公开(公告)号：DE3328771A1

公开(公告)日：1985-02-28

申请号：DE3328771

申请日：1983-08-10

Applicant: BASF AG

Inventor： HARTIG JUERGEN DR ,  SCHUCH GUNTER DR ,  STOESSEL ARMIN DR ,  HERRMANN GUENTER DR ,  BRUNNER ARTHUR ,  ZEHNER PETER DR ,  GROSSKINSKY OTTO-ALFRED DR

IPC: C07C27/12 ,  C07C27/00 ,  C07C29/50 ,  C07C35/08 ,  C07C45/33 ,  C07C49/403 ,  C07C51/16 ,  C07C51/215 ,  C07C51/265 ,  C07C67/00

Abstract: Oxygen-containing compounds are prepared by oxidizing a hydrocarbon in the liquid phase with a gas containing molecular oxygen, at elevated temperatures and under superatmospheric pressure, by a continuous process in which the said gas is fed into the liquid reaction mixture, in a downward direction, at several points along the reaction zone via nozzle apertures, so that it emerges at each nozzle aperture with a velocity of from 0.01 to 1 m/sec in an amount of from 0.001 to 10 liters per second per nozzle aperture, and the said reaction mixture is brought into substantially uniform contact with the gas containing molecular oxygen, over the volume of the reaction zone.

公开(公告)号：DE3460248D1

公开(公告)日：1986-07-24

申请号：DE3460248

申请日：1984-07-28

Applicant: BASF AG

Inventor： HARTIG JUERGEN DR ,  SCHUCH GUNTER DR ,  STOESSEL ARMIN DR ,  HERRMANN GUENTER DR ,  BRUNNER ARTHUR ,  ZEHNER PETER DR ,  GROSSKINSKY OTTO-ALFRED DR

IPC: C07C27/12 ,  C07C27/00 ,  C07C29/50 ,  C07C35/08 ,  C07C45/33 ,  C07C49/403 ,  C07C51/16 ,  C07C51/215 ,  C07C51/265 ,  C07C67/00

Abstract: Oxygen-containing compounds are prepared by oxidizing a hydrocarbon in the liquid phase with a gas containing molecular oxygen, at elevated temperatures and under superatmospheric pressure, by a continuous process in which the said gas is fed into the liquid reaction mixture, in a downward direction, at several points along the reaction zone via nozzle apertures, so that it emerges at each nozzle aperture with a velocity of from 0.01 to 1 m/sec in an amount of from 0.001 to 10 liters per second per nozzle aperture, and the said reaction mixture is brought into substantially uniform contact with the gas containing molecular oxygen, over the volume of the reaction zone.