公开(公告)号：DE59208331D1

公开(公告)日：1997-05-15

申请号：DE59208331

申请日：1992-12-18

Applicant: BASF AG

Inventor： KARRER LOTHAR DR ,  HERZOG KLAUS DR ,  AICHINGER HEINRICH DR ,  EICHHORN HANS-DIETER DR ,  HERRMANN GUENTER DR

IPC: B01J23/92 ,  B01J23/84 ,  B01J23/90 ,  B01J23/94 ,  B01J37/00 ,  B01J38/02 ,  B01J38/12 ,  B01J38/60 ,  C07C45/35

公开(公告)号：DK0475173T3

公开(公告)日：1994-03-28

申请号：DK91114242

申请日：1991-08-24

Applicant: BASF AG

Inventor： SCHWARZMANN MATTHIAS DR ,  AICHINGER HEINRICH DR ,  BOEHNING KARL-HEINZ DR ,  HERZOG KLAUS DR ,  WISTUBA HERMANN DR ,  BUERGER GERT DR ,  HERRMANN GUENTER DR

IPC: B01D53/94 ,  B01D53/86 ,  B01J23/50 ,  B01J35/10 ,  B01D53/36

Abstract: In a catalyst for the decomposition of nitrous oxide, pure or in gaseous mixtures, metallic silver is applied to an alumina support having a BET surface area of 5 to 25 m /g.

公开(公告)号：DE4100505A1

公开(公告)日：1992-07-16

申请号：DE4100505

申请日：1991-01-10

Applicant: BASF AG

Inventor： FRANK GERHARD DR ,  HERRMANN GUENTER DR ,  BUERGER GERT DR ,  MANEGOLD JOST HENRICH DR ,  KARBACH STEFAN DR ,  SCHMITZ RUEDIGER

IPC: B01J23/847 ,  C07B61/00 ,  C07C51/31 ,  C07C51/42 ,  C07C51/44 ,  C07C51/47 ,  C07C55/14

Abstract: A process for working up mother liquors resulting from the preparation of adipic acid by oxidation of cyclohexanol or cyclohexanone or mixtures thereof with nitric acid entails removal of nitric acid by azeotropic distillation with water, heating the resulting melt at from 130 DEG to 180 DEG C. and then dissolving it in water, treating the aqueous solution with cation exchangers, subsequently again evaporating off the water and heating the resulting dicarboxylic acid melt at from 200 DEG to 240 DEG C. and then obtaining a mixture of dicarboxylic acids by distillation.

公开(公告)号：AT271425B

公开(公告)日：1969-06-10

申请号：AT877066

申请日：1966-09-16

Applicant: BASF AG

Inventor： DOCKNER TONI DR ,  PLATZ ROLF DR ,  HERRMANN GUENTER DR ,  MINSINGER MANFRED DR ,  DREHER ERICH DR

IPC: C07C20060101

公开(公告)号：DE19640886A1

公开(公告)日：1998-04-09

申请号：DE19640886

申请日：1996-10-04

Applicant: BASF AG

Inventor： SCHERZER DIETRICH DR ,  HAHN KLAUS DR ,  LORENZ MARIA DR ,  HERRMANN GUENTER DR ,  DIETZEN FRANZ-JOSEF DR ,  EHRMANN GERD DR ,  NAEGELE DIETER DR

IPC: C08J9/00 ,  C08K3/00 ,  C08K3/22 ,  C08K3/32 ,  C08K13/02 ,  C08L25/06 ,  C08J9/04 ,  C08K3/20 ,  C08K5/521 ,  C08K5/524 ,  C09K21/14

公开(公告)号：DE59104800D1

公开(公告)日：1995-04-06

申请号：DE59104800

申请日：1991-12-19

Applicant: BASF AG

Inventor： FRANK GERHARD DR ,  HERRMANN GUENTER DR ,  BUERGER GERT DR ,  MANEGOLD JOST HENRICH DR ,  KARBACH STEFAN DR ,  SCHMITZ RUEDIGER

IPC: B01J23/847 ,  C07B61/00 ,  C07C51/31 ,  C07C51/42 ,  C07C51/44 ,  C07C51/47 ,  C07C55/14

Abstract: A process for working up mother liquors resulting from the preparation of adipic acid by oxidation of cyclohexanol or cyclohexanone or mixtures thereof with nitric acid entails removal of nitric acid by azeotropic distillation with water, heating the resulting melt at from 130 DEG to 180 DEG C. and then dissolving it in water, treating the aqueous solution with cation exchangers, subsequently again evaporating off the water and heating the resulting dicarboxylic acid melt at from 200 DEG to 240 DEG C. and then obtaining a mixture of dicarboxylic acids by distillation.

公开(公告)号：DE3763474D1

公开(公告)日：1990-08-09

申请号：DE3763474

申请日：1987-01-13

Applicant: BASF AG

Inventor： HARTIG JUERGEN DR ,  HERRMANN GUENTER DR ,  LUCAS EKHART DR

IPC: C07C49/403 ,  B01J31/00 ,  B01J31/18 ,  B01J31/26 ,  C07C27/00 ,  C07C27/12 ,  C07C27/26 ,  C07C29/50 ,  C07C35/08 ,  C07C45/00 ,  C07C45/33 ,  C07C45/53 ,  C07C45/78 ,  C07C45/80 ,  C07C67/00 ,  C07C409/06

Abstract: Reaction mixtures which contain cyclohexyl hydroperoxide, cyclohexanol and cyclohexanone and are obtained by oxidizing cyclohexane with molecular oxygen, or a gas containing this, in the liquid phase at from 130 DEG to 200 DEG C. under from 5 to 25 bar are worked up by treatment with an aqueous alkali solution in the presence of a cobalt salt at elevated temperatures by an improved process wherein a phosphonic acid compound of the formula I where X is alkylene or 2 to 6 carbon atoms, R1 is -CH2PO3H and R2, R3 and R4 may be identical or different and are each -CH2PO3H, -CH2OH, hydrogen or alkyl of 1 to 4 carbon atoms, is concomitantly used.

公开(公告)号：DE3601218A1

公开(公告)日：1987-07-23

申请号：DE3601218

申请日：1986-01-17

Applicant: BASF AG

Inventor： HARTIG JUERGEN DR ,  HERRMANN GUENTER DR ,  LUCAS EKHART DR

IPC: C07C49/403 ,  B01J31/00 ,  B01J31/18 ,  B01J31/26 ,  C07C27/00 ,  C07C27/12 ,  C07C27/26 ,  C07C29/50 ,  C07C35/08 ,  C07C45/00 ,  C07C45/33 ,  C07C45/53 ,  C07C45/78 ,  C07C45/80 ,  C07C67/00 ,  C07C409/06 ,  C07C27/14 ,  C07C179/053

Abstract: Reaction mixtures which contain cyclohexyl hydroperoxide, cyclohexanol and cyclohexanone and are obtained by oxidizing cyclohexane with molecular oxygen, or a gas containing this, in the liquid phase at from 130 DEG to 200 DEG C. under from 5 to 25 bar are worked up by treatment with an aqueous alkali solution in the presence of a cobalt salt at elevated temperatures by an improved process wherein a phosphonic acid compound of the formula I where X is alkylene or 2 to 6 carbon atoms, R1 is -CH2PO3H and R2, R3 and R4 may be identical or different and are each -CH2PO3H, -CH2OH, hydrogen or alkyl of 1 to 4 carbon atoms, is concomitantly used.

公开(公告)号：DE3560109D1

公开(公告)日：1987-05-07

申请号：DE3560109

申请日：1985-01-25

Applicant: BASF AG

Inventor： BRUNNER ERWIN DR ,  GROSSKINSKY OTTO-ALFRED DR ,  HERRMANN GUENTER DR ,  KROKOSZINSKI ROLAND DR ,  MAGNUSSEN PETER DR

IPC: C07C27/12 ,  C07C27/00 ,  C07C29/50 ,  C07C35/08 ,  C07C45/00 ,  C07C45/33 ,  C07C49/403 ,  C07C67/00 ,  C07C407/00 ,  C07C409/06 ,  C07C409/14 ,  C07C179/053 ,  C07C178/00

公开(公告)号：DE3360059D1

公开(公告)日：1985-03-14

申请号：DE3360059

申请日：1983-05-31

Applicant: BASF AG

Inventor： HARTIG JUERGEN DR ,  STOESSEL ARMIN DR ,  HERRMANN GUENTER DR ,  MAROSI LASZLO DR

IPC: C07C27/00 ,  B01J23/00 ,  B01J23/75 ,  B01J29/04 ,  B01J29/072 ,  B01J29/10 ,  B01J29/14 ,  C07B61/00 ,  C07C27/12 ,  C07C29/132 ,  C07C29/50 ,  C07C35/08 ,  C07C45/00 ,  C07C45/53 ,  C07C49/403 ,  C07C67/00

Abstract: Cyclohexanol and cyclohexanone are prepared by treating cyclohexyl hydroperoxide with a supported catalyst containing from 2 to 30% by weight, calculated as cobalt, of cobalt in oxidic form, at from 30 DEG to 160 DEG C., by a process wherein a zeolite is used as the carrier.