7.
    发明专利
    未知

    公开(公告)号:DE2703811A1

    公开(公告)日:1978-08-10

    申请号:DE2703811

    申请日:1977-01-29

    Applicant: BASF AG

    Abstract: A pressure-sensitive recording material which comprises a substrate bearing a dye-forming component and a binder. The dye-forming component is a spirodipyran of the formula where A is the radical of a fused benzene or naphthalene ring (which rings may or may not be substituted), R1 is alkyl of 1 to 16 carbon atoms, substituted or unsubstituted phenyl or phenalkyl of 7 to 10 carbon atoms, R2 is H or together with R1 is a trimethylene or tetramethylene bridge which is unsubstituted or substituted by from 1 to 3 alkyl, R3 is benzyl or beta -phenylethyl and R4 is benzyl, beta -phenylethyl or substituted or unsubstituted phenyl, or R3 is alkyl of 1 to 4 carbon atoms and R4 is substituted or unsubstituted phenyl or R3 is benzyl and R4 is beta -cyanoethyl. The recording materials give violet to bluish green colorations (copies) only on paper coated with an electron acceptor.

    10.
    发明专利
    未知

    公开(公告)号:DE2430568A1

    公开(公告)日:1976-01-15

    申请号:DE2430568

    申请日:1974-06-26

    Applicant: BASF AG

    Abstract: New spirodipyrans of the formula (I) in which A is an optionally substituted benzene or naphthalene nucleus, B is dimethylene, trimethylene or tetramethylene substituted by from 1 to 3 alkyl groups and R1 and R2 are each alkyl of 1 to 6 carbon atoms, which may be substituted by cyano. The compounds (I) give deep blue to violet colorations with acid materials. They may be used for the manufacture of pressure-sensitive recording materials. The compounds (I) exhibit improved solubility in the solvents used for the manufacture of microcapsules.

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