CF3CHFCF2H, CF3CH2CF3, CF3CF2CF2H, CH2FCF2CF3, CHF2CF2CH3, CF3CF2CF2CH3, CF3CF2CF2CF2H, and CF3CFHCFHCF3.

公开(公告)号：EP0675935B1

公开(公告)日：1997-02-19

申请号：EP94902506.8

申请日：1993-12-06

Applicant: AlliedSignal Inc.

Inventor： SINGH, Rajiv, R. ,  THOMAS, Raymond, H., P. ,  WILSON, D., P. ,  ROBINSON, R.

IPC: C09K5/06 ,  C09K5/04 ,  F28D20/00

CPC classification number: C09K5/063 ,  C09K5/066 ,  F28D20/003 ,  Y02E60/142

Abstract: An improved thermal energy storage system and a process for thermal energy storage and transfer are disclosed. The cooling medium, a clathrate forming mixture, comprises water, and a hydrofluorocarbon having at least carbon atoms and a molecular diameter less than about 7 Å. Preferably the hydrofluorocarbon is selected from hydrofluoropropanes and more preferably is selected from the group consisting of CHF2CHFCHF2, CF2HCF2CH2F, CF3CHFCH2F, CF3CH2CF2H, CF3CF2CH3, CF3CHFCF2H, CF3CH2CF3, CF3CF2CF2H, CH2FCF2CF3, CHF2CF2CH3, CF3CF2CF2CH3, CF3CF2CF2CF2H, and CF3CFHCFHCF3.