中科微点-全球专利检索

  1. Login
  2. Sign Up

Search Results

20 records (took 0.024 seconds)

    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS
    1.
    发明申请
    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：WO2007147740A1

    公开(公告)日：2007-12-27

    申请号：PCT/EP2007/055618

    申请日：2007-06-07

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  COLLINA, Gianni ,  DI DIEGO, Maria ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  VINCENZI, Paolo

    Inventor： COLLINA, Gianni ,  DI DIEGO, Maria ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  VINCENZI, Paolo

    IPC: B01J27/135 ,  B01J27/138 ,  C08F4/642 ,  C08F10/00

    CPC classification number: C08F10/00 ,  C08F210/06 ,  C08F4/6545 ,  C08F4/651 ,  C08F2/001 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

    Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and an electron donor is obtained by a batch process comprising: (A) A first step comprising reacting an adduct of formula MgCl 2 (ROH) n , where R is a C1-C10 alkyl group, and n is from 0.5 to 6, in a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature ranging from 0°C to 80°C and then removing the liquid medium; (B) A subsequent step comprising reacting the solid product obtained in (A) in a liquid medium comprising an electron donor ED selected from ethers, esters, ketones, silanes, amines, nitriles and amides, and a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C and then, after removing the liquid medium; (C) A subsequent step comprising reacting the solid product coming from (B) with a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C.

    Abstract translation: 通过分批方法获得包含Mg，Ti，卤素和电子给体的烯烃聚合的催化剂组分，包括：（A）第一步，包括使式MgCl 2（ROH） 在含有至少Ti-Cl键的钛化合物的液体介质中，其中R为C1-C10烷基，n为0.5至6，其中R为0〜 至80℃，然后除去液体介质; （B）后续步骤，包括使（A）中获得的固体产物在包含选自醚，酯，酮，硅烷，胺，腈和酰胺的电子给体ED的液体介质中，和至少具有Ti -Cl键在高于80℃的温度下，然后除去液体介质; （C）随后的步骤包括使来自（B）的固体产物与包含在高于80℃的温度下具有至少Ti-Cl键的钛化合物的液体介质反应。

    PROCESS FOR PREPARING CATALYST COMPONENTS FOR THE OLEFIN POLYMERIZATION
    3.
    发明申请
    PROCESS FOR PREPARING CATALYST COMPONENTS FOR THE OLEFIN POLYMERIZATION 审中-公开
    制备烯烃聚合催化剂组分的方法

    公开(公告)号：WO2005123783A1

    公开(公告)日：2005-12-29

    申请号：PCT/EP2005/005966

    申请日：2005-06-01

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  VINCENZI, Paolo ,  SPOTO, Rosa

    Inventor： VINCENZI, Paolo ,  SPOTO, Rosa

    IPC: C08F4/02

    CPC classification number: C08F10/00 ,  C08F110/02 ,  Y10T428/2982 ,  C08F4/6543 ,  C08F4/6567 ,  C08F4/6555 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/18

    Abstract: Process for the preparation of a solid catalyst component for the polymerization of olefins, the process comprising the steps of­: - continuously contacting solid particles of a MgCl 2 .mROH adduct, wherein 0.5 2 .nROH, wherein n is lower than m; - reacting the slurry from step a) with one or more titanium compounds of formula Ti(OR) p X q-p , wherein q=3-4 and p=0-q, X is an halogen and R is an alkyl, cicloalkyl or aryl radical having 1-18 carbon atoms.

    Abstract translation: 用于制备用于烯烃聚合的固体催化剂组分的方法，该方法包括以下步骤： - 连续接触MgCl 2 .mOH加合物的固体颗粒，其中0.5 <6.0，R是烷基，环烷基或芳基 具有1-12个碳原子，液相包含一种或多种能够与所述加合物的-OH基反应的化合物，以获得含有MgCl 2·nROH的浆料，其中n低于m; 使来自步骤a）的浆料与一种或多种式Ti（OR）pXq-p的钛化合物反应，其中q = 3-4且p = 0-q，X为卤素，R为烷基，环烷基或芳基 具有1-18个碳原子的基团。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    6.
    发明申请
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化组分

    公开(公告)号：WO2009080497A2

    公开(公告)日：2009-07-02

    申请号：PCT/EP2008/067118

    申请日：2008-12-09

    Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  PATRONCINI, Giovanni ,  VINCENZI, Paolo

    Inventor： VINCENZI, Paolo

    IPC: C08F10/00 ,  C08F4/651

    CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F2500/18 ,  C08F2500/24

    Abstract: Catalyst component having average particle size equal to or lower than 40 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 15 to 50% by mol with respect to the total amount of donors and selected from succinates of formula (I) below (I) in which the radicals R 1 and R 2 , equal to, or different from, each other are a C 1 -C 20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms; and the radicals R 3 and R 4 equal to, or different from, each other, are C 1 -C 20 alkyl, C3-C20 cycloalkyl, C5-C20 aryl, arylalkyl or alkylaryl group with the proviso that at least one of them is a branched alkyl; said compounds being, with respect to the two asymmetric carbon atoms identified in the structure of formula (I), stereoisomers of the type (S, R) or (R, S) and at least another electron donor compound which is extractable, under the test of extractability disclosed in the characterization section, for more than 30% by mol.

    Abstract translation: 平均粒度等于或小于40μm的催化剂组分包括卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种以15-50％的量存在，其量为15-50％ 相对于供体的总量，选自下列式（I）的琥珀酸酯（I），其中基团R 1和R 2彼此相同或不同，为C 1 -C 20直链或支链烷基，烯基 ，环烷基，芳基，芳烷基或烷基芳基，任选地含有杂原子; 并且彼此相同或不同的基团R 3和R 4是C 1 -C 20烷基，C 3 -C 20环烷基，C 5 -C 20芳基，芳基烷基或烷基芳基，条件是它们中的至少一个是支链烷基; 所述化合物相对于在式（I）结构中鉴定的两个不对称碳原子，是可以提取的（S，R）或（R，S）型的至少另一种电子给体化合物的立体异构体 在表征部分中公开的可萃取性试验，超过30％（摩尔）。

    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    10.
    发明公开
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：EP2545082A1

    公开(公告)日：2013-01-16

    申请号：EP11705595.4

    申请日：2011-03-01

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： BRITA, Diego ,  COLLINA, Gianni ,  EVANGELISTI, Daniele ,  GADDI, Benedetta ,  CARBONARA, Maria ,  VINCENZI, Paolo

    IPC: C08F4/654 ,  C08F4/649

    CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F4/022 ,  C08F4/6543 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/651

    Abstract: The present invention relates to catalysts component for the polymerization of ethylene and its mixtures with olefins CH
    2 =CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising Ti, Mg, halogen, and electron donor belonging to 1,2-diethers as internal electron donor compound. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high bulk density.

    Abstract translation: 本发明涉及用于乙烯及其与烯烃CH 2 = CHR的混合物聚合的催化剂组分，其中R为具有1-12个碳原子的烷基，环烷基或芳基，包含Ti，Mg，卤素和电子给体 到1,2-二醚作为内部电子给体化合物。 本发明的催化剂适合用于乙烯的（共）聚合过程以制备具有窄分子量分布（MWD）和高堆积密度的（共）聚合物。

Patent Agency Ranking