2.
    发明专利
    未知

    公开(公告)号:DE4219129A1

    公开(公告)日:1993-12-16

    申请号:DE4219129

    申请日:1992-06-11

    Applicant: BASF AG

    Abstract: A process for the preparation of copolymers of ethylene with acrylic esters (acrylates) by copolymerisation of 100 parts by weight of ethylene with from 0.1 to 25.0 parts by weight of acrylic esters in a continuous, tubular polymerisation system at pressures of from 500 to 4,000 bar and temperatures of from 100 to 400 DEG C in the presence of polymerisation initiators which decompose to form free radicals, where the temperature regime for the reaction mixture comprising ethylene, acrylic esters, polymerisation initiators and optionally regulators after entry into the reaction zone is designed in such a way that the quotient dT/dt (increase in temperature per time unit) is kept constant at a value between 1.5 and 2.5 DEG C per second.

    3.
    发明专利
    未知

    公开(公告)号:DE3784657D1

    公开(公告)日:1993-04-15

    申请号:DE3784657

    申请日:1987-12-03

    Applicant: BASF AG

    Abstract: Continuous high pressure polymerisation systems for ethylene (co)polymerisation operate at 500-5000 bar and 150-400 deg.C and the unreacted gas is recycled to the polymerisation system through the high pressure recirculation system after relieving the pressure to 200-400 bar. If given pressure and/or temp. limits are exceeded or other difficulties occur, the pressure is relieved rapidly to a value below the polymerisation pressure by opening valve(s) and passing the hot reaction mixt. from the polymerisation system through expansion pipe(s) and sepn. system(s) into the atmos. The novelty is that, when the pressure is relieved, the polymerisation system is cut off into several sub-sections at the same time and only the sub-section in which the pressure is relieved into the atmos.

    9.
    发明专利
    未知

    公开(公告)号:NO167984B

    公开(公告)日:1991-09-23

    申请号:NO875046

    申请日:1987-12-03

    Applicant: BASF AG

    Abstract: The pressure in a continuous high pressure polymerization system, in which ethylene, with or without comonomers, is polymerized under high pressures and temperatures and the unconverted amounts of gas are recycled through the high pressure recycle gas system into the polymerization system, is rapidly reduced to below the particular reaction pressure when predetermined limiting pressure and/or temperature values are exceeded or when other faults occur by opening one or more pressure-relief apparatuses mounted on the high pressure polymerization system and transferring the hot let-down reaction mixture from the polymerization system via one or more let-down lines through one or more separator systems into the atmosphere, by a process in which the high pressure polymerization system is divided into a plurality of isolated sections at the same time as the let-down process is triggered and only the section in which the let-down process is triggered is let down to the atmosphere. Preferably, the sections in which the let-down process is not triggered can be let down into the high pressure recycle gas system, if necessary through a product separator, in synchronization with triggering of the let-down to the atmosphere.

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