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公开(公告)号:DE1643238A1
公开(公告)日:1972-02-24
申请号:DE1643238
申请日:1967-08-16
Applicant: BASF AG
Inventor: BERDING CHRISTOPH DR , GUENTHERT PAUL DR , KOEHLER WALDEMAR DR , SCHULZ GERHARD DR
Abstract: Continuous production of alkali metal salts of nitrilotriacetic acid from an alkali metal cyanide, formaldehyde and ammonia by reaction of the components in at least two stages, the alkali metal cyanide being reacted with formaldehyde in stoichiometric or substantially stoichiometric ratio at temperatures of 50 DEG to 200 DEG and pressures of from atmospheric pressure to 50 atmospheres gauge in the presence of an excess of ammonia in the first stage and (while simultaneously removing ammonia) further amounts of alkali metal cyanide and formaldehyde being allowed to act at temperatures of 60 DEG to 110 DEG C in one or more subsequent stages, 5 to 35 mole percent of the total amount of alkali metal cyanide required being replaced by free hydrocyanic acid and/or hydroxyacetonitrile.
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公开(公告)号:CH501591A
公开(公告)日:1971-01-15
申请号:CH1193569
申请日:1969-08-06
Applicant: BASF AG
Inventor: BERDING CHRISTOPH DR , GUENTHERT PAUL DR , SCHULZ GERHARD DR , KOEHLER WALDEMAR DR
IPC: C07C101/20
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公开(公告)号:DE1643232A1
公开(公告)日:1971-05-27
申请号:DE1643232
申请日:1967-07-12
Applicant: BASF AG
Inventor: BERDING CHRISTOPH DR , GUENTHERT PAUL DR , KOEHLER WALDEMAR DR , SCHULZ GERHARD DR
IPC: C07C20060101 , C07C
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公开(公告)号:CH502306A
公开(公告)日:1971-01-31
申请号:CH1147268
申请日:1968-07-31
Applicant: BASF AG
Inventor: BERDING CHRISTOPH DR , GUENTHERT PAUL DR , KOEHLER WALDEMAR DR , SCHULZ GERHARD DR
IPC: C07C263/02 , C07C263/10 , C07C265/04 , C07C101/20
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公开(公告)号:DE1793227A1
公开(公告)日:1972-03-09
申请号:DE1793227
申请日:1968-08-17
Applicant: BASF AG
Inventor: BERDING CHRISTOPH DR , GUENTHERT PAUL DR , SCHULZ GERHARD DR , KOEHLER WALDEMAR DR
IPC: C07C101/20
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公开(公告)号:CH374988A
公开(公告)日:1964-02-15
申请号:CH7731159
申请日:1959-08-24
Applicant: BASF AG
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公开(公告)号:CH491860A
公开(公告)日:1970-06-15
申请号:CH1034268
申请日:1968-07-11
Applicant: BASF AG
Inventor: BERDING CHRISTOPH DR , GUENTHERT PAUL DR , KOEHLER WALDEMAR DR , SCHULZ GERHARD DR
IPC: C07C20060101 , C07C101/20
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