公开(公告)号：US20030170473A1

公开(公告)日：2003-09-11

申请号：US10353093

申请日：2003-01-29

Applicant: ATOFINA

Inventor： Christophe Lacroix

IPC: B32B027/08

CPC classification number: B32B1/08 ,  B32B7/10 ,  B32B27/08 ,  B32B27/34 ,  Y10T428/31732

Abstract: A multilayer structure based on polyamides, comprising: a first layer (1) formed from a polyamide P1 or from a blend of a polyamide P1 and a polyolefin PO1 having a P1 polyamide matrix, optionally, a layer (2a) formed from EVOH; a layer (2) formed from a blend of PA-6/12 copolyamides, one comprising by weight more 6 than 12 and the other more 12 than 6; a layer (3) formed from a polyamide P3, it being possible for P1 and P3 to be identical or different, the layers (1), (2), (2a) and (3) being successive and adhering to one another in their respective contact regions.

公开(公告)号：US20030124288A1

公开(公告)日：2003-07-03

申请号：US10301826

申请日：2002-11-22

Applicant: ATOFINA

Inventor： Joachim Merziger ,  Christophe Lacroix

IPC: B32B001/08

CPC classification number: B32B27/34 ,  B32B1/08 ,  F16L11/04 ,  F16L2011/047 ,  Y10T428/1393

Abstract: The present invention relates to a multilayer tube comprising, in its radial direction from the outside inwards: an outer layer formed from a polyamide chosen from PA-11 and PA-12, a layer formed from a tie compound, a layer formed from an EVOH, a layer formed from a blend of a polyamide and a polyolefin having a polyamide matrix a layer from a tie compound an inner layer formed from a polyamide chosen from PA-11 and PA-12 and including a dispersed electrically conducting filler producing a surface resistivity of less than 106null-null, the layers being successive and adhering to one another in their respective contact region. The tube of the present invention has a very low permeability to petrol, particularly to hydrocarbons and their additives, and in particular to alcohols, such as methanol and ethanol, or to ethers, such as MTBE or ETBE. These tubes also have good resistance to engine lubrication oils and fuels. The tube has very good mechanical properties at low or high temperatures.

Abstract translation: 本发明涉及一种多层管，其从外向内径向包括：由选自PA-11和PA-12的聚酰胺形成的外层，由连接化合物形成的层，由EVOH形成的层 ，由聚酰胺和聚烯烃的共混物形成的层，其具有来自连接化合物的层，聚酰胺和聚烯烃的共混物，所述内层由选自PA-11和PA-12的聚酰胺形成，并且包含分散的导电填料，其产生表面电阻率 小于106OMEGA正方形，这些层是连续的并且在各自的接触区域中彼此附着。 本发明的管具有非常低的汽油渗透性，特别是对烃及其添加剂，特别是醇，如甲醇和乙醇，或醚，如MTBE或ETBE。 这些管也具有良好的耐发动机润滑油和燃料的能力。 该管在低温或高温下具有非常好的机械性能。

公开(公告)号：US20030065107A1

公开(公告)日：2003-04-03

申请号：US10137734

申请日：2002-05-03

Applicant: ATOFINA

Inventor： Christophe Lacroix ,  Reinhard Linemann ,  Philippe Blondel ,  Yves Lermat

IPC: C08G063/91

CPC classification number: C08L101/00 ,  Y10T428/1352 ,  C08L2666/14

Abstract: The present invention relates to a composition comprising, per 100 parts by weight: 99 to 60 parts of a thermoplastic polymer (D), 1 to 40 parts of (A)null(B)null(C) (A) being a copolymer comprising polyamide blocks and polyether blocks, (B) being a polymer or an oligomer which comprises, in its chain, at least one ionic functional group and is chosen from: polyamides, copolymers comprising polyamide blocks and polyether blocks, thermoplastic polyesters or polyesteramides, copolymers comprising polyester blocks and polyether blocks, polyethers, polyurethanes. The invention also relates to the blends of (A) and (B) as product.

Abstract translation: 本发明涉及一种组合物，其包含每100份（重量）：99至60份热塑性聚合物（D），1至40份（A）+（B）=（C）（A） 聚酰胺嵌段和聚醚嵌段，（B）是聚合物或低聚物，其在其链中包含至少一个离子官能团，并且选自：聚酰胺，包含聚酰胺嵌段和聚醚嵌段的共聚物，热塑性聚酯或聚酯酰胺，包含 聚酯嵌段和聚醚嵌段，聚醚，聚氨酯。 本发明还涉及作为产品的（A）和（B）的共混物。

公开(公告)号：US20030165699A1

公开(公告)日：2003-09-04

申请号：US10353094

申请日：2003-01-29

Applicant: ATOFINA

Inventor： Christophe Lacroix

IPC: B32B003/14

CPC classification number: B32B27/08 ,  B32B1/08 ,  B32B7/10 ,  B32B27/30 ,  B32B27/34 ,  F16L11/04 ,  F16L2011/047 ,  Y10T428/31725 ,  Y10T428/31728 ,  Y10T428/31732 ,  Y10T428/31743

Abstract: A multilayer structure based on polyamides, comprising: a first layer (1) formed from a polyamide P1 or from a blend of a polyamide P1 and a polyolefin PO1 having a P1 polyamide matrix, optionally, a layer (2a) formed from EVOH; a layer (2) formed from a blend of PA-6/12 copolyamides, one comprising by weight more 6 than 12 and the other more 12 than 6; a layer (3) formed from a polyamide P3, it being possible for P1 and P3 to be identical or different, the layers (1), (2), (2a) and (3) being successive and adhering to one another in their respective contact regions.

Abstract translation: 一种基于聚酰胺的多层结构，包括：由聚酰胺P1形成的第一层（1）或由聚酰胺P1和具有P1聚酰胺基质的聚烯烃PO1的共混物形成的任选的由EVOH形成的层（2a）; 由PA-6/12共聚酰胺的共混物形成的层（2），一个重量比6重量多，另外多于12个; 由聚酰胺P3形成的层（3），P1和P3可以相同或不同，层（1），（2），（2a​​）和（3）在它们的 各个接触区域。

公开(公告)号：US20030130429A1

公开(公告)日：2003-07-10

申请号：US10213446

申请日：2002-08-07

Applicant: ATOFINA

Inventor： Alain Bouilloux ,  Christophe Lacroix

IPC: C08L023/00

CPC classification number: C08L23/10 ,  C08L23/06 ,  C08L23/0815 ,  C08L23/0853 ,  C08L23/0869 ,  C08L2314/06 ,  C08L2666/04

Abstract: The invention relates to a composition based on polypropylene homopolymer or copolymer and on an impact modifier comprising an ethylene/alkyl acrylate copolymer. This composition comprises substantially between 1 and 40% by weight of impact modifier and it may comprise an ethylene-based copolymer taken from the group comprising ethylene/acrylate copolymers, vinyl acetate copolymers, polyethylene obtained by metallocene catalysis or mPE and linear low-density polyethylene or LLDPE. The PP thus modified is useful for manufacturing motor-vehicle parts for example of the bumper or dashboard type, requiring good thermomechanical strength over a wide range of temperatures.

Abstract translation: 本发明涉及基于聚丙烯均聚物或共聚物的组合物以及包含乙烯/丙烯酸烷基酯共聚物的抗冲改性剂。 该组合物基本上包含1至40重量％的抗冲击改性剂，并且其可以包含乙烯/丙烯酸酯共聚物，乙酸乙烯酯共聚物，通过茂金属催化或mPE获得的聚乙烯和线性低密度聚乙烯的乙烯基共聚物 或LLDPE。 如此修改的PP可用于制造例如保险杠或仪表板类型的机动车零件，在宽的温度范围内需要良好的热机械强度。

公开(公告)号：US20030035971A1

公开(公告)日：2003-02-20

申请号：US10174507

申请日：2002-06-19

Applicant: ATOFINA

Inventor： Philippe Bussi ,  Christophe Lacroix ,  David Silagy

IPC: B32B027/08

CPC classification number: B32B27/08 ,  B32B7/10 ,  B32B27/18 ,  B32B27/20 ,  B32B27/304 ,  Y10T156/10 ,  Y10T428/31504 ,  Y10T428/31725 ,  Y10T428/31743 ,  Y10T428/3175

Abstract: A structure made of a fluoropolymer layer and directly attached to one of its sides a tie layer based on a polyamide which results from the condensation of at least one diacid and at least one diamine of the following formula (1): 1 in which R1 represents H or nullZ1nullNH2 and Z1 represents an alkyl, a cycloalkyl or an aryl having up to 15 carbon atoms and R2 represents H or nullZ2nullNH2 and Z2 represents an alkyl, a cycloalkyl or an aryl having up to 15 carbon atoms, it being possible for R1 and R2 to be identical or different. The tie resin may also be a copolymer having polyamide blocks and polyether blocks, the polyamide blocks resulting from condensation of at least one diacid and at least one diamine of formula (1). The invention also relates to a structure comprising a fluoropolymer layer, the tie layer and a substrate layer, respectively, as well as to a structure comprising a tie layer, respectively. This structure may be placed between two substrate layers and may be in the form of a sheet, film, profile or tube. It is particularly useful in the form of a tube for transporting gasoline between the tank and the injection device in motor-vehicle engines.

Abstract translation: 由含氟聚合物层构成的结构，其直接附着在其一侧上，基于由至少一种二酸与至少一种下式（1）的二胺缩合产生的聚酰胺的连接层：其中R1表示H 或-Z1-NH2，Z1表示具有至多15个碳原子的烷基，环烷基或芳基，R2表示H或-Z2-NH2，Z2表示烷基，环烷基或至多15个碳原子的芳基， R1和R2可能相同或不同。 粘结树脂还可以是具有聚酰胺嵌段和聚醚嵌段的共聚物，由至少一种二酸和至少一种式（1）的二胺的缩合产生的聚酰胺嵌段。 本发明还涉及分别包括含氟聚合物层，连接层和基底层的结构，以及分别包括粘结层的结构。 该结构可以放置在两个基底层之间，并且可以是片，膜，轮廓或管的形式。 在汽车发动机中的罐和注射装置之间输送汽油的管子的形式特别有用。