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公开(公告)号:DE59306830D1
公开(公告)日:1997-08-07
申请号:DE59306830
申请日:1993-04-08
Applicant: BASF AG
Inventor: PFLEGER KLAUS DR , ARNOLD GERHARD , SCHILLER SIEGFRIED , SCHUMACHER MANFRED
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公开(公告)号:DE4219129A1
公开(公告)日:1993-12-16
申请号:DE4219129
申请日:1992-06-11
Applicant: BASF AG
Inventor: PFLEGER KLAUS DR , ARNOLD GERHARD , SCHILLER SIEGFRIED , MUELLER HERBERT
IPC: C08F2/00 , C08F2/34 , C08F2/38 , C08F210/02 , C08F220/12 , H01B3/44
Abstract: A process for the preparation of copolymers of ethylene with acrylic esters (acrylates) by copolymerisation of 100 parts by weight of ethylene with from 0.1 to 25.0 parts by weight of acrylic esters in a continuous, tubular polymerisation system at pressures of from 500 to 4,000 bar and temperatures of from 100 to 400 DEG C in the presence of polymerisation initiators which decompose to form free radicals, where the temperature regime for the reaction mixture comprising ethylene, acrylic esters, polymerisation initiators and optionally regulators after entry into the reaction zone is designed in such a way that the quotient dT/dt (increase in temperature per time unit) is kept constant at a value between 1.5 and 2.5 DEG C per second.
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公开(公告)号:DE3784657D1
公开(公告)日:1993-04-15
申请号:DE3784657
申请日:1987-12-03
Applicant: BASF AG
Inventor: KANNE FRIEDRICH DR , MIETZNER FRANZ GEORG DR , PFLEGER KLAUS DR , KURSAWE SIEGFRIED , BOETTCHER KLAUS DR , ARNOLD GERHARD
Abstract: Continuous high pressure polymerisation systems for ethylene (co)polymerisation operate at 500-5000 bar and 150-400 deg.C and the unreacted gas is recycled to the polymerisation system through the high pressure recirculation system after relieving the pressure to 200-400 bar. If given pressure and/or temp. limits are exceeded or other difficulties occur, the pressure is relieved rapidly to a value below the polymerisation pressure by opening valve(s) and passing the hot reaction mixt. from the polymerisation system through expansion pipe(s) and sepn. system(s) into the atmos. The novelty is that, when the pressure is relieved, the polymerisation system is cut off into several sub-sections at the same time and only the sub-section in which the pressure is relieved into the atmos.
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公开(公告)号:AT86639T
公开(公告)日:1993-03-15
申请号:AT87117866
申请日:1987-12-03
Applicant: BASF AG
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公开(公告)号:NO170336B
公开(公告)日:1992-06-29
申请号:NO874154
申请日:1987-10-02
Applicant: BASF AG
Inventor: KANNE FRIEDRICH , PFLEGER KLAUS , GLOMB HANS , ARNOLD GERHARD , BOETTCHER KLAUS , KURSHAWE SIEGFRIED
IPC: B01J3/04 , B01J8/00 , B01J19/00 , C08F2/00 , C08F2/34 , C08F6/00 , C08F6/28 , C08F10/00 , C08F10/02
Abstract: Separating system (1 to 11) for tubular reactors or autoclaves used for the polymerisation of ethylene or copolymerisation of ethylene with ethylenically unsaturated comonomers in the presence of initiators at pressures of from 500 to 4000 bar and temperatures of from 150 to 350 DEG C, for reducing the emission of solids during relaxation processes of the reaction mixture present in the reactor or autoclave, characterised in that the relaxed reaction mixture is passed through at least two separating tanks (1, 1a) installed in series, before reaching the atmosphere.
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公开(公告)号:DE3750016D1
公开(公告)日:1994-07-14
申请号:DE3750016
申请日:1987-09-26
Applicant: BASF AG
Inventor: KANNE FRIEDRICH DR , PFLEGER KLAUS DR , GLOMB HANS , ARNOLD GERHARD , BOETTCHER KLAUS DR , KURSAWE SIEGFRIED
Abstract: Separating system (1 to 11) for tubular reactors or autoclaves used for the polymerisation of ethylene or copolymerisation of ethylene with ethylenically unsaturated comonomers in the presence of initiators at pressures of from 500 to 4000 bar and temperatures of from 150 to 350 DEG C, for reducing the emission of solids during relaxation processes of the reaction mixture present in the reactor or autoclave, characterised in that the relaxed reaction mixture is passed through at least two separating tanks (1, 1a) installed in series, before reaching the atmosphere.
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公开(公告)号:AT106904T
公开(公告)日:1994-06-15
申请号:AT87114099
申请日:1987-09-26
Applicant: BASF AG
Inventor: KANNE FRIEDRICH DR , PFLEGER KLAUS DR , GLOMB HANS , ARNOLD GERHARD , BOETTCHER KLAUS DR , KURSAWE SIEGFRIED
Abstract: Separating system (1 to 11) for tubular reactors or autoclaves used for the polymerisation of ethylene or copolymerisation of ethylene with ethylenically unsaturated comonomers in the presence of initiators at pressures of from 500 to 4000 bar and temperatures of from 150 to 350 DEG C, for reducing the emission of solids during relaxation processes of the reaction mixture present in the reactor or autoclave, characterised in that the relaxed reaction mixture is passed through at least two separating tanks (1, 1a) installed in series, before reaching the atmosphere.
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公开(公告)号:DE4214173A1
公开(公告)日:1993-11-04
申请号:DE4214173
申请日:1992-04-30
Applicant: BASF AG
Inventor: PFLEGER KLAUS DR , SCHILLER SIEGFRIED , ARNOLD GERHARD , MUELLER HERBERT
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公开(公告)号:NO167984B
公开(公告)日:1991-09-23
申请号:NO875046
申请日:1987-12-03
Applicant: BASF AG
Inventor: KANNE FRIEDRICH , MIETZNER FRANZ GEORG , PFLEGER KLAUS , KURSAWE SIEGFRIED , BOETTCHER KLAUS , ARNOLD GERHARD
Abstract: The pressure in a continuous high pressure polymerization system, in which ethylene, with or without comonomers, is polymerized under high pressures and temperatures and the unconverted amounts of gas are recycled through the high pressure recycle gas system into the polymerization system, is rapidly reduced to below the particular reaction pressure when predetermined limiting pressure and/or temperature values are exceeded or when other faults occur by opening one or more pressure-relief apparatuses mounted on the high pressure polymerization system and transferring the hot let-down reaction mixture from the polymerization system via one or more let-down lines through one or more separator systems into the atmosphere, by a process in which the high pressure polymerization system is divided into a plurality of isolated sections at the same time as the let-down process is triggered and only the section in which the let-down process is triggered is let down to the atmosphere. Preferably, the sections in which the let-down process is not triggered can be let down into the high pressure recycle gas system, if necessary through a product separator, in synchronization with triggering of the let-down to the atmosphere.
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公开(公告)号:DD264151A5
公开(公告)日:1989-01-25
申请号:DD30756487
申请日:1987-10-02
Applicant: BASF AG
Inventor: KANNE FRIEDRICH , PFLEGER KLAUS , GLOMB HANS , ARNOLD GERHARD , BOETTCHER KLAUS , KURSAWE SIEGFRIED
IPC: B01J3/04 , B01J8/00 , B01J19/00 , C08F2/00 , C08F2/34 , C08F6/00 , C08F6/28 , C08F10/00 , B01D47/06 , B01D50/00
Abstract: Separating system (1 to 11) for tubular reactors or autoclaves used for the polymerisation of ethylene or copolymerisation of ethylene with ethylenically unsaturated comonomers in the presence of initiators at pressures of from 500 to 4000 bar and temperatures of from 150 to 350 DEG C, for reducing the emission of solids during relaxation processes of the reaction mixture present in the reactor or autoclave, characterised in that the relaxed reaction mixture is passed through at least two separating tanks (1, 1a) installed in series, before reaching the atmosphere.
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