公开(公告)号：US3880940A

公开(公告)日：1975-04-29

申请号：US41807073

申请日：1973-11-21

Applicant: BASF AG

Inventor： BAER KARL ,  ELLIEHAUSEN HEINRICH ,  HOHENSCHUTZ HEINZ ,  STROHMEYER MAX ,  ZIRKER GUENTER

IPC: C07C29/14 ,  B01J23/00 ,  B01J23/883 ,  C07B61/00 ,  C07C27/00 ,  C07C29/141 ,  C07C31/02 ,  C07C67/00

CPC classification number: B01J23/883 ,  C07C29/141 ,  C07C31/12

Abstract: Manufacture of saturated aliphatic alcohols by hydrogenation of saturated aliphatic aldehydes at temperatures of from 140* to 230*C at pressures of from 50 to 350 atmospheres in the presence of catalysts containing from 5 to 15% by weight nickel and 5 to 20% by weight molybdenum supported on silicic acid, in which process catalysts are used which have been obtained by heating silicic acid carrier materials to temperatures of from 700* to 1200*C, impregnating the resulting silicic acid carrier materials with nickel and molybdenum salts, drying the resulting material with or without further heating to temperatures of from 200* to 500*C and subsequently treating the product with hydrogen at elevated temperature in conventional manner. The alcohols obtained are used as solvents or for the manufacture of plasticizers for polyvinyl chloride.

Abstract translation: 在含有5至15重量％镍和5至20重量％催化剂的催化剂存在下，通过在140至230℃的温度下，在50至350大气压的压力下，饱和脂族醛的氢化制备饱和脂族醇 负载在硅酸上的钼，其中使用通过将硅酸载体材料加热至700℃至1200℃的温度而获得的工艺催化剂，用镍和钼盐浸渍所得硅酸载体材料，干燥所得材料 有或没有进一步加热至200℃至500℃的温度，随后以常规方式在升高的温度下用氢处理产物。 所得的醇用作溶剂或制造聚氯乙烯的增塑剂。

公开(公告)号：US3427356A

公开(公告)日：1969-02-11

申请号：US3427356D

申请日：1967-03-14

Applicant: BASF AG

Inventor： BAER KARL ,  HOFFMANN HERWIG ,  SUESSENGUTH HERMANN

IPC: C07C209/48 ,  C07C85/12 ,  B01J11/22

CPC classification number: C07C209/48

公开(公告)号：DE2357751A1

公开(公告)日：1975-08-07

申请号：DE2357751

申请日：1973-11-20

Applicant: BASF AG

Inventor： BAER KARL ,  BROECKER FRANZ JOSEF DR ,  HOFFMANN HERWIG DR ,  MAROSI LASZLO DR ,  REISS WOLFGANG DR ,  SCHROEDER WOLFGANG DR

IPC: B01J23/72 ,  B01J23/745 ,  B01J23/86 ,  B01J27/232 ,  B01J31/22 ,  C07B61/00 ,  C07C27/00 ,  C07C29/42 ,  C07C33/04 ,  C07C67/00 ,  C07F1/08 ,  C07F5/06

公开(公告)号：FR1474661A

公开(公告)日：1967-03-24

申请号：FR56690

申请日：1966-04-06

Applicant: BASF AG

Inventor： WINDERL SIEGFRIED ,  HOFFMANN HERWIG ,  PALM CHRISTOF ,  NOHE HEINZ ,  BAER KARL ,  HARDERS HARTWIG

IPC: B01J23/16 ,  B01J23/68 ,  B01J23/70 ,  B01J23/88 ,  B01J23/888 ,  B01J23/89

公开(公告)号：CA1212933A

公开(公告)日：1986-10-21

申请号：CA448003

申请日：1984-02-22

Applicant: BASF AG

Inventor： BAER KARL ,  BASSLER PETER ,  DUEMBGEN GERD ,  FOUQUET GERD ,  KRABETZ RICHARD ,  MERGER FRANZ ,  NEES FRIEDBERT

IPC: C07C69/54 ,  B01J23/00 ,  B01J23/06 ,  B01J23/62 ,  C07B61/00 ,  C07C67/39

Abstract: Catalysts for the preparation of carboxylates from an aldehyde and an alkanol in the presence of oxygen, which contain palladium and lead as active components, these being present on a carrier containing zinc oxide, and the palladium being applied as a palladium salt in a solution containing hydrochloric acid and then being liberated by reduction, and whose carrier consists solely of zinc oxide, are particularly active and selective.

公开(公告)号：CA915708A

公开(公告)日：1972-11-28

申请号：CA915708D

Applicant: BASF AG

Inventor： TOUSSAINT HERBERT ,  BAER KARL ,  HOFFMANN HERWIG

公开(公告)号：FR1404710A

公开(公告)日：1965-07-02

申请号：FR978093

申请日：1964-06-12

Applicant: BASF AG

Inventor： BAER KARL ,  SPERBER HEINRICH ,  GOEHRE OTTO ,  LEIBNER GERHARD

IPC: B01J21/00

公开(公告)号：FR1274699A

公开(公告)日：1961-10-27

申请号：FR839862

申请日：1960-09-29

Applicant: BASF AG

Inventor： BAER KARL ,  HUEHN WERNER ,  HENGST KONRAD

IPC: C01B17/32

公开(公告)号：RO73246A

公开(公告)日：1982-09-09

申请号：RO7671373

申请日：1973-11-21

Applicant: BASF AG

Inventor： BAER KARL ,  ELLIEHAUSEN HEINRICH ,  HOHENSCHUTZ HEINZ ,  STROHMEYER MAX ,  ZIRKER GUENTER

IPC: C07C29/14 ,  B01J23/00 ,  B01J23/883 ,  C07B61/00 ,  C07C27/00 ,  C07C29/141 ,  C07C31/02 ,  C07C67/00

Abstract: Manufacture of saturated aliphatic alcohols by hydrogenation of saturated aliphatic aldehydes at temperatures of from 140 DEG to 230 DEG C at pressures of from 50 to 350 atmospheres in the presence of catalysts containing from 5 to 15% by weight nickel and 5 to 20% by weight molybdenum supported on silicic acid, in which process catalysts are used which have been obtained by heating silicic acid carrier materials to temperatures of from 700 DEG to 1200 DEG C, impregnating the resulting silicic acid carrier materials with nickel and molybdenum salts, drying the resulting material with or without further heating to temperatures of from 200 DEG to 500 DEG C and subsequently treating the product with hydrogen at elevated temperature in conventional manner. The alcohols obtained are used as solvents or for the manufacture of plasticizers for polyvinyl chloride.

公开(公告)号：CA1108165A

公开(公告)日：1981-09-01

申请号：CA297717

申请日：1978-02-24

Applicant: BASF AG

Inventor： FOUQUET GERD ,  MERGER FRANZ ,  BAER KARL

IPC: B01J31/00 ,  C07B61/00 ,  C07D301/02 ,  C07D303/04

Abstract: O.Z. 32,460 Propylene oxide is prepared by elimination of water from propylene glycol which in turn is obtainable from propylene glycol acetate. The water is eliminated in the gas phase over a solid catalyst which consists of a weakly acidic carrier and an alkaline additive. The process offers a new method of manufacturing propylene oxide.