公开(公告)号：JP2001213854A

公开(公告)日：2001-08-07

申请号：JP2000024891

申请日：2000-02-02

Applicant: ASAHI KASEI CORP

Inventor： OGAWA HIROO ,  KANEJIMA SADATAKA

IPC: B01J27/053 ,  C07B61/00 ,  C07C249/10 ,  C07C251/44

Abstract: PROBLEM TO BE SOLVED: To provide a method for producing cyclohexanone oxime by a few processes in high conversion/productivity with small energy consumption under a mild reaction condition by a simple operation/facility. SOLUTION: This method for producing cyclohexanone oxime is characterized in that benzene is used as a starting raw material and production processes comprise (1) a process for partially hydrogenating (A) benzene in the presence of a catalyst (A) to give cyclohexene, (2) a process for nitrating cyclohexene to give nitrocyclohexene and (3) a process for partially hydrogenating (B) nitrocyclohexene in the presence of a catalyst (B) to give cyclohexanone oxime.

公开(公告)号：JP2001213861A

公开(公告)日：2001-08-07

申请号：JP2000024890

申请日：2000-02-02

Applicant: ASAHI KASEI CORP

Inventor： OGAWA HIROO ,  KANEJIMA SADATAKA

IPC: C07D201/00 ,  C07D201/04

Abstract: PROBLEM TO BE SOLVED: To produce ε-caprolactam with an industrially advantageous simple method comprising small number of steps in high conversion of each step, high productivity and decreased energy consumption under a mild reaction condition with simple operation and equipment essentially without producing ammonium sulfate as a by-product while dispensing with a reaction reagent necessitating a complicate process for preparation. SOLUTION: ε-Caprolactam is produced by using benzene as a starting raw material and successively subjecting the material to partial hydrogenation, nitration, partial hydrogenation and vapor-phase rearrangement reaction.

公开(公告)号：JP2002275116A

公开(公告)日：2002-09-25

申请号：JP2001072710

申请日：2001-03-14

Applicant: ASAHI KASEI CORP

Inventor： KANEDA KIYOOMI ,  OGAWA HIROO

IPC: B01J27/185 ,  C07B61/00 ,  C07C45/33 ,  C07C45/38 ,  C07C45/39 ,  C07C47/232 ,  C07C47/54 ,  C07C49/04 ,  C07C49/385 ,  C07C49/78

Abstract: PROBLEM TO BE SOLVED: To provide a highly effective catalyst usable for oxidizing alcohols. SOLUTION: This method for producing an aldehyde or ketone is characterized by comprising oxidizing an alcohol in the presence of a palladium- immobilized hydroxyapatite obtained by immobilizing palladium on a hydroxyapatite represented by the general formula Ca10- Z(HPO4 )Z(PO4 )6- Z(OH)2- Z.nH2 O (wherein, Z is a number satisfying 0

公开(公告)号：JP2002274852A

公开(公告)日：2002-09-25

申请号：JP2001072709

申请日：2001-03-14

Applicant: ASAHI KASEI CORP

Inventor： KANEDA KIYOOMI ,  OGAWA HIROO

IPC: C01G45/00 ,  B01J27/236 ,  C01F7/00 ,  C01G51/00 ,  C07B61/00 ,  C07C45/33 ,  C07C45/38 ,  C07C47/232 ,  C07C47/54 ,  C07C49/786

Abstract: PROBLEM TO BE SOLVED: To provide a high efficiency catalyst which is used for the oxidation of alcohols and methylene compounds. SOLUTION: Metal is fixed to hydrotalcite expressed by the general formula of (M )a (M )b (OH )c Xd .n H2 O [wherein, M is a divalent metal and denotes at least one metal selected from Co, Mn, Fe, Zn and Mg; M is a tervalent metal, and denotes at least one metal selected from Al and Ru; and X denotes an anion other than a hydroxide ion (OH ); wherein, (a), (b), (c) and (d) are respectively positive numbers satisfying 2a+2b=c and b=md; wherein, (m) is the valance of the anion X, and is an integer of 1 to 4. (n) is the number of 0 to 30].