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公开(公告)号:WO2006103170A1
公开(公告)日:2006-10-05
申请号:PCT/EP2006/060737
申请日:2006-03-15
Applicant: BASELL POLIOLEFINE ITALIA S.R.L. , MORINI, Giampiero , CAMURATI, Isabella Maria Vittoria , DALL'OCCO, Tiziano , LIGUORI, Dario , VITALE, Gianni
Inventor: MORINI, Giampiero , CAMURATI, Isabella Maria Vittoria , DALL'OCCO, Tiziano , LIGUORI, Dario , VITALE, Gianni
CPC classification number: C08F10/00 , C08F4/6565 , C08F4/6548
Abstract: Catalysts components for the polymerization of ethylene comprising Ti, Mg, halogen, OR I groups, where R I is a C1-C12 hydrocarbon group optionally containing heteroatoms, having specific relationship among OR I /Ti and Mg/Ti molar ratio and characterized by a specific SS-NMR pattern are particularly useful for preparing narrow MWD crystalline ethylene polymers.
Abstract translation: 用于聚合包含Ti,Mg,卤素,OR I基团的乙烯的催化剂组分,其中R 1是任选地含有杂原子的C 1 -C 12烃基,其具有特定关系 Ti和Mg / Ti摩尔比,并且通过特定的SS-NMR图谱表征特别适用于制备窄MWD结晶乙烯聚合物。
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公开(公告)号:WO2020249388A1
公开(公告)日:2020-12-17
申请号:PCT/EP2020/064491
申请日:2020-05-26
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: CAVALIERI, Claudio , MASSARI, Paola , CAMURATI, Isabella Maria Vittoria , PANTALEONI, Roberto , COLLINA, Gianni , VITALE, Gianni , CIARAFONI, Marco , GADDI, Benedetta
IPC: C08F210/06 , C08F2/00 , C08J5/18 , C08F210/14 , C08F210/16
Abstract: A propylene polymer composition comprising: a) from 15 wt% to 35 wt% of a propylene 1-hexene copolymer containing from 6.2 to 8.5 % by weight, of 1-hexene derived units having a Melt Flowrate from 3.5 to 8.5 g/10 min; b) from 15 wt% to 35 wt% of a propylene 1-hexene copolymer containing from 10.4 wt% to 14.5 wt%, of 1-hexene derived units having a Melt Flow Rate from 3.5 to 8.5 g/10 min; c) from 38 wt% to 68 wt% of a propylene ethylene copolymer containing from 3.4 wt% to 5.7 wt% of ethylene derived units, a having a Melt Flow Rate from 3.5 to 12.0 g/10 min; the sum of the amount of a), b) and c) being 100.
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公开(公告)号:WO2019166223A1
公开(公告)日:2019-09-06
申请号:PCT/EP2019/053512
申请日:2019-02-13
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MASSARI, Paola , FELISATI, Andrea , IZZI, Marco , CAVALIERI, Claudio , TARTARI, Davide , CAMURATI, Isabella Maria Vittoria , CAPUTO, Tiziana
Abstract: A multilayer film comprising at least one core layer comprising a polypropylene composition comprising: A) From 90 wt% to 50 wt%; of a propylene homopolymer; B) From 10 wt% to 50 wt%; of a propylene ethylene copolymer having: i) xylene soluble fraction at 25°C ranging from 14 wt% to 27 wt% ii) intrinsic viscosity of the fraction soluble in xylene at 25°C ranging from 1.0 to 2.4 dl/g; iii) melt flow rate ranging from 1.0 g/10 min to 4.0 g/10 min; iv) an ethylene content ranging from 5.0 wt% to 12.0 wt% the sum of A) and B) being 100wt%.
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公开(公告)号:WO2020249386A1
公开(公告)日:2020-12-17
申请号:PCT/EP2020/064488
申请日:2020-05-26
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: DE PALO, Roberto , TARTARI, Davide , GALVAN, Monica , CAVALIERI, Claudio , CAMURATI, Isabella Maria Vittoria
IPC: D01F6/30 , C08L23/14 , D01F8/06 , C08F210/06
Abstract: A fiber comprising a propylene ethylene copolymer, said propylene ethylene copolymer having: i) xylene soluble fraction at 25°C ranging from 14 wt% to 27 wt% ii) intrinsic viscosity of the fraction soluble in xylene at 25°C ranging from 1.0 to 2.4 dl/g; 111) melt flow rate, MFR, ranging from 1.0 g/10 min to 50.0 g/10 min; iv) an ethylene derived units content ranging from 5.0 wt% to 12.0 wt% v) the ethylene derived units content on the fraction insoluble in xylene at 25°C ranging from 2.5 wt% to 6.0 wt%; Vl) the ethylene derived units content on the fraction soluble in xylene at 25 °C ranging from 15.2. wt% to 30.2 wt% vii) the C 13 NMR sequences PEP measured on the fraction insoluble in xylene at 25°C ranging from 3.5mol% to 5.5mol% and the C 13 NMR sequences PEP measured on the fraction soluble in xylene at 25 °C ranging from 11.0 mol% to 14.2 mol%.
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公开(公告)号:WO2019052822A1
公开(公告)日:2019-03-21
申请号:PCT/EP2018/073313
申请日:2018-08-30
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: MASSARI, Paola , CAVALIERI, Claudio , TARTARI, Davide , CAPUTO, Tiziana , CAMURATI, Isabella Maria Vittoria
IPC: C08F210/16 , C08L23/14 , C08F210/06
Abstract: A propylene ethylene copolymer having: i) xylene soluble fraction at 25 °C ranging from 14 wt% to 27 wt% ii) intrinsic viscosity of the fraction soluble in xylene at 25°C ranging from 1.0 to 2.4 dl/g; iii) melt flow rate, MFR, ranging from 1.0 g/10 min to 50.0 g/10 min; iv) an ethylene derived units content ranging from 5.0 wt% to 12.0 wt% v) the ethylene derived units content on the fraction insoluble in xylene at 25 °C ranging from 2.5 wt% to 6.0 wt%; vi) the ethylene derived units content on the fraction soluble in xylene at 25 °C ranging from 15.2. wt% to 30.2 wt% vii) the C13 NMR sequences PEP measured on the fraction insoluble in xylene at 25°C ranging from 3.5mol% to 5.5mol% and the C13 NMR sequences PEP measured on the fraction soluble in xylene at 25°C ranging from 11.0 mol% to 14.2 mol%.
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6.
公开(公告)号:WO2011006776A1
公开(公告)日:2011-01-20
申请号:PCT/EP2010/059440
申请日:2010-07-02
Applicant: Basell Poliolefine Italia s.r.l. , VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella Maria Vittoria
Inventor: VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella Maria Vittoria
IPC: C08F210/08 , C08F4/649 , C08F4/651
CPC classification number: C08F210/08 , C08F10/08 , C08F110/08 , C08F4/651 , C08F4/6494 , C08F2500/15 , C08F2500/17 , C08F210/06
Abstract: A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH 2 =CHZ wherein Z is a C 3 -C 20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl 2 (b) an alkylaluminum cocatalyst; and (c) a compound of formula (I) as external donor wherein R 1 , R 2 , R 3 , R 4 and R 5 hydrogen atoms or C 1 -C 20 hydrocarbon radicals, or two R 1 , R 2 , R 3 and R 4 can be joined to form a C 5 -C 20 , saturated or unsaturated, ring.
Abstract translation: 一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法,其中α-烯烃选自式CH 2 = CHZ的乙烯,丙烯或α-烯烃,其中Z为C 3 -C 20烷基,其包括使1- 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下,包括:(a)固体组分,其包含Ti化合物和负载在MgCl 2(b)烷基铝助催化剂上的内电子给体化合物; 和(c)作为外给体的式(I)化合物,其中R1,R2,R3,R4和R5的氢原子或C1-C20烃基,或者两个R1,R2,R3和R4可以连接形成C5- C20,饱和或不饱和的环。
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7.
公开(公告)号:EP1863856B1
公开(公告)日:2013-09-18
申请号:EP06725065.4
申请日:2006-03-15
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: MORINI, Giampiero, Basell Poliolefine Italia S.p.A , CAMURATI, Isabella Maria Vittoria , DALL'OCCO, Tiziano , LIGUORI, Dario , VITALE, Gianni
CPC classification number: C08F10/00 , C08F210/16 , C08F4/6543 , C08F4/6565 , C08F210/08 , C08F2500/12
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公开(公告)号:EP3983454A1
公开(公告)日:2022-04-20
申请号:EP20727644.5
申请日:2020-05-26
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: CAVALIERI, Claudio , MASSARI, Paola , CAMURATI, Isabella Maria Vittoria , PANTALEONI, Roberto , COLLINA, Gianni , VITALE, Gianni , CIARAFONI, Marco , GADDI, Benedetta
IPC: C08F210/06 , C08F2/00 , C08J5/18 , C08F210/14 , C08F210/16
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9.
公开(公告)号:EP1863856A1
公开(公告)日:2007-12-12
申请号:EP06725065.4
申请日:2006-03-15
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: MORINI, Giampiero, Basell Poliolefine Italia S.p.A , CAMURATI, Isabella Maria Vittoria , DALL'OCCO, Tiziano , LIGUORI, Dario , VITALE, Gianni
CPC classification number: C08F10/00 , C08F210/16 , C08F4/6543 , C08F4/6565 , C08F210/08 , C08F2500/12
Abstract: A process for preparing crystalline ethylene (co)polymers comprising (co)polymerizing ethylene in the presence of carried out in the presence catalyst system comprising (a) a solid catalyst component comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having ORI/Ti molar ratio of at least 0.5, an amount of titanium, with respect to the total weight of said solid catalyst component, higher than 4% by weight, and showing a specific pattern of the SS-NMR; and (b) an aluminum alkyl compound as a cocatalyst. The process allows to obtain in good yelds ethylene polymers with narrow MWD.
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公开(公告)号:EP3759169A1
公开(公告)日:2021-01-06
申请号:EP19703375.6
申请日:2019-02-13
Applicant: Basell Poliolefine Italia S.r.l.
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