公开(公告)号：US20220072499A1

公开(公告)日：2022-03-10

申请号：US17424382

申请日：2020-01-21

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： TIZIANA CAPUTO ,  ANTONIO MAZZUCCO ,  NICOLO ARICH DE FINETTI ,  MARCO BOCCHINO

IPC: B01J19/00 ,  B01J19/24

Abstract: A method for monitoring and controlling the polymerization in a polymerization vessel by using a camera viewing unit to (a) detect features of the polymer particles, or the particles' environment, (b) compare the features to pre-defined acceptable values of these features or the environment, and (c) if a variation from the pre-defined values is detected, act on process parameters to reduce or eliminate the variation.

公开(公告)号：US20200216587A1

公开(公告)日：2020-07-09

申请号：US16647672

申请日：2018-08-30

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PAOLA MASSARI ,  CLAUDIO CAVALIERI ,  DAVIDE TARTARI ,  TIZIANA CAPUTO ,  ISABELLA MARIA VITTORIA CAMURATI

IPC: C08F210/06 ,  C08F2/34 ,  C08L23/14

Abstract: A propylene ethylene copolymer having: i) xylene soluble fraction at 25° C. ranging from 14 wt % to 27 wt %; ii) intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 1.0 to 2.4 dl/g; iii) melt flow rate, MFR, ranging from 1.0 g/10 min to 50.0 g/10 min; iv) an ethylene derived units content ranging from 5.0 wt % to 12.0 wt %; v) the ethylene derived units content on the fraction insoluble in xylene at 25° C. ranging from 2.5 wt % to 6.0 wt %; vi) the ethylene derived units content on the fraction soluble in xylene at 25° C. ranging from 15.2. wt % to 30.2 wt %; and vii) C13 NMR sequences PEP measured on the fraction insoluble in xylene at 25° C. ranging from 3.5 mol % to 5.5 mol % and C13 NMR sequences PEP measured on the fraction soluble in xylene at 25° C. ranging from 11.0 mol % to 14.2 mol %.

公开(公告)号：US20180066086A1

公开(公告)日：2018-03-08

申请号：US15559374

申请日：2016-03-14

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ROBERTA MARZOLLA ,  PAOLA MASSARI ,  NICOLETTA MARTINI ,  MARCO CIARAFONI ,  TIZIANA CAPUTO

IPC: C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08J5/18 ,  C08J2323/14 ,  C08F210/08 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/26 ,  C08F4/651 ,  C08F4/6545 ,  C08F4/6465 ,  C08F2/001

Abstract: A propylene, ethylene, 1-butene terpolymer made from or containing a) from about 1.8 wt % to about 5.9 wt % of ethylene derived units; and b) from about 2.0 wt % to about 4.5 wt % of 1 butene derived units; and having i) a ratio of C2 wt %/C4 wt % in the range from about 0.9 to about 1.3; wherein C2 wt % is the weight percent of ethylene derived units and C4 wt % is the weight percent of 1-butene derived units; ii) a Melt flow rate (determined according to ISO 1133 230° C., 2.16 kg) in the range from about 1.0 to about 30.0 g/10 min; and iii) a xylene soluble fraction at 25° C. between about 10 wt % and about 30 wt %. The weight percentages are based upon the total weight of the terpolymer.

公开(公告)号：US20160319058A1

公开(公告)日：2016-11-03

申请号：US15103203

申请日：2014-10-27

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ROBERTA MARZOLLA ,  TIZIANA CAPUTO

IPC: C08F210/06 ,  B32B27/32 ,  C08J5/18

CPC classification number: C08F210/06 ,  B32B27/32 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/14 ,  C08F210/08 ,  C08F2500/03 ,  C08F2500/26

Abstract: The present disclosure relates to a propylene ethylene 1-butene terpolymer wherein:(i) the content of ethylene derived units ranges from 1.1 wt % to 1.9 wt %, (ii) the content of 1-butene ranges from 5.0 wt % to 9.0 wt %, (iii) the melting point (Tm) of the non-nucleated terpolymer ranges from 125° C. to 137° C.; and (iv) the xylene soluble fraction at 25° C. is lower than 8.0 wt %.

公开(公告)号：US20160145365A1

公开(公告)日：2016-05-26

申请号：US14896644

申请日：2014-05-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： MARA DESTRO ,  MARCO CIARAFONI ,  PAOLA MASSARI ,  TIZIANA CAPUTO ,  THOMAS BOHM

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F2500/12 ,  C08F210/16 ,  C08F210/14

Abstract: A container comprising a propylene, ethylene, 1-hexene terpolymer wherein in the terpolymer: (i) the content of ethylene derived units ranges from 0.5 wt % to 2.0 wt %; (ii) the content of 1-hexene derived units ranges from 1.5 wt % to 5.5 wt %; (iii) the content of ethylene derived units fulfills the following equation (I); C2

Abstract translation: 一种包含丙烯，乙烯，1-己烯三元共聚物的容器，其中在三元共聚物中：（i）乙烯衍生单元的含量为0.5wt％至2.0wt％; （ii）1-己烯衍生单元的含量为1.5wt％至5.5wt％; （iii）乙烯衍生单元的含量满足下式（I）; C2

公开(公告)号：US20200032041A1

公开(公告)日：2020-01-30

申请号：US16495289

申请日：2018-03-23

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： GABRIELE MEI ,  ANTONIO MAZZUCCO ,  TIZIANA CAPUTO ,  ENRICO BALESTRA ,  DAVIDE TARTARI ,  GILBERTO MOSCARDI

IPC: C08L23/12 ,  C08L23/06

Abstract: A propylene ethylene copolymer having: (i) an ethylene derived units content (C2) ranging from 2.0 wt % to 11.0 wt %, based upon the total weight of the copolymer; (ii)) a fraction soluble in xylene (Xs) at 25° C. (Xs) ranging from 7.1 wt % to 28.5 wt %, based upon the total weight of the copolymer; (iii) an intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 3.2 dl/g to 5.6 dl/g; (iv) a melting point (Tm) higher than 140.0° C. and fulfilling the relation (I): Tm>155−1.4×C2   (I); and (v) a flexural modulus (TM) higher than 500 MPa and fulfilling the relation (II) TM>1900−285×C2+50×Xs   (II).

公开(公告)号：US20190023885A1

公开(公告)日：2019-01-24

申请号：US16064900

申请日：2016-11-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ANTONIO MAZZUCCO ,  GABRIELE MEI ,  TIZIANA CAPUTO ,  ROBERTO PANTALEONI ,  ENRICO BALESTRA ,  MARIA DI DIEGO ,  MARA DESTRO ,  RICCARDO RINALDI

IPC: C08L23/12

Abstract: A process for the preparation of polyolefins carried out in the presence of an antistatic composition made from or containing:a) a compound of formula R—OH wherein R represents hydrogen or a linear or branched, saturated alkyl group having from 1 to 15 carbon atoms; and b) an oligomeric or polymeric organic compound having one or more terminal hydroxyl groups and a viscosity at 40° C. of at least about 20 mm2/sec (DIN 51562).

公开(公告)号：US20200031957A1

公开(公告)日：2020-01-30

申请号：US16498303

申请日：2018-03-07

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： GABRIELE MEI ,  ANTONIO MAZZUCCO ,  TIZIANA CAPUTO ,  ENRICO BALESTRA ,  DAVIDE TARTARI ,  PAOLA MASSARI

IPC: C08F2/34 ,  C08F10/06 ,  C08F2/00 ,  C08F4/622 ,  C08L23/14 ,  C08F4/02

Abstract: Process for the preparation of heterophasic propylene copolymer compositions (RAHECO) made from or containing a random propylene copolymer (RACO) and an elastomeric propylene copolymer (BIPO), the process being carried out in a reactor having two interconnected polymerization zones, a riser and a downcomer, wherein growing polymer particles: (a) flow through the first polymerization zone, the riser, under fast fluidization conditions in the presence of propylene and of ethylene or an alpha-olefin having from 4 to 10 carbon atoms, thereby obtaining the random propylene copolymer (RACO); (b) leave the riser and enter the second polymerization zone, the downcomer, through which the growing polymer particles flow downward in a densified form in the presence of propylene and of ethylene or an alpha-olefin having from 4 to 10 carbon atoms, wherein the concentration of ethylene or of the alpha-olefin in the downcomer is higher than in the riser, thereby obtaining the elastomeric propylene copolymer (BIPO); and (c) leave the downcomer and are reintroduced into the riser, thereby establishing a circulation of polymer between the riser and the downcomer.

公开(公告)号：US20190336930A1

公开(公告)日：2019-11-07

申请号：US16477283

申请日：2017-12-15

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ENRICO BALESTRA ,  TIZIANA CAPUTO ,  MASSIMO COVEZZI ,  MAURIZIO DORINI ,  ANTONIO MAZZUCCO ,  GABRIELE MEI ,  RICARDO RINALDI

IPC: B01J8/24 ,  B01J8/18 ,  C08F2/01 ,  C08F2/44

Abstract: A fluid is fed into a polymer bed of a fluidized bed gas phase polymerization reactor by introducing the fluid into the polymer bed through a distributor protruding into the fluidized bed zone of the reactor and terminating with a discharge end positioned so that the following equation is fulfilled: d/D>0.002 wherein d is the distance of the distributor's discharge end from the wall of the reactor, and D is the diameter of the reactor in the fluidized bed zone.

公开(公告)号：US20170066855A1

公开(公告)日：2017-03-09

申请号：US15309138

申请日：2015-04-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PAOLA MASSARI ,  FABRIZIO PIEMONTESI ,  GIANNI VITALE ,  CAROLINE CATHELIN ,  GIAMPIERO MORINI ,  MARCO CIARAFONI ,  CLAUDIO CAVALIERI ,  TIZIANA CAPUTO

IPC: C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08F210/02 ,  C08F2800/20 ,  C08J5/18 ,  C08J2323/14 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F10/00 ,  C08F4/6492 ,  C08F4/6574

Abstract: The present disclosure relates to a propylene ethylene copolymer comprising: an ethylene content of between 1.8 and 10.0% by weight; a molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; a content of xylene soluble fraction (XS) and ethylene content (C2) that fulfills the following relationship: XS

Abstract translation: 一种丙烯乙烯共聚物，其特征在于以下特征：乙烯含量在1.8至10.0重量％之间; 分子量分布（MWD），以Mw / Mn表示，大于4.0; 二甲苯可溶成分（XS）和乙烯含量（C2）的含量满足下列关系：XS <（C2x2.1）-2.4其中：XS​​ =在25℃下可溶于二甲苯的馏分的重量％ C2 =通过NMR确定的共聚物中乙烯单元的重量％。